HT-730改性酚醛-丁腈胶粘剂的研制

对酚醛-丁腈胶粘剂进行改性，添加5．0％的硅烷偶联剂，改善了酚醛-丁腈胶粘剂的工艺性能，提高了粘接强度，特别是降低了酚醛-丁腈胶对环境湿度的敏感性。研制的HT-730胶在环境湿度90％时仍有很高的粘接强度，同时老化性能和适用期并没有受到影响。     

Transient and isotopic studies of the oxygen transport and exchange during oxidative coupling of methane on Sr promoted La2O3

Isotopic transient techniques were applied to study oxidative coupling of methane over lanthanum oxide and strontium promoted La₂O₃ catalysts. Results of the¹⁸O₂/¹⁶O₂ isotopic exchange experiments indicate that Sr promotion increases oxygen uptake from the lattice of the catalyst. Oxygen self diffusion coefficients, which were determined for the series of lanthana catalysts, reach a maximum for the 1% Sr/La₂O₃. Steps of¹⁸O₂ in the presence of a steady flow of methane over Sr/La₂O₃ catalysts, indicate that surface and bulk oxygen appear in the reaction products before gas-phase¹⁸O². Steps of CO₂ over catalysts in which lattice oxygen has been exchanged with¹⁸O₂, show that gas/solid exchange involves over 50% of the lattice oxygen. Under reaction conditions, methane pulses with no gas-phase oxygen yield negligible amounts of products which indicates that methane interacts with lattice oxygen only in the presence of the gas-phase oxygen.     

FEM analyses for influences of stress corrosion and pressure solution on THM coupling in dual-porosity rock mass

With the models of stress corrosion and pressure solution, by Yasuhara et al., two computation conditions were designed for a hypothetical nuclear waste repository in an unsaturated dual-porosity rock mass: (i) the fracture apertures are changed with the stress corrosion and pressure solution (the porosity of rock matrix is also a function of stress); (ii) the fracture apertures and the porosity of rock matrix are constants. Then the corresponding two-dimensional FEM analyses for the coupled thermohydro-mec...     

军工院校大学文化与大学发展耦合度评价实证分析

大学文化在现代大学发展中的作用越来越突出,已成为提升大学核心竞争力的重要因素,越来越多的大学把大学文化建设作为学校建设的重要组成部分.因此,大学文化建设的效果评价十分重要.通过建立"大学文化与大学发展耦合度"评价模型,对军工院校大学文化建设的效果进行实证分析.结果表明,哈尔滨工程大学的大学文化与大学发展之间的耦合度较高,耦合作用较强,大学文化在促进学校自觉肩负服务国防使命、实现自身发展目标中的作用明显,大学文化系统与大学发展系统之间呈正相关关系.     

Synthesis of thermosetting poly(phenylene ether) containing allyl groups

New thermosetting poly(2-allyl-6-methylphenol-co-2,6-dimethylphenol)s (3) have been developed by oxidative coupling copolymerization of 2-allyl-6-methylphenol (1) with 2,6-dimethylphenol (2), followed by thermal curing. Copolymerization was conducted in nitrobenzene in the presence of copper(I) chloride and pyridine as the catalyst under a stream of oxygen, producing high molecular weight copolymers (M_n∼50,000) with broad molecular weight distributions (M_w/M_n∼35). The structure of resulting copolymers 3 was characterized by IR, ¹H, and ¹³C NMR spectroscopy. Cross-linking reactions of copolymers were carried out by thermal treatment in the absence or presence of a peroxide (3 wt%, 2,5-dimethyl-2,5-di(tert-butylperoxy)-3-butane). The 10% weight loss and glass transition temperatures of the cured copolymers were 436 °C in nitrogen and 235 °C, respectively after curing at 70 °C for 1 h and 300 °C for 1 h. The average refractive index of the cured copolymer (3b) film was 1.5407, from which the dielectric constant (ε) at 1 MHz was estimated as 2.6. The ε and dissipation factor of copolymer-films at 1 MHz were directly measured from their capacitances as 2.5-2.6 and 0.0015-0.0019, respectively.     

考虑桩顶水平反力的水平受荷单桩弹塑性解析解

基于线性地基反力法和土体的弹塑性本构关系,对桩顶水平反力系数不为零时的水平受荷桩进行了研究,给出了桩顶土屈服临界荷载（水平力、弯矩）的耦合关系式。研究结果表明,当荷载大于临界荷载时,桩顶土发生塑性屈服,其塑性屈服深度随荷载的增加而增加,但其塑性区扩展速率随桩顶荷载的增加而逐渐减小。给出了弹性区与塑性区桩内力耦合的矩阵方程及其迭代求解格式;利用曲面拟合软件给出了塑性区换算深的计算公式。通过工程算例验证,证明该方法可靠快捷,便于手算,值得推广。      

TYPHOON PROCESS AND ITS IMPACT ON THE SURFACE CIRCULATION IN THE NORTHERN SOUTH CHINA SEA

A severe typhoon Utor,occurring between July 3 and 8,2001,brought heavy rainfall,strong wind and storm surge.Utor was responsible for tremendous destruction and economic losses in Philippines,Taiwan and Guangdong.An air-sea model system (MM5 and Princeton Ocean Model(POM))was built to simulate meteorological dynamics and ocean circulation in the South China Sea(SCS).In the POM the output of MM5 was used as the input data.With an increased number of vertical levels,a high-resolution planetary boundary layer scheme and updated landuse/vegetation data,the accuracy of computing wind,temperature and other meteorological fields are improved in near surface and upper levels in MM5 simulations.The simulated trajectory and wind speed of Utor are close to the observed results.The simulated distribution of rainfall is accorded well with measured data in the Pearl River Delta(PRD)area.At different meteorological stations in Hong Kong,the wind,temperature and sea surface pressure are well simulated.The simulated ocean surface current and surface temperature fields have an obvious rightward-biased response to the typhoon Utor,and the maximum velocity and the lowest temperature region appear in the 30 km of the right side of the typhoon track.The typhoon Utor could make the water 50m under the surface ocean unwell to surface and the ocean surface temperature decrease by about 2°C.     

数字解耦控制器设计及其在DDC上的实现

介绍了一种通过设计数字解耦控制器来实现解耦的方法。该方法的优势在于它是通过软件的方式来实现解耦,无须增加任何硬件,在大大地节约了成本的同时也提高控制系统的稳定性能。数字解耦控制器在实际系统中的应用表明该方法取得了良好的控制效果。论文在介绍了目前常用四种解耦方法的基础上对数字解耦控制器的设计思想进行了论述,进而详细地介绍了数字解耦控制器的设计步骤,给出了数字解耦控制器的算法流程图。     

工业机器人机械设计参数对控制能量的影响

以三自由度搬运工业机器人为研究对象,通过机械设计参数与能量指标关系的程序计算和仿真的方法,研究了机械设计参数对控制能量的影响,从而为在提高控制系统性能角度优化机械设计参数提供了依据。     

Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.