Removal of chromium (VI) from dilute aqueous solutions by activated carbon developed from Terminalia arjuna nuts activated with zinc chloride

Different structured activated carbons were prepared from Terminalia arjuna nuts, an agricultural waste, by chemical activation with zinc chloride for the adsorption of Cr(VI) from dilute aqueous solutions. The most important parameter in chemical activation was found to be the chemical ratio (activating agent/precursor, g/g). Carbonization temperature and time are the other two important variables, which had significant effect on the pore structure of carbon. A high surface area of was obtained at a chemical ratio of 300%, carbonization time and temperature of 1 h and 500 °C, respectively. The activated carbon developed shows substantial capability to adsorb Cr(VI) from dilute aqueous solutions. The parameters studied include pH, adsorbent dosage, contact time, and initial concentrations. The kinetic data were best fitted to the Lagergren pseudo-first-order model. The isotherm equilibrium data were well fitted by the Langmuir and Freundlich models. The maximum removal of chromium was obtained at pH 1.0 (about 99% for adsorbent dose of 2 g/l and 10 mg/l initial concentration).     

中国建筑涂料工业的现状及当前形势下的发展对策

本文详细分析了中国建筑涂料工业的现状和存在问题，并结合当前形势，提出了中国建筑涂料工业的发展对策。     

结构光视觉引导的焊接机器人系统自标定技术

为实现结构光视觉引导的焊接机器人系统的标定,解决现有标定方法复杂,标定靶标制作要求高等缺点,提出一种基于主动视觉的自标定方法。该标定方法对场景中3个特征点取像,通过精确控制焊接机器人进行5次平移运动,标定摄像机内参数和手眼矩阵旋转部分;通过进行2次带旋转运动,结合激光条在特征点平面的参数方程,标定手眼矩阵平移部分和结构光平面在摄像机坐标系下的平面方程;并针对不同焊枪长度进行修正。在以Denso机器人为主体构建的结构光视觉引导的焊接机器人系统上的测试结果稳定,定位精度可达到±0.93 mm。该标定方法简单,特征选取容易,对焊接机器人系统在实际工业现场的使用有重要意义。     

无线体域网技术研究现状与展望

无线体域网(WBAN)技术是当前重要的研究热点,可以应用于医院内患者实时监测和家庭健康护理领域,具有广泛的应用前景和巨大的市场潜力。WBAN对设备的可穿戴性和数据传输的可靠性、安全性提出了更高的要求,技术发展中存在一些需要深入研究和解决的问题。对WBAN关键技术的研究现状和产业化进展进行了综述,并对WBAN技术的未来研究和发展前景进行了展望。     

基于FPGA的多路矿用气体传感器智能调校系统

矿用气体传感器因煤矿安全被大量使用,国家规定必须定期进行调校,目前的传感器调校系统可同时对5-8台传感器进行调校,针对大中型煤矿生产过程中需要调校的矿用气体传感器数量大、调校耗时长的现状,提出了一种基于单片机与现场可编程门阵列（FPGA）的64路气体传感器调校系统,介绍了系统的整体设计并详细阐述了该系统的气路控制模块和传感器输出信号采集模块,使用Verilog语言在QuartusⅡ工具中实现FPGA的逻辑设计、仿真和综合。结果证明：该系统能有效地完成对64路气体传感器同时调校的目的,很大程度节省了人力消耗,提高了调校效率,节约了调校时间。     

MEMS气体流量传感器的简易流量测试装置

为了完成所研制的MEMS气体流量传感器样品的流量测试与标定,设计制作了一种由标准流量发生器和传感器信号读出与数据采集电路组成的简易流量测试装置。标准流量发生器由注射器和可更换的砝码组成,利用不同的砝码配重,在注射器出气口产生合适的恒定气体流速。通过理论分析和Ansys有限元数值仿真,验证了简易标准流量发生器的可行性。传感器信号读出与数据采集电路基于内建多路A/D转换器的单片机实现,具有传感器加热电阻器的恒温控制、流量信号的数字检测和显示的功能。采用该简易流量测试装置对自行研制的MEMS气体流量传感器进行了流量测试与标定,获得了待测器件的标定参数、传感器流量测量的绝对误差和相对误差。     

