Kinetics of phenol oxidation in a trickle bed reactor over active carbon catalyst

The wet air oxidation of phenol over a commercial active carbon catalyst was studied in a trickle bed reactor (TBR) in the temperature and oxygen partial pressure ranges of 120–160 °C and 0.1–0.2 MPa, respectively. The performance of the active carbon was compared in terms of phenol and COD destruction. The weight change of active carbon due to reaction was also measured. Finally, oxic phenol adsorption isotherms were assessed in batch conditions at 25, 125 and 160 °C. In order to use the conversion data obtained from the TBR for a kinetic study, special care was taken to check the kinetic control in the TBR experiments. Several kinetic models including power law or Langmuir–Hinshelwood expressions were considered to describe the catalytic oxidation of phenol over active carbon. The simple power law model with first order dependence on both phenol and oxygen concentration predicted satisfactorily the experimental data not only over the entire range of operating conditions studied, but also outside its validity range. Copyright © 2005 Society of Chemical Industry     

The Danish Twin Apartment Study – Part II: Mathematical modeling of the relative strength of sources of indoor air pollution

Abstract This study deals with the modeling of air pollution in apartments from laboratory measurements of source strengths, using formaldehyde and Total Volatile Organic Compounds (TVOCs) as model pollutants. The sources in two test apartments were grouped into two: building-related sources and occupant-related sources. The measured source strengths and ventilation rates were used for the prediction of concentrations expected in the apartments. These predictions were compared to measurements in the apartment over 12 months. The conclusions were that the model predictions based on emission rates measured in the laboratory can be used to predict the long-term concentration of the two model pollutants in the apartments. Considering the measured differences in ventilation between the apartments, an occupant emission rate of between 0.2 and 0.3 mg/h/kg body weight could be estimated. Based on previous suggested limits of acceptable exposures of humans to VOCs, an acceptable average emission rate of VOCs from building materials in general was estimated to be about 30 (μ/m²/h. The modeling showed that during the first 200 days, building materials dominated the emissions. After this, sources relating to the occupants dominated. On average about half of the VOC pollution originated from the building materials.     

Analysis of low load transients for the Vandellòs-II NPP: Application to operation and control support

The Technical University of Catalonia (UPC) has been jointly working with the Asociación Nuclear Ascó-Vandellòs (ANAV) for a number of years in order to establish, qualify and use best estimate (BE) models for the reactors under the control of ANAV. ANAV is the consortium that is responsible for operation of the Ascó and Vandellòs-II reactors. The reactors are Westinghouse-design three-loop PWRs with an approximate electrical power of 1000 MW. The existing integral plant models for each plant are currently used for many different purposes among which are support of plant operation and control. Quite a number of studies have been done in order to improve both safety and plant competitiveness. Most of these dynamic analyses were carried out in relation to transients starting at nominal full power or at least, very close to full power. This paper develops a specific use of the Vandellòs-II plant model for operation and control support at low power involving new ranges of system actuation parameters. It also examines scenarios that are somewhat different from those typically analysed. The study starts showing the results of an assessment case, which is a start-up test and provides some additional qualification, and subsequently attempts to establish calculations to support both an improvement in feed water controls and to set up operating recommendations for low-load manual operation of feed water turbo-pump. Both results hopefully, will produce an outcome, which leads to an improvement in safety and reduces reactor trip probability.     

Air entrainment in fresh concrete with PFA

The results of a study into the influence of PFA on air entrainment in fresh concrete are discussed It is shown that the required dosage of AEA to produce an air content of 5.5 ± 0.5% in a PFA modified concrete mix is two-six times that required in the corresponding neat OPC concrete mix. The dosage of a vinsol based air entraining agent (AEA) required appears to be directly related to the PFA content of the mix. Similar direct relationships were obtained with a range of different PFAs. The dosage of an AEA based on the salt of a fatty acid appears to be sensitive to both PFA and OPC contents. For the type of PFA used, the variability of measured air content or the amount of air retained after continued agitation both indicated that vinsol based AEAs show the highest variability whilst fatty acid based AEAs show low variability. The between batch variability of air content was significantly improved by the addition of PFA regardless of the AEA used.     

The magnetic applications choice among ferrite ceramics,metallic strips,or metal powder cores

Iron-based metallic strip materials such as iron, silicon-iron, and amorphous metal are used for low frequency (50–60 Hz. line) power applications. Low-loss Nickel-based alloys as high permeability strip or insulated powder cores are the choices for stable, low-level higher frequency applications. Iron-based powder cores offer low cost as power supply filter chokes. Ceramic ferrites combine highest frequency operation with low cost and reduced component size as transformers and chokes in telecommunication and high frequency power supply applications.     

