差分脉冲极谱法测定苯胺中微量硝基苯

建立了测定苯胺中微量硝基苯的差式微分脉冲极谱法。试验发现硝基苯在-0.57V(vs.Ag/AgCl)处有一个良好的差分脉冲极谱峰。硝基苯质量浓度在1～600μg/mL的范围内,质量浓度与差分脉冲极谱峰的峰高呈线性关系。此法简便、快速、灵敏,结果准确。     

Maximum principle for mean-field jump–diffusion stochastic delay differential equations and its application to finance

This paper investigates a stochastic optimal control problem with delay and of mean-field type, where the controlled state process is governed by a mean-field jump–diffusion stochastic delay differential equation. Two sufficient maximum principles and one necessary maximum principle are established for the underlying system. As an application, a bicriteria mean–variance portfolio selection problem with delay is studied to demonstrate the effectiveness and potential of the proposed techniques. Under certain conditions, explicit expressions are provided for the efficient portfolio and the efficient frontier, which are as elegant as those in the classical mean–variance problem without delays.     

FracSym: Automated symbolic computation of Lie symmetries of fractional differential equations

In this paper, we present an algorithm for the systematic calculation of Lie point symmetries for fractional order differential equations (FDEs) using the method as described by Buckwar & Luchko (1998) and Gazizov, Kasatkin & Lukashchuk (2007, 2009, 2011). The method has been generalised here to allow for the determination of symmetries for FDEs with n$n$ independent variables and for systems of partial FDEs. The algorithm has been implemented in the new MAPLE package FracSym (Jefferson and Carminati 2013) which uses routines from the MAPLE symmetry packages DESOLVII (Vu, Jefferson and Carminati, 2012) and ASP (Jefferson and Carminati, 2013). We introduce FracSym by investigating the symmetries of a number of FDEs; specific forms of any arbitrary functions, which may extend the symmetry algebras, are also determined. For each of the FDEs discussed, selected invariant solutions are then presented.     

Synthesis,characterization, and thermal properties of phosphorus‐containing,wholly aromatic thermotropic copolyesters

A series of phosphorus‐containing, wholly aromatic thermotropic copolyesters from acetylated 2‐(6‐oxide‐6H‐dibenz〈c,e〉〈1,2〉oxa phosphorin‐6‐yl)‐1,4‐dihydroxy phenylene, p‐acetoxybenzoic acid, terephthalic acid, and isophthalic acid were prepared by melting polycondensation. The structure and basic properties of the polymers, such as the glass‐transition temperature (T_g), melting temperature (T_m), thermal stability, crystallinity, and liquid crystallinity, were investigated with Fourier transform infrared, elemental analysis, differential scanning calorimetry (DSC), thermogravimetric analysis, wide‐angle X‐ray diffraction, and hot‐stage polarizing optical microscopy. The copolyesters had relatively high T_g values ranging from 183 to 192°C. The T_m values obtained from DSC curves for samples P‐20 and P‐25 were 290 and 287°C, respectively (where the number in the sample name indicates the molar fraction of the phosphorus‐containing monomer in the reactants). The initial flow temperatures of other samples observed with hot‐stage polarizing microscopy were 271–290°C. The 5% degradation temperatures in nitrogen ranged from 431 to 462°C, and the char yields at 640°C were 41–52%. All the copolyesters, except P‐40, were thermotropic and nematic. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 1278–1284, 2002     

Milk fat fractionation today: A review

Although anhydrous milk fat (AMF) has excellent properties, its variable physicochemical properties and its lack of functionality restrict its uses in the food industry. A technology involving dry fractionation of AMF has been developed, and its attributes include selectivity, reliability and general application. Combining two simple and reliable technologies,i.e., multi-step fractionation and blending, it is possible to overcome functionality problems and the seasonal variations of AMF. Lecture presented at the joint meeting of the International Society for Fat Research and the American Oil Chemists’ Society in Toronto, May 10, 1992.     

SIS-g-AN热降解性能的研究

采用热重分析法和差示热重分析法研究丙烯腈(AN)接枝热塑性弹性体SIS(SIS g AN)的热降解性能。结果得出,SIS g AN的平衡起始降解温度、平衡最大降解速率温度和平衡终止降解温度分别为659. 17, 713. 94 和740.05 K;热降解反应活化能为195.2 kJ·mol-1;热降解机理是Deceleration中的D3 降解机理;不同质量损失率下的热寿命与温度呈线性关系。     

Improvement of polymer blend properties by changing sequence of mixing

The basic objective of this article is to improve the polymer blend properties by changing mixing sequence. Blending of two elastomers does not lead to a molecularly homogeneous blend (true solution), but to a heterogeneous system in which both polymer phases are present. In this article, the detailed study of heterogeneous distribution of carbon black as well as blend inhomogenity and the physicomechanical including dynamic mechanical properties of the blend has been carried out. The choice of the blend was natural rubber/polybutadiene rubber as 85:15. Heterogeneous carbon black distribution study was also performed in differential scanning calorimeter. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 2735–2742, 2007     

Crystallization behavior of dry‐brush PEO‐PS block copolymer and PEO homopolymer blend

The crystallization behavior of semicrystalline PEO homopolymer/triblock PS‐PEO‐PS copolymer blend system, which exhibited “Dry‐Brush” in the melt. A symmetric polystyrene–poly(ethylene oxide)–polystyrene triblock copolymer was blended with PEO homopolymer (h‐PEO) having the same molecular weight as that of the PEO block in the copolymer. Considering the composition of the blend (W_ps ≥ 0.8), PEO spheres were formed in the blend. Because of the dry‐brush phase behavior of this blend, h‐PEO added was localized in the PEO microdomains, which increases the domain size without changing the microdomain morphology. The crystallization of PEO block was confined within the microdomains and the crystallization temperature was about 60°C lower than normal. Self‐seeding tests were performed to clarify the nucleation mechanism of the blend. Because the droplets size varies greatly, multicrystallization peaks were witnessed in the self‐seeding process. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

全自动污泥脱水离心机的电气控制系统

介绍了采用恒差速恒力矩控制方案克服卧螺离心机处理城市污泥时容易产生的堵料问题,介绍了絮凝剂自动制备和添加装置。