Fabrication of high surface area graphitic nanoflakes on carbon nanotubes templates

Graphitic nanoflakes were fabricated on the carbon nanotubes templates for increasing the surface area utilizing bias assisted microwave plasma enhanced chemical vapor deposition (MWPECVD). The analysis of morphologies and structures were achieved by means of scanning electron microscopy and transmission electron microscopy. The surface area of graphitic nanoflakes, carbon nanotubes (CNTs) and graphitic nanoflakes/CNTs were 57.44 m²/g, 90.31 m²/g and 130.96 m²/g from BET measurement, respectively. The cyclic voltammetry was used to calculate the active area of platinum catalysts in 1 M sulfuric acid from hydrogen adsorption peak. An enhancement of activity could be observed from the calculation of CV results. This may be attributed to the small particle size and high dispersion of platinum particles coated on graphitic nanoflakes/CNTs. These high surface area materials could be used as catalysts supports or electrode for fuel cell applications.     

压痕法确定纤维复合材料界面影响区蠕变特性的数值模拟法

研究由平头压痕蠕变试验来确定纤维复合材料界面影响区蠕变性能参数的可行性。利用有限元蠕变分析确定在定压痕应力下的压痕蠕变率，重点放在稳定压痕蠕变率和复合材料材料界面影响区的蠕变性能参数的关系上。计算结果表明，界面影响区的剪应力沿纤维轴向在蠕变的主要过程中均匀分布，并且保持不变；详细地研究了压头大小对压痕蠕变响应的影响：提出两种方法由压痕蠕变试验来确定界面影响区蠕变性能参数，并给出了算例。这些结果也有利于准确认识平头压痕蠕变试验从而拓宽其应用范围。     

Surface modification of macroporous Al2O3 tubes with carbon-doped TiO2 intermediate layer and preparation of highly permeable palladium composite membranes for hydrogen separation

ABSTRACT

To prepare H₂-permeable palladium composite membranes, a novel carbon-doped microporous TiO₂ intermediate layer was introduced to modify the surface of macroporous Al₂O₃ substrates. The Pd/TiO₂–C/Al₂O₃ membrane was prepared via electroless plating, and thereafter, carbon residue in the intermediate layer was removed by calcination in air, yielding a Pd/TiO₂/Al₂O₃ membrane. Experimental results indicate that the carbon residue shrinks the pore size of the intermediate layer and facilitates a decrease of membrane defects. Additionally, carbon removal induces a higher effective membrane area at the permeate side, which enhances hydrogen permeability. Furthermore, the apparent activation energy (E_A) and stability of the as-prepared Pd/TiO₂/Al₂O₃ membrane were investigated.     

风拖曳力系数和曼宁系数对风暴潮流模拟的影响

利用0205号威马逊台风期间实测风暴增水和风暴潮流数据,采用NCEP FNL和台风模型风场的融合风场作为驱动项,建立了覆盖东海的三维风暴潮流数值模型,研究风拖曳力系数和曼宁系数对风暴增水和风暴潮流的影响。计算结果表明:(1)风拖曳力系数取值应考虑随风速变化。表层风暴潮流受风拖曳力系数影响较大,中层和底层风暴潮流基本不受影响。(2)风暴潮流结构在一定程度上取决于曼宁系数;曼宁系数对中层和底层风暴潮流影响大于表层,曼宁系数越大,底摩擦阻力越大,风暴潮流垂向分层越明显。(3)风暴增水和风暴潮流对曼宁系数的响应不同,建立模型时,应同时率定风暴增水和风暴潮流。