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Utilising a pseudo-reference electrode in polymer electrolyte fuel cells allows for the separation of anodic and cathodic contributions to the entire cell impedance. Modelling the impedance responses by using equivalent circuits inhibits the investigation of kinetic parameters of the basic electrochemical reactions, which take place at single electrode-electrolyte interfaces. Therefore, we evaluate single electrode impedance measurements by a kinetic model, which is based on specific reaction pathways, either for the oxygen reduction reaction (ORR) or the hydrogen oxidation reaction (HOR). As a consequence, it is possible to obtain kinetic parameters for the specific reaction of interest. Furthermore, the information gained from the single electrode impedance measurements and the kinetic model can give insight into single reactions steps. In particular, the ORR has to include a chemical step in the reaction pathway. 相似文献
74.
A hierarchical scheme for elastic graph matching applied to hand gesture recognition is proposed. The proposed algorithm exploits the relative discriminatory capabilities of visual features scattered on the images, assigning the corresponding weights to each feature. A boosting algorithm is used to determine the structure of the hierarchy of a given graph. The graph is expressed by annotating the nodes of interest over the target object to form a bunch graph. Three annotation techniques, manual, semi-automatic, and automatic annotation are used to determine the position of the nodes. The scheme and the annotation approaches are applied to explore the hand gesture recognition performance. A number of filter banks are applied to hand gestures images to investigate the effect of using different feature representation approaches. Experimental results show that the hierarchical elastic graph matching (HEGM) approach classified the hand posture with a gesture recognition accuracy of 99.85% when visual features were extracted by utilizing the Histogram of Oriented Gradient (HOG) representation. The results also provide the performance measures from the aspect of recognition accuracy to matching benefits, node positions correlation and consistency on three annotation approaches, showing that the semi-automatic annotation method is more efficient and accurate than the other two methods. 相似文献
75.
《Pattern recognition》2014,47(2):588-602
Fingerprint matching has emerged as an effective tool for human recognition due to the uniqueness, universality and invariability of fingerprints. Many different approaches have been proposed in the literature to determine faithfully if two fingerprint images belong to the same person. Among them, minutiae-based matchers highlight as the most relevant techniques because of their discriminative capabilities, providing precise results. However, performing a fingerprint identification over a large database can be an inefficient task due to the lack of scalability and high computing times of fingerprint matching algorithms.In this paper, we propose a distributed framework for fingerprint matching to tackle large databases in a reasonable time. It provides a general scheme for any kind of matcher, so that its precision is preserved and its time of response can be reduced.To test the proposed system, we conduct an extensive study that involves both synthetic and captured fingerprint databases, which have different characteristics, analyzing the performance of three well-known minutiae-based matchers within the designed framework. With the available hardware resources, our distributed model is able to address up to 400 000 fingerprints in approximately half a second. Additional details are provided at http://sci2s.ugr.es/ParallelMatching. 相似文献
76.
This paper addresses the problem of reinforcing the ability of the k-NN classification of handwritten characters via distortion-tolerant template matching techniques with a limited quantity of data. We compare three kinds of matching techniques: the conventional simple correlation, the tangent distance, and the global affine transformation (GAT) correlation. Although the k-NN classification method is straightforward and powerful, it consumes a lot of time. Therefore, to reduce the computational cost of matching in k-NN classification, we propose accelerating the GAT correlation method by reformulating its computational model and adopting efficient lookup tables. Recognition experiments performed on the IPTP CDROM1B handwritten numerical database show that the matching techniques of the simple correlation, the tangent distance, and the accelerated GAT correlation achieved recognition rates of 97.07%, 97.50%, and 98.70%, respectively. The computation time ratios of the tangent distance and the accelerated GAT correlation to the simple correlation are 26.3 and 36.5 to 1.0, respectively. 相似文献
77.
Polyaniline emeraldine base/epoxy resin (EB/ER) coating was investigated for corrosion protection of mild steel coupled with copper in 3.5% NaCl solution. EB/ER coating with 5-10 wt% EB had long-term corrosion resistance on both uncoupled steel and copper due to the passivation effect of EB on the metal surfaces. During the 150 immersion days, the impedance at 0.1 Hz for the coating increased in the first 1-40 days and subsequently remained constant above 109 Ω cm2, whereas that for pure ER coating fell below 106 Ω cm2 after only 30 or 40 days. Immersion tests on coated steel-copper galvanic couple showed that EB/ER coating offered 100 times more protection than ER coating against steel dissolution and coating delamination on copper, which was mainly attributed to the passive metal oxide films formed by EB blocking both the anodic and cathodic reactions. Salt spray tests showed that 100 μm EB/ER coating protected steel-copper couple for at least 2000 h. 相似文献
78.
在时空数据中有一类表示用户在某一时间到达某一地点的数据——到达数据,到达数据可以是社交网站的签到数据、轨迹数据中的停留点及公共交通中乘客抵达的位置数据,这些数据的聚簇可以反映用户的聚集行为.基于到达数据,提出一类新的时空数据查询——时空异常聚簇发现.将到达数据进行周期性划分,通过时空聚类算法对一个时间段的数据进行聚类,比较不同时间段内聚簇的差异度,发现具有最大簇异常度的前k个簇.通过该查询发现的时空异常聚簇可以应用于城市安全管理、基于位置的服务和交通调度等方面.定义了异常簇查询模型,提出了针对任意形状聚簇的簇差异度度量,将异常簇查询转化为二分图最大匹配问题,对二分图构建与匹配进行了优化并提出了高效的查询算法.利用真实数据集进行了充分实验,验证了查询结果的实际意义,评估了所提出的各查询算法在不同参数设置下的查询效率. 相似文献
79.
传统合成聚焦超声成像方法在图像重建过程中处理数据量较大,致使其在便携式B型超声设备中应用受限。针对该问题,提出一种基于压缩感知理论和合成聚焦波束形成算法的便携式B型超声成像方法(SFCS)。该方法通过对接收到的射频回波信号进行随机采样得到欠采样的测量信号,将测量信号经过合成聚焦波束形成处理获得欠采样的射频信号线,基于压缩感知的信号重构算法,由欠采样的射频信号线高质量地恢复信号后供后续成像处理使用。仿真实验结果表明,SFCS可有效地解决合成聚焦超声成像过程中数据量大的问题,从而在保证较高成像质量的前提下满足便携式B型超声设备小型化、低成本的技术要求,具有工程应用价值。 相似文献
80.
In recent years, polymer amines have been studied as an efficient corrosion inhibitor for iron in acid media. In this article, the performance of water soluble polyaniline as corrosion inhibitor for iron in 0.5M H2SO4 has been evaluated by potentiodynamic polarization, linear polarization, and electrochemical impedance spectroscopy and compared with the performance of the aniline monomer. It has been found that polyaniline is an efficient inhibitor, since the maximum efficiency of 84% has been observed at a concentration of 100 ppm, whereas the monomer has accelerated the corrosion. FTIR studies have shown that the polyaniline is strongly adsorbed on the iron surface and inhibits the corrosion effectively. However, aniline has been found to improve the passivation tendency of iron at higher concentrations. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 2144–2153, 2006 相似文献