Degradation of p-nitrotoluene by 03/H2 02 process and oxidation mechanism

The degradation of p-nitrotoluene by O2/H2O2 process in a bubble contact column was investigated.Effects of the molar ratio of hydrogen peroxide to ozone, pH value and t-butanol on the oxidation process were discussed. It was found that the proper H2 O2/O3 molar ratio for the degradation of p-nitrotoluene was around O. 6, different pH values and the presence of t-butanol highly influenced the removal efficiency of p-nitrotoluene. 5-metbyl-2-nitrophenol, 2-methy1-5-nitrophenol, (4-nitrophenyl) methanol, 5-(hydroxymethyl) -2-nitro phenol, acetic acid, 2-methylpropanc diacid and 2-(hydroxylmethyl) propane diacid were identified as degradation intermediates and products through GC-MS. Radical reaction mechanism and degradation pathway were proposed based on the results of experiments. It is deduced that the benzene ring of p-nitrotoluene can be only destroyed by hydroxyl radicals through a polyhydrexy intermediate pathway. Then unstable polybydroxy intermediates can be oxidized to different acids with low molecular weight rapidly.     

计算机在化工设计中的应用

计算机用于化工设计有着独特的优点。比如在分子模拟、稳态流程模拟和计算机辅助设计(Computer Aided Design)等领域。化工设计者应敏锐地看到计算机技术在化工设计中显示出的发展潜力。     

“准老年”高技能人才资源开发的途径

随着经济的高速发展和产业结构调整的加快,我国对中高级人才的需求日趋旺盛,许多地方和行业出现了中高级人才荒。探讨“准老年”高技能人才资源对人力资源配置和社会养老保障的意义,“准老年”高技能人才资源具有可开发性,提出利用社会组织、网络平台、专家协会和老年教育等途径。     

卷取机动态补偿力矩的计算及在系统中的实现

详细论述了卷取机动态力矩的数学模型及在控制系统中的实现问题,最后给出了采用CAD计算动态力矩和动态电流、确定相关工艺参数的方法.     

岩土工程勘察的重点分析

近年来,岩土工程勘察技术发展得非常快,研究领域不断拓展,取得了较多的成就。但是,在发展过程中也存在一些不足。重点分析了岩土工程勘察工作,并结合实际工作提出一些个人意见,以期能为相关工作提供帮助。     

CAD/CAE公共服务平台中资源共享智能型系统研究

在产业技术公共服务平台的影响和带动下,随着其用户规模不断扩大和信息技术的发展,越来越要求平台服务向智能化发展,有必要对其中之一的资源共享智能型系统建设进行探讨。     

基于ADS的脉冲压缩雷达系统仿真与性能分析

在高级设计系统ADS仿真平台上,开发了一套具有良好通用性和灵活性的脉冲压缩雷达系统模型库,为今后开发大规模雷达系统模型库和进行复杂雷达系统仿真打下了基础;在此工作基础上,以巴克码脉冲压缩信号为例,建立了相应的雷达系统模型,并结合系统性能分析的需求,在该系统仿真设计过程中引入蒙特.卡罗模型,较全面地得到了系统基本性能指标值;由这些指标值可以看出,该巴克码脉冲压缩雷达系统性能良好;仿真结果与理论值和真实系统值相符,从而正确地完成了系统的方案论证和性能评估。     

Aperture-Adjustable and Repairable Metal-Based MOFs Catalysis Membrane for Water Purification

Precise adjustment of the pore size, damage repair, and efficient cleaning is all challenges for the wider application of inorganic membranes. This study reports a simple strategy of combining dry-wet spinning and electrosynthesis to fabricate stainless-steel metal–organic framework composite membranes characterized by customizable pore sizes, targeted reparability, and high catalytic activity for membrane cleaning. The membrane pore size can be precisely customized in the range of 14–212 nm at nanoscale, and damaged membranes can be repaired by targeted treatment in 120 s. In addition, advanced oxidation processes can be used to quickly clean the membrane and achieve 98% flux recovery. The synergistic actions of the membrane matrix and the selective layer increase the adsorption energy of active sites to oxidant, shorten the electron transfer cycle, and enhance the overall catalytic performance. This study can provide a new direction for the development of advanced membranes for water purification and high-efficiency membrane cleaning methods.     

“汇编语言程序设计”的比较教学法

基于比较教学法的优势,文章从数据安排、数据处理、流程控制、子程序结构等程序设计的基本方面对汇编语言和高级语言中的相关机制作了对比分析,提出了"汇编语言程序设计"比较教学的基本思路。     

车用尾气催化转化器结构的计算辅助设计与分析系统

采用ＡｕｔｏＬＩＳＰ语言,编制了运行于ＡｕｔｏＣＡＤ平台上的车用尾催化转化器结构的计算辅助设计与分析系统。该系统结合了参数化设计与性能分析功能,并采用对话框驱动执行的方式,使系统的使用具有直观、方便的特点,可为车用尾气催化转化器的研制工作提供有益帮助。,