α黄铜选择性溶解的研究

采用恒电流E-t曲线与旋转盘环电极方法研究了α黄铜(Cu32Zn)在酸性Na2SO4和HNO3稀溶液中的阳极溶解行为,得到的典型E-t曲线上存在几个特征区,证明在较低电流密度条件下的初始阶段只存在Zn的选择性溶解。用恒电位法研究了Cu32Zn选择性溶解过程,得到了按抛物线衰减的暂态扩散曲线,由i-t-1/2直线关系求得了不同介质中Cu32Zn中Zn的固相扩散系数D在10-16～10-13cm2·s-1数量级,发现中性介质中测出的D值比酸性介质中要大两个数量级。     

氯化铜在水溶液中的扩散系数的测定SCIEI

用膈膜池法测定了298K条件下CuCl_2在CuCl_2和CuCl_2-HCl水溶液中的扩散系数。发现CuCl_2的扩散系数与其浓度依赖性主要取决于它的化学位和溶液的粘度。     

激光合金化熔池成分均匀性与形状系数的关系SCIEI

本文研究了激光工艺参数对镀Cr中碳低合金钢激光合金化熔池形状系数及成分均匀性的影响。实验结果表明,熔池成分均匀性取决于其截面形状系数,后者是光束功率密度和交互作用时间的函数。在功率密度一定时,形状系数与交互作用时间成线性关系。当形状系数为1.6—3.0时,可以获得成分均匀的熔池。     

基于容量参数的二次电池嵌入型电极材料固相扩散系数的测定方法

介绍了一种以容量参数为主变量的测定锂二次电池中电极材料固相扩散系数的方法.该方法只需颗粒半径这一辅助参数,通过球型扩散模型建立了恒流-恒压充电容量(RPG)比,进一步发展成为容量间歇滴定技术(CITT).采用RPG法可在较宽的电压范围内测定嵌入型电极材料的平均固相扩散系数,实验结果重现性好.由RPG法测得0～1.5 V时锂离子在石墨电极中的平均固相扩散系数值为1.055×10-10cm2/s.由CITT技术测得锂离子在LiMn2 O4中的固相扩散系数在3.95 V和4.12 V左右存在个两个极小峰,且随着循环次数的增加,扩散系数值逐渐增大.     

石墨化率不同的自焙炭块的热膨胀

采用精密垂直拉杆膨胀仪在１４～１０００℃范围内测量了具有不同石墨化率的自焙炭块的相对热伸长量，并由此获得了热线膨胀系数α。结果表明：石墨化率一定时，α值在较低温度下随温度升高而增加，在较高温度下，α值随温度变化不明显；恒温时，石墨化率越高，α值越低。讨论了单位热应力下的弹性模量概念     

中频炉酸性炉衬使用寿命的探讨

通过对炉衬材料的选择,作用机理及影响石英砂炉衬材料寿命的相关因素的阐述,说明了SD-T-A石英砂干振料可提高中频炉酸性炉衬使用寿命的原因.     

On the evaluation of the global heat transfer coefficient in cutting

The use of numerical simulations for investigating machining processes is remarkably increasing because of the simulation cost is lower than the experiments and the possibility to analyze local variables such as pressures, strains, and temperatures is allowable. Process simulation is very hard from a computational point of view, since it frequently requires remeshing phases and very small time steps. As a consequence, the simulated cutting time is usually of the order of few milliseconds and no steady cutting conditions are generally achieved, at least as far as thermal conditions are concerned. Therefore, nowadays numerical prediction of cutting temperatures cannot be considered fully reliable. In the paper this issue was taken into account: a mixed Lagrangian-Eulerian numerical approach was utilized and the global heat transfer (film) coefficient at the tool-chip interface was derived through an inverse approach. Finally, the dependence of the film coefficient on pressure and temperature on the rake face was investigated.     

气动位置伺服系统的高精度控制研究

提出采用电-气压力比例阀构成气动位置伺服系统,运用全局线性化的观点线性化描述系统动态特性的数学方程,补偿了气缸活塞行程变化对系统控制性能的不良影响,并采用离散线性二次最优控制原理设计了系统的控制补偿器,实现了气动位置伺服系统的高精度控制。     

Diffusion of additives and plasticizers in poly(vinyl chloride): 4. A programmed temperature technique for the determination of the diffusion parameters of three dialkylphthalates

A programmed temperature technique has been developed for the measurement of the self-diffusion coefficients of additives in polymers. This has been applied to the diffusion of three dialkylphthalate plasticizers in poly(vinyl chloride). Values of the self-diffusion coefficients and the calculated activation energies obtained in this way have been compared with values previously obtained from measurements at constant temperature. It has been shown that the programmed temperature technique gives a very rapid method for the estimation of the activation energy of self-diffusion.     

用WKB方法讨论透射系数和反射系数

本文用WKB近似方法讨论了势垒贯穿问题系数T和其透射反射系数R之和恒等为1,即满足恒等式T R=1,并进一步得出这一结论不仅适用于一般势垒贯穿而且在方势垒贯穿中也成立,最后讨论了势垒贯穿的几种极限情况,例如,h→0(即经典情况),势垒高度v→∞、v→0,势垒宽度a→∞、a→0,等几种特殊情况下的T及R的取值问题。