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61.
Peter Weyerstahl Helga Marschall Hans‐Christian Wahlburg Christian Christiansen Abdolhossein Rustaiyan Fatemeh Mirdjalili 《Flavour and Fragrance Journal》1999,14(2):121-130
The essential oil of Pulicaria gnaphalodes (Vent.) Boiss. from Iran was investigated by GC, GC–MS and NMR spectroscopy. Typical for this oil are pinane [chrysanthenone ( 23 ), cis‐chrysanthenol ( 34 )], cadinane [cadina‐1(10),4‐dien‐8α‐ol ( 114 )] and bisabolane derivatives [nuciferol ( 118 ), γ‐curcumen‐12‐ol ( 119 )]. New, naturally occurring compounds are (Z)‐3‐methylnon‐3‐en‐2‐one ( 43 ), the so‐called helifolen‐12‐als 94 , 95 , 98 , 99 , tricyclic sesquiterpene aldehydes with a helifolane (syn. allo‐cedrane or khusiane) skeleton, and the italicen‐12‐ols 108 and 110 . These aldehydes and alcohols are presumably formed by [4+2] resp. [2+2] cycloaddition of the corresponding γ‐curcumene derivatives. Copyright © 1999 John Wiley & Sons, Ltd. 相似文献
62.
Nicolau J. Ferreira Inês G. Meireles de Sousa Tiago Cunha Luís Antnio Jos M. Currais Ana Cristina Figueiredo Monya M. Costa A. Sofia B. Lima Pedro A. G. Santos Jos G. Barroso Luis G. Pedro Johannes J. C. Scheffer 《Flavour and Fragrance Journal》2007,22(1):1-9
Aerial parts of Pittosporum undulatum were collected fortnightly for 1 year at the Parque de Saúde de Lisboa. Collective samples of two populations were investigated, i.e. from pruned and non‐pruned trees, and in addition samples from one pruned and one non‐pruned individual. An SEM study of the aerial parts showed the presence of non‐glandular T‐shaped trichomes, and capitate trichomes with an elongated stalk and two to four round‐shaped cells on the top. Numerous canals were seen at the level of the capsule wall as well as in the leaves and stems. Essential oil samples were isolated from the (deep‐frozen) aerial parts by hydrodistillation to estimate the oil yields, and by distillation–extraction to determine their percentage composition, and analysed by GC and GC–MS. Monoterpenes (59–97%) were dominant in all oils, sabinene (5–58%), limonene (2–37%) and terpinen‐4‐ol (4–27%) being the major components, although in different relative amounts during the year of collection. Benzyl benzoate (8%) and benzyl salicylate (10%) attained high relative amounts in the oils from fully developed flowers, whereas in the oils from the other plant parts their relative amounts did not exceed 1%. The enantiomeric ratio of sabinene, limonene and terpinen‐4‐ol was investigated in the leaf, flower and capsule oils, showing dominance of the (+)‐forms and homogeneity between all the oil samples. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
63.
论述HCSC6型环锤式碎煤机筛板间隙的调节原理和理论计算方法,并使之运用于实际,使碎煤机筛板间隙的调节快速、准确,为环锤式碎煤机在理想工况下运行创造必要的条件。 相似文献
64.
Thermal explosion hazards on 18650 lithium ion batteries with a VSP2 adiabatic calorimeter 总被引:1,自引:0,他引:1
Thermal abuse behaviors relating to adiabatic runaway reactions in commercial 18650 lithium ion batteries (LiCoO2) are being studied in an adiabatic calorimeter, vent sizing package 2 (VSP2). We select four worldwide battery producers, Sony, Sanyo, Samsung and LG, and tested their Li-ion batteries, which have LiCoO2 cathodes, to determine their thermal instabilities and adiabatic runaway features. The charged (4.2 V) and uncharged (3.7 V) 18650 Li-ion batteries are tested using a VSP2 with a customized stainless steel test can to evaluate their thermal hazard characteristics, such as the initial exothermic temperature (T0), the self-heating rate (dT/dt), the pressure rise rate (dP/dt), the pressure-temperature profiles and the maximum temperature (Tmax) and pressure (Pmax). The Tmax and Pmax of the charged Li-ion battery during the runaway reaction reach 903.0 °C and 1565.9 psig (pound-force per square inch gauge), respectively. This result leads to a thermal explosion, and the heat of reaction is 26.2 kJ. The thermokinetic parameters of the reaction of LiCoO2 batteries are also determined using the Arrhenius model. The thermal reaction mechanism of the Li-ion battery (pack) proved to be an important safety concern for energy storage. Additionally, use of the VSP2 to classify the self-reactive ratings of the various Li-ion batteries demonstrates a new application of the adiabatic calorimetric methodology. 相似文献
65.
