Charge transfer resistance of spray deposited and compressed counter electrodes for dye-sensitized nanoparticle solar cells on plastic substrates

Electrochemical impedance spectroscopy was used to determine the effective charge transfer resistances of porous dye-sensitized solar cell counter electrodes prepared by low-temperature spray deposition and compression of conductive carbon and platinized Sb-doped SnO₂ powders on indium tin oxide-coated plastic substrates. The charge transfer resistances were 0.5–2 and 8–13 Ω cm², respectively, when using 3-methoxypropionitrile as the electrolyte solvent. The manufacturing method used lends itself to produce mechanically stable and even-quality electrodes in an easy and fast manner.     

NiCuZn铁氧体和银内电极的共烧行为

NiCuZn铁氧体正作为磁介质广泛地应用于低烧多层片式电感，因此有必要对其与银内电极的共烧行为进行研究。该文主要介绍NiCuZn铁氧体／银内电极多层复合体共烧过程中的烧结收缩、界面反应、扩散对介质性能的影响。尖晶石结构中存在相当数量的空位，这为银离子提供了一定的溶解度，因此在共烧过程中银对铁氧体的相组成影响较小。银对铁氧体性能的影响体现在两个方面。一方面是由于银具有相对低的烧结温度，从而在烧结过程中起到助烧剂的作用，促进致密化过程，提高烧结体的密度和磁导率；另一方面，银促使铁氧体中的铜在晶界处析出，导致晶界处应力，使磁导率降低，晶粒生长也被一定程度地抑制。     

催化部分氧化法制氢的水碳比控制与探讨

简要介绍了国内少有的干气催化部分氧化转化制氢工艺,重点讨论了转化水碳比的控制条件,对降低水碳比操作进行了有益地探讨。     

系列尼古丁PVC膜选择性电极的研制

以尼古丁为研究对象 ,研制了一系列含有不同增塑剂 (苯二甲酸二辛酯、苯二甲酸二壬酯和癸二酸二辛酯 )和电活性物质 (尼古丁 四苯硼缔合物、尼古丁 硅钨酸缔合物、尼古丁 磷钨酸缔合物和尼古丁 雷氏盐缔合物 )的PVC膜电极。所有的 8支电极均对尼古丁盐酸溶液有Nernst响应。所制备的电极中 ,以尼古丁 四苯硼缔合物、尼古丁 硅钨酸缔合物、尼古丁 磷钨酸缔合物或尼古丁 雷氏盐缔合物为活性物的电极 ,其线性范围达到 10 - 4～ 10 - 1 mol/L ,以尼古丁 硅钨酸缔合物为活性物的电极线性范围达到 10 - 5～ 10 - 1 mol/L。电极响应的均匀性还在进一步的研究和改善中     

Investigation of electrode and hydrogen induced crack in welded joint of dissimilar steel

The welded joint of dissimilar heat-resisting steels 20Crl2MoV(F12)and 12 Cr2MoWVTiB(102)generally works around 600°C.In this paperthree kinds of ferritic electrodes are used for testing.They are R817 high-strength electrode(CrllMoVNi),R347 low-strength electrode(Cr2MoVWB)and newly-developed R507MoNb medium-strength electrode.The study on theinfluence of those three different electrodes on carbon migration,HIC and hy-drogen diffusion shows that medium-strength electrodes can well control thecarbon migration,and that the tendency to HIC in the joint formed by R817 issmaller than that by R347 instead.Considering the effect of weld metal transfor-mation on the restraint stress and hydrogen concentration of a joint,the hydro-gen distribution in the heat-affected zone(HAZ)is calculated by using finite ele-ment method(FEM)with stress and strain changing,and so the effect of thetransformation behaviour on HIC is revealed.In addition,newly-developedR507MoNb electrodes,tested the elevated-temperature property,oxidation re-sistance and creep rupture strength,have fulfilled the technical standards con-cerned and passed the examination of on-the-spot operation.     

浅谈软弱地基应用干振法加固施工技术

分析了软弱地基干振法的加固原理及承载力特点，介绍了加固施工过程的程序及有关注意事项，对施工中的疑难问题提出了处理措施，总结了该施工技术的诸多优点。     

Effects of thermal oxidation conditions of silicon electrodes on cathodic electrochemiluminescence of Ru(bpy)3 chelate

Hot electrons emitted from thin oxide film-coated heavily doped silicon electrodes by cathodic pulse polarization can induce electrochemiluminescence from luminophores. The intensity of electrochemiluminescence produced at the electrode surface is dependent on the features of thin oxide films formed by thermal oxidation. As a preliminary study, we investigated the effect of thermal oxide growth conditions on the intensity of electrochemiluminescence produced at these electrodes, such as oxidation atmospheres, oxidation temperature, oxidation time and pre-treatment of wafers, using ruthenium(II) tris-(2,2′-bipyridine) chelate as a model luminophore. Optimal oxidation conditions of heavily doped silicon electrodes were obtained for the generation of intense electrochemiluminescence at this kind of silicon electrodes.     

石墨电极高温抗氧化技术研究现状

概述石墨电极抗氧化技术的研究现状，重点介绍选择抗氧化涂层体系的要求及涂层制备方法，包括包埋浸渗法、化学气相沉积法、等离子喷涂法及溶胶--凝胶法．展望了石墨电极材料高温抗氧化涂层研究的方向．     

土石坝无粘性粗粒料填筑标准和质量评价探讨

土石坝无粘性粗粒料填筑标准往往根据经验确定,而施工质量主要是通过碾压参数控制,理论依据不足。最大干密度和已建工程实践证明表面振动器法最大干密度与实际填筑干密度基本相等,可以直接指导设计和施工,据此提出了设计和施工控制标准;从砂砾石料、堆石料等无粘性粗粒料的特性探讨了填筑标准的适用范围,利用干密度与<5 mm粒径含量关系和填筑干密度,可以准确及时地对照填筑标准作出填筑质量评价结果。     

Electrochemical determination of estradiol using a poly(l-serine) film-modified electrode

A thin film of poly(l-serine) was prepared via electropolymerization for the determination of trace levels of estradiol. In pH 5.0 phosphate buffer, l-serine was oxidized during the cyclic potential sweeps between −0.60 and 2.0 V, forming a thin film at the electrode surface. The electrochemical behavior of estradiol was investigated. The oxidation peak potential of estradiol shifts negatively at the poly(l-serine) film-coated glassy carbon electrode (GCE) compared with that at the bare GCE. Otherwise, the oxidation peak current greatly increases at the poly(l-serine) film-modified GCE. These phenomena suggest that the poly(l-serine) film exhibits catalytic activity towards the electrochemical oxidation of estradiol. Based on this, a sensitive, rapid and simple electrochemical method was proposed for the determination of estradiol. The limit of detection is evaluated to be 2.0 × 10⁻⁸ mol L⁻¹. Finally, this method was successfully used to determine estradiol in blood serum.