基于马尔可夫决策过程的电动汽车充电行为分析

针对电动汽车充电行为不确定性问题,建立了基于出行链理论的电动汽车出行及电池电量变化模型,提出了引入马尔可夫决策过程（Markov decision processes, MDP）的电动汽车用户充电行为分析方法。该方法将用户充电行为作为马尔可夫决策集,根据车辆在各区域间的转移概率构造状态转移矩阵,设置用户满意度指标作为决策过程报酬函数,通过求解有限阶段总报酬准则得到电动汽车用户在每个决策点处的最优充电决策。算例部分根据抽取电动汽车特征量数据进行马尔可夫决策过程仿真,得出充电负荷的时间与空间分布情况,通过与传统蒙特卡洛方法进行对比表明该文所提方法可以较好地模拟用户整个出行过程中的充电行为,反映充电需求的时空分布特点;同时,分析了不同区域、不同停车时长情况下电动汽车的不同充电行为,能够为电动汽车充电桩的规划建设提供参考。     

两阶段机场多特种车辆协同充电调度策略

在机场区域内,新能源特种车辆充电具有很大的随机性,且不同种类特种车辆充电情况各不相同,造成飞行区内各充电桩利用率相差过大,影响机场配电网的健康运行。针对上述现象,设计了十一车型两阶段特种车辆协同充电调度策略。第一阶段通过分析不同车辆对航班的保障流程,以同一车辆对相邻航班保障起始时间差值最小为目标,生成存在充电需求的车辆序列。第二阶段以减小飞行区各区充电桩时间利用率方差和车辆充电排队时间为目标,在上一阶段车辆序列基础上采用改进的自适应变异粒子群算法进行模型求解,并以国内某枢纽机场的实际车辆充电数据进行对比验证。实验表明,采用该算法后,车辆充电时的等待时间降低了93.5%、飞行区充电桩时间利用率的整体方差下降了88.7%,达到了均衡使用充电桩的目标。     

ZIF-67原位负载纳米纤维素基锂离子电池隔膜的制备及性能研究

本研究以纳米纤维素（CNF）为原料,经乙酰化、原位负载ZIF-67和浸渍电解液制备出一种新型ZIF-67@乙酰化纳米纤维素（ZIF-67@ACNF）锂离子电池隔膜,系统探讨了ZIF-67的粒径对隔膜结构及性能的影响。结果表明,当ZIF-67的粒径从0.46 μm（ZIF-67₄@ACNF隔膜）减小至0.25 μm（ZIF-67₈@ACNF隔膜）时,隔膜的孔隙率从74.2%减小至52.1%,离子电导率从0.75 mS/cm下降至0.22 mS/cm,界面电阻从112.5 Ω增加至1 115.7 Ω,锂离子迁移数从0.41减小至0.31,电化学稳定窗口从5.1 V减小至4.5 V。采用ZIF-67₄@ACNF隔膜组装电池,在室温、0.5 C的条件下进行电池充/放电测试,初始容量达到159.6 mAh/g,循环200圈后容量保持率达到90%。     

Metal–Organic Gel‐Derived FexOy/Nitrogen‐Doped Carbon Films for Enhanced Lithium Storage

The development of cost‐effective and flexible electrodes is demanding in the field of energy storage. Herein, flexible Fe_xO_y/nitrogen‐doped carbon films (Fe_xO_y/NC‐MOG) are prepared by facile electrospinning of Fe‐based metal–organic gels (MOGs) followed by high‐temperature carbonization. This approach allows the even mixing of fragile coordination polymers with polyacrylonitrile into flexible films while reserving the structural characteristics of coordination polymers. After thermal treatment, Fe_xO_y/NC‐MOG films possess uniformly distributed Fe_xO_y nanoparticles and larger accessible surface areas than traditional Fe_xO_y‐NC films without MOG. Taking advantage of the unique structure, Fe_xO_y/NC‐MOG exhibits a superior rate performance (449.8 mA h g^?1 at 5000 mA g^–1) and long cycle life (629.3 mA h g^–1 after 500 cycles at 1000 mA g^–1) when used as additive‐free anodes in lithium‐ion batteries.     

Selective Recovery of Cadmium,Cobalt, and Nickel from Spent Ni–Cd Batteries Using Adogen® 464 and Mesoporous Silica Derivatives

Spent Ni–Cd batteries are now considered an important source for many valuable metals. The recovery of cadmium, cobalt, and nickel from spent Ni–Cd Batteries has been performed in this study. The optimum leaching process was achieved using 20% H₂SO₄, solid/liquid (S/L) 1/5 at 80 °C for 6 h. The leaching efficiency of Fe, Cd, and Co was nearly 100%, whereas the leaching efficiency of Ni was 95%. The recovery of the concerned elements was attained using successive different separation techniques. Cd(II) ions were extracted by a solvent, namely, Adogen^® 464, and precipitated as CdS with 0.5% Na₂S solution at pH of 1.25 and room temperature. The extraction process corresponded to pseudo-2nd-order. The prepared PTU-MS silica was applied for adsorption of Co(II) ions from aqueous solution, while the desorption process was performed using 0.3 M H₂SO₄. Cobalt was precipitated at pH 9.0 as Co(OH)₂ using NH₄OH. The kinetic and thermodynamic parameters were also investigated. Nickel was directly precipitated at pH 8.25 using a 10% NaOH solution at ambient temperature. FTIR, SEM, and EDX confirm the structure of the products.     

风能、太阳能储能用铅蓄电池的开发前景

分析了风能、太阳能独立发电系统储能蓄电池的使用状况,探讨了储能蓄电池使用环境对蓄电池的要求,认为储能蓄电池开发和应用面临着很多困难,需从板栅合金、铅膏配方、固化、化成等各工序进行分析研究,力争有所突破。     

侧链多阳离子型氟化聚芴醚阴离子交换膜及其全钒液流电池性能

阳离子基团的分布对阴离子交换膜的微观相态和阴离子传导率有显著的影响.为开发全钒液流电池用高性能阴离子交换膜,本文通过向含有二甲胺基团的氟化聚芴醚前驱体接枝含阳离子烷基链的方式,合成了具有相似离子交换容量的一系列侧链多阳离子型氟化聚芴醚.实验结果表明,多阳离子侧链的引入能促进微观相分离的形成并提升阴离子传导率.同时,侧链...     

氨浸工艺从废旧锂电池中选择性回收有价金属

研究了碳酸氢铵-还原剂体系选择性浸出废旧三元锂电池中锂、镍、钴的过程。考察了浸出温度、碳酸氢铵浓度、还原剂的种类和浓度、固液比及浸出时间等对有价金属浸出率的影响,并通过XRD、SEM-EDS和FT-IR等表征方法对选择性浸出机理进行了初步探明。结果表明：在浸出温度80 ℃、浸出时间2.5 h、碳酸氢铵浓度2.5 mol/L、固液比50 g/L、还原剂亚硫酸钠浓度0.6 mol/L的条件下,锂、镍、钴的浸出率分别为96.86%、96.36%、93.43%,而锰几乎不被浸出。碳酸氢铵-亚硫酸钠还原浸出体系可以实现从废旧三元锂电池材料中高效、选择性回收锂、镍和钴。