Action semantics-directed prototyping

We present a methodology for compiler synthesis based on Mosses-Watt's action semantics. Each action in action semantics notation is assigned specific “analysis functions”, such as a typing function and a binding-time function. When a language is given an action semantics, the typing and binding-time functions for the individual actions compose into typing and binding-time analyses for the language; these are implemented as the type checker and static semantics processor, respectively, in the synthesized compiler. Other analyses can be similarly formalized and implemented. We show a sample language semantics and its synthesized compiler, and we describe the compiler synthesizer that we have developed.     

基于激光多普勒测速法的2×106m/s2高冲击校准技术

在高冲击传感器动态性能校准中,实现高量程、宽脉冲激励是目前高冲击校准急需解决的问题。采用速度改变法校准原理,以气炮为激励源,利用激光多普勒测速方法测量砧体运动速度,建立高冲击校准系统。分析碰撞系统的作用原理,提出调整和控制激励脉宽的方法;分析测速误差,提出双光束差动侧向测速方法。实验结果表明:高冲击校准系统校准量程为2×106m/s2,激励脉宽在2×106m/s2时大于100μs,校准冲击灵敏度的扩展不确定度小于5%(k=2)。     

Advantages of high-field tokamaks for fusion reactor development

High-field designs could reduce the cost and complexity of tokamak reactors. Moreover, the certainty of achieving required plasma performance could be increased. Strong Ohmic heating could eliminate or significantly decrease auxiliary heating power requirements and high values of n_E could be obtained in modest-size plasmas. Other potential advantages are reactor operation at modest values of , capability of higher power density and wall loading, and possibility of operation with advanced fuel mixtures. Present experimental results and basic scaling relations imply that the parameterB ²a, where B is the magnetic field and a is the minor radius, may be of special importance. A superhigh-field compact ignition experiment with very high values ofB ²a (e.g.,B ²a=150 T² m) has the potential of Ohmically heating to ignition. This short-pulse device would use inertially cooled copper plate magnets. Compact engineering test reactor and/or experimental hybrid reactor designs would use steady-state, water-cooled copper magnets and provide long-pulse operation. Design concepts are also described for demonstration/commercial reactors. These devices could use high-field superconducting magnets with 7–10 T at the plasma axis.     

The need and prospects for improved fusion reactors

Conceptual fusion reactor studies over the past 10–15 yr have projected systems that may be too large, complex, and costly to be of commercial interest. One main direction for improved fusion reactors points toward smaller, higher-power-density approaches. First-order economic issues (i.e., unit direct cost and cost of electricity) are used to support the need for more compact fusion reactors. The results of a number of recent conceptual designs of reversed-field pinch, spheromak, and tokamak fusion reactors are summarized as examples of more compact approaches. While a focus has been placed on increasing the fusion-power-core mass power density beyond the minimum economic threshold of 100–200 kWe/tonne, other means by which the overall attractiveness of fusion as a long-term energy source are also addressed.Nomenclature a Plasma minor radius at outboard equatorial plane (m) - A Plasma aspect ratioR _T /a - AC Annual charges ($/yr) - b Plasma minor radius in vertical direction (m) - B Magentic field at plasma or blanket (T) - B _c Magnetic field at the coil (T) - B Toroidal magnetic field (T) - B Poloidal magnetic field (T) - BOP Balance of plant - C Coil - COE Cost of electricity (mills/kWeh) - CRFPR Compact RFP reactor - CT Compact torus (FRC or spheromak) - c _FPC Unit cost of fusion power core ($/kg) - DC Direct cost ($) - DZP Dense Z-pinch - E Escalation rate (1/yr) - EDC Escalation during construction ($) - ET Elongated tokamak - F Annual fuel charges ($/yr) - FC Component of UDC not strongly dependent or FPC size ($/kWe) - FW First wall - FPC Fusion power core - f _Aux Fraction of gross electric power recirculated to BOP - f ₁ (IC+IDC+EDC)/DC - f ₂ (O&M + SCR + F)/AC - IC Indirect cost ($) - IDC Interest during construction ($) - I _w Neutron first-wall loading (MW/m²) - i Toroidal plasma current (MA) - j Plasma current density, I/a² - k _B Boltzmann constant, 1.602(10)^–16 (J/keV) - LWR Light-water (fission) reactor - MPD Mass power density 1000P_E/M_FPC (kWe/tonne) - M _N Blanket energy multiplication of 14.1-MeV neutron energy - M _FPC Mass of fusion power core (tonne) - n Plasma density (m^–3) or toroidal MHD mode number - O&M Annual operating and maintenance cost ($/yr) - p _f Plant availability factor - PFD Poloidal field dominated (CTs, RFP, DZP) - P Construction time (yr) - P_TH Thermal power (MWt) - P _E Net electric power (1-)P _ET (MWe) - P_ET Total gross electric power (MWe) - p_f Fusion power (MW) - