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Paul J Tikalsky Della RoyBarry Scheetz Tara Krize 《Cement and Concrete Research》2002,32(8):1239-1246
Experimental research was performed to relate specific cement characteristics to expansion due to sulfate attack. Twenty-one North American cement of statistically diverse chemical composition were used in the study. ASTM 1012 “Standard Test Method for Length Change of Hydraulic Cement Mortars Exposed to a Sulfate Solution” was performed using mortars prepared with each of the cement. First-order and multivariate relationships between cement characteristics and sulfate expansion were correlated at different ages. Analysis revealed that while tricalcium aluminate (C3A) has typically been targeted as the chief contributor to sulfate attack, iron oxide (Fe2O3) or tetracalcium aluminoferrite (C4AF) content, combined with total equivalent alkalis, showed a much stronger negative correlation with expansions at all ages. These results are in agreement with a broad spectrum of sulfate expansion theories and can provide a better means of specifying sulfate-resistant cement. 相似文献
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The electrochemical characterization of 304 stainless steel in 0.1–0.5m Na2SO4 and Na2SO4 + NaHCO3 aqueous solutions at pH8 was done in combination with SEM surface analysis. Passivation of the surface film without any pitting events is observed for the current–potential and current–time experiments, and no anodic current spikes, which are associated with depassivation events, are distinguishable above the background current level. However, SEM pictures of an electrode surface polarized at potentials above 0.4V show microscopic pit nucleation. Even when the metal may be regarded as passive from a current–time or current–potential characteristics, passivity is not stable and localized film breakdown can still occur. The events are ascribed to pit nucleation at the active inclusion sites. The pits do not grow even into the metastable state but die through repassivation by metal salt precipitation immediately after birth. The effect is ascribed to the solubility of metal salts with the electrolyte produced by dissolution in the nucleation sites. The results show that pit nucleation and pit growth are two distinct processes. The importance of solution composition and the protective effect of bicarbonate ions is also discussed. 相似文献
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The study reported in this article deals with understanding the physical, chemical and microstructural differences in sulfate attack from seawater and groundwater. Portland cement mortars were completely immersed in solutions of seawater and groundwater. Physical properties such as length, mass, and compressive strength were monitored periodically. Thermal analysis was used to study the relative amounts of phases such as ettringite, gypsum, and calcium hydroxide, and microstructural studies were conducted by scanning electron microscopy. Portland cement mortars performed better in seawater solution compared to groundwater solution. The difference in performance could be attributed to the reduction in the quantity of the expansive attack products (gypsum and ettringite). The high Cl concentration of seawater could have played an important role by binding the C3A to form chloroaluminate compounds, such as Friedel's salt (detected in the microstructural studies), and also by lowering the expansive potential of ettringite. Furthermore, the thicker layer of brucite forming on the specimens in seawater could have afforded better protection against ingress of the solution than in groundwater. 相似文献
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虫洞攻击(wormhole attack)是Ad Hoc网络中一种常见的路由攻击方法。在移动Ad Hoc网络中,虫洞攻击会严重破坏路由协议的正常运行,甚至使整个网络陷于瘫痪。基于Omnet++网络仿真器设计实现了Ad Hoc网络中的虫洞攻击,并提出若干衡量虫洞攻击的指标。仿真实验表明,由于虫洞攻击节点的破坏,网络的性能明显下降。 相似文献
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一种新的多重代理多重数字签名方案* 总被引:4,自引:1,他引:3
基于离散对数问题,提出了一种新的多重代理多重签名方案,该方案指定了签名验证人,在门方案的基础上又完善了签名过程,最终签名由其中一位代理人给出,从而避免了门方案中不具有追踪性、可滥用签名权的漏洞,签名体现了签名者身份信息,进一步防止了伪造攻击,是一种相对安全的多种代理多重数字签名方案。 相似文献