PolyHIPE块体中甲基丙烯酸甲酯的ATRP溶液聚合

将用高内相比乳液(HIPE)聚合法得到的多孔聚合物块体(poly HIPE)作为聚合的反应器,在其内部进行甲基丙烯酸甲酯(MMA)的原子转移自由基聚合反应(ATRP),通过扫描电镜、凝胶渗透色谱、红外光谱、热重分析、核磁共振和差示扫描量热等测试手段对块体内聚合的PMMA进行了分析测试。研究表明,MMA在poly HIPE块体内部按照ATRP聚合机理发生聚合;poly HIPE块体对MMA的ATRP溶液聚合影响不同于受限空间内部进行的传统自由基聚合及反向原子转移自由基聚合(RATRP);相较于普通的ATRP溶液聚合,块体内部ATRP聚合所得PMMA的数均相对分子质量有所降低,相对分子质量分布变窄,热稳定性有所提高,间同立构比例有所下降,但全同立构比例明显增加,玻璃化转变温度有所下降。     

Differentiation between the terms ”confined masonry“ and ”infill masonry“

This publication concerns the differentiation between the terms ”confined masonry“ and ”infill masonry“ using the example of the national technical approval Z‐17.1‐1145 – POROTON S9 MW –vertically perforated clay units with integrated thermal insulation using thin layer mortar [1].     

利用GM（1,1）模型对地下水恢复进行预测分析

沧州市区关停深层自备井后,深层地下水恢复取得了明显的效果。本文采用色系统中GM（1,1）模型对第Ⅴ含水组地下水埋深进行预测。     

有限封闭环境中基于PCA的水声测距方法

有限空间中多途效应严重影响测距的准确性,针对该问题,提出一种基于主成分分析的水声信号测距方法,对信号协方差矩阵进行降维和特征抽取,在保留协方差矩阵信息量的同时抑制多途干扰信号的影响。实验结果表明,该方法能够提高有限封闭液态场环境中水声测距的准确性和稳健性。     

Interplay Between Wetting and Phase Behavior in Binary Polymer Films and Wedges: Monte Carlo Simulations and Mean Field Calculations

Confining a binary mixture, one can profoundly alter its miscibility behavior. The qualitative features of miscibility in confined geometry are ratheruniversal and shared by polymer mixtures as well as small molecules, but the unmixing transition in the bulk and the wetting transition are typically well separated in polymer blends. The interplay between wetting and miscibility of a symmetric polymer mixture via large-scale Monte Carlo simulations in the framework of the bond fluctuation model and via numerical self–consistent field calculations is studied. The film surfaces interact with the monomers via short ranged potentials, and the wetting transition of the semi–infinite system is of first order. It can be accurately located in the simulations by measuring the surface and interface tensions and using Young’s equation. If both surfaces in a film attract the same component, capillary condensation occurs and the critical point is close to the critical point of the bulk. If surfaces attract different components, an interface localization/delocalization occurs which gives rise to phase diagrams with two critical points in the vicinity of the pre-wetting critical point of the semi–infinite system. The crossover between these two types of phase diagrams as a function of the surface field asymmetry is studied. The dependence of the phase diagram on the film thickness Δ for antisymmetric surface fields is investigated. Upon decreasing the film thickness, the two critical points approach the symmetry axis of the phase diagram, and below a certain thickness Δ_tri, there remains only a single critical point at the symmetric composition. This corresponds to a second-order interface localization/delocalization transition even though the wetting transition is of first order. At a specific film thickness, Δ_tri, tricritical behavior is found. The behavior of antisymmetric films is compared with the phase behavior in an antisymmetric double wedge. While the former is the analog of the wetting transition of a planar surface, the latter is related to the filling behavior of a single wedge. Evidence for a second-order interface localization/delocalization transition in an antisymmetric double wedge is presented, and its unconventional critical behavior is related to the predictions of Parry et al. (Phys. Rev. Lett. 83:5535 (1999)) for wedge filling. The critical behavior differs from the Ising universality class and is characterized by strong anisotropic fluctuations.Invited paper presented at the Fifteenth Symposium on Thermophysical Properties, June 022–27, 2003, Boulder, Colorado, U.S.A.     

圆柱壳限制失稳的实验研究

采用高分子高弹性材料Mylar薄膜制作衬壳,其外侧的刚性限制为钢制圆柱筒壳,两端用加强环压紧以模拟边界条件。用气压加载模拟圆柱壳受周向均匀压力,观察衬壳的屈曲过程,同时测量衬壳的临界载荷。实验测量结果与有限元计算的结果符合较好。另外还通过人为制造不同初始缺陷和变换不同壳体长度,研究了限制失稳临界载荷与初始缺陷及不同长度的关系。结果表明圆柱薄衬壳受侧向外压的限制失稳临界载荷比自由失稳临界载荷有很大提高。     

钢管混凝土梁柱节点受力性能的试验研究

钢筋混凝土梁与钢管混凝土柱节点的受力性能是影响钢管混凝土结构应用的关键问题．针对某电信枢纽中心的工程实践提出了穿心牛腿 环梁的新型节点构造形式，依据相似原理进行了静载及反复荷载下节点模型试验研究．试验研究表明，该节点传力路线明确，受力性能较好．根据试验结果改进后的新型节点已用于工程实践．