《International Journal of Hydrogen Energy》2019,44(31):16841-16851
Cryo-compressed hydrogen storage promises to deliver the highest system storage density leading to practical vehicles with range comparable to today's gasoline vehicles and fundamental cost and safety advantages. However, cryogenic vessels are complex systems, continuously drifting in thermodynamic space depending on use patterns, insulation performance, vessel characteristics, liquid hydrogen pump performance, and para-H2 to ortho-H2 conversion. In this paper, cryogenic vessel fill density results from a previous publication are extended to calculate system storage performance, including volumetric (gH2/L), gravimetric (H2 weight fraction), and vent losses over a broad range of conditions. The results confirm previous experiments and models indicating that cryogenic pressure vessels have maximum system density of all available storage technologies while avoiding vent losses in all but the most extreme situations. Design pressures in the range 250–350 bar seem most advantageous due to high system density and low weight and cost, although determining an optimum pressure demands a complete economic and functional analysis. Future insulation, vessel, and liquid hydrogen pump improvements are finally analyzed that, while not experimentally demonstrated to date, show promise of being feasible in the future as their level of technical maturity increases, leading to maximum H2 storage performance for cryo-compressed storage. If proven feasible and incorporated into future cryogenic vessels, these improvements will enable 50 + gH2/L system density at 10+% H2 weight fraction. 相似文献
66.
《International Journal of Hydrogen Energy》2019,44(47):26100-26108
Experiments were conducted in an obstructed 3-m-long duct to investigate the effects of equivalence ratio, thickness of rupture membrane, and vent area on vented hydrogen–air deflagrations. Shockwave-induced pressure peaks were observed inside and outside the duct in some tests. In the tests with one end of the duct totally opened, the location at which the overall maximum internal overpressure is achieved depends on the thickness of the rupture membrane for a given equivalence ratio; however, it is independent of equivalence ratio for a given thickness of rupture membrane. The pressure peak resulting from an external explosion always dominates the pressure–time histories 1.5 m downstream of the duct exit. The maximum internal and external overpressures first increase and then decrease as the equivalence ratio increases from 0.26 to 3.57, unexpectedly; none of these increase monotonically with an increase in the thickness of the rupture membrane. Two explosion venting regimes, namely sonic and subsonic, are observed. During sonic venting, the maximum internal overpressure increases exponentially with a decrease in vent area; it is nearly independent of the vent area during subsonic venting when the vent area is larger than approximately 19% of the cross-sectional area of the duct. 相似文献
67.
Explosion relief panels or doors are often used in industrial buildings to reduce damages caused by gas explosions. Decades of research have contributed to the understanding of the phenomena involved in gas explosions in order to establish an effective method to predict reliably the explosion overpressure. All the methods predict a monotonic increase of the overpressure with the concentration of the gas in the range from the lower explosion limit to the stoichiometric one. Nevertheless, in few cases, a non-monotonic behaviour of the maximum developed pressure as a function of hydrogen concentration was reported in the literature. The non-monotonic behaviour was also observed during experimental tests performed at the Scalbatraio laboratory at the University of Pisa, in a 25 m3 vented combustion test facility, with a vent area of 1,12 m2. This paper presents the results obtained during the tests and investigates the possible explanations of the phenomena. 相似文献
68.
文章在研究了双螺杆挤出机各段中物态变化及作用的基础上,分析了目前硬PVC制品生产中使用双螺杆挤出机的一些问题,如平行双螺杆挤出机能否用于生产异型材、是否一定要使用定量给料器、挤出机排气口冒料的工艺控制及螺杆设计等问题。 相似文献
69.