熔融温度对PP中成核剂的异相成核作用的影响

用DSC研究了熔融温度对不同类型成核剂成核PP的异相成核作用的稳定性的影响。观察到随熔融温度提高，纯PP的成核作用稳定，降温结晶温度基本不变。而有机磷酸盐类成核剂成核PP的结果温度比纯PP的高，而且异相成核作用受熔融温度的影响也很小。但山梨醇类成核剂成核PP的异相成核作用随熔融温度提高，结晶温度逐步降低明显，表明其异相成核作用对热不稳定。     

Neutral poly(3,4-ethylenedioxythiophene-2,5-diyl)s: preparation by organometallic polycondensation and their unique p-doping behavior

Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C₆(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C₆(Ni) was soluble in organic solvents and ¹H NMR data indicated that it had an M_n of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave M_n and M_w of about 1700 and 2400, respectively. PEDOTh-C₆(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl₃. Electrochemical oxidation of PEDOTh-C₆(Ni) started at about −0.40 V vs Ag⁺/Ag and gave a peak at 0.20 V vs Ag⁺/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C₆(Ni), both in solutions and in a solid state, led to weakening of the original π-π^∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C₆(Ni) caused not only a decrease in the intensity of ¹H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm⁻³; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data.     

微电机与微加工

简述了和微电机相关的微加工生产中的方法，介绍了微型机电部件成型的实现途径。     

B. F. Skinner: Au-delá de la controverse.

Discusses controversies surrounding the work of B. F. Skinner's influence on various theories of human and animal behavior. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Improvement of oxygen mass transfer estimation from oxygen concentration measurements in bubble column reactors

An original procedure has been established for estimating the overall volumetric mass transfer coefficient using the oxygen concentration curves resulting from the usual gassing-in and gassing-out method. This procedure was applied to experimental data obtained in a small scale bubble column using both tap water and a coalescence-inhibiting liquid mixture that represents the coalescence behavior of biological media. It is based on the analysis of the characteristics times of the system, including those of the hydrodynamics of the two phases, the sensor dynamics and the system inertia when the gas composition is modified. A numerical procedure was developed to estimate the characteristic time of the system inertia t_i, using the assumption that this inertia is nearly independent of superficial gas velocity U_G. The calculations confirmed that the optimized t_i value was nearly independent of U_G and of the coalescence behavior of the liquid phase. Additionally, the resulting K_La_L values for tap water were closer to the correlation of Shah et al. [1982. Design parameters estimations for bubble column reactors. A.I.Ch.E. Journal 28, 353-379] than those of other conventional models. Finally, the original procedure was also reported to reduce significantly the square sum deviation between the predicted and the measured oxygen response curves.     

FAFFA加速的PO-MM研究复杂金属载体上线天线电磁特性

本文提出了一种快速远场近似(FAFFA)加速的混合物理光学矩量法(POMM),利用FAFFA加速计算矩阵方程中的矩阵矢量积,明显提高了计算效率.对物体表面上的远场组之间的耦合作用推导出了一组简洁的计算公式,并分析了计算复杂度.复杂金属组合体上线天线输入导纳、互导纳和方向性图的计算结果与文献结果一致.利用该方法分析计算了一个舰船模型上线天线的电磁特性.数值结果表明了这种方法的正确性和工程应用中的有效性.     

The Importance of Shared Environment in Infant-Father Attachment: A Behavioral Genetic Study of the Attachment Q-Sort.

In this first behavior genetic study on infant-father attachment, we estimated genetic and environmental influences on infant-father attachment behaviors and on temperamental dependency, both assessed with the Attachment Q-Sort (AQS; B. E.Vaughn & E. Waters, 1990; E. Waters, 1995). Mothers of mono- and dizygotic twins (N = 56 pairs) sorted the AQS with a focus on the infant's behaviors in the presence of the father. Genetic modeling showed that attachment was largely explained by shared environmental (59%) and unique environmental (41%) factors. For dependency, genetic factors explained 66% of the variance, and unique environmental factors including measurement error explained 34%. Attachment to father appears to be, to a significant degree, a function of the environment that twins share. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Predicting Youth Access to Tobacco: The Role of Youth Versus Store-Clerk Behavior and Issues of Ecological Validity.

Twenty-one 15- to 17-year-olds attempted to purchase cigarettes in 232 stores in the manner that confederates typically do in access studies, as well as in the manipulative ways (e.g., lying about their ages) that youth smokers do, thereby modeling youth access to tobacco within versus outside of studies, respectively. Youth typical-research versus manipulative behavior was contrasted with clerk behavior (requests for youth ID cards) to examine the relative contributions of both to youth access to tobacco for the 1st time. Results revealed that clerk behavior was the strongest predictor of cigarette sales to youth and hence underscore the need for interventions with merchants. Sales nonetheless were higher under youth-manipulative conditions and thereby highlight the low ecological validity of access research. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

镁质瓷泥浆流变性能的改进

滑石质瓷是一种高性能瓷的材料，但由于其泥浆的稠化性及泥料塑性差，阻碍了滑石质瓷的大量生产。实验表明：引入长石作助熔剂并加入适量粘土，可以改进泥料塑性及泥浆流变性能，使烧成变形度小，机械强度提高，能较好地满足制品成型的工艺要求。实验中设计了多组配料，分析比较烧后试样的性能测试结果，确定最佳配方及烧结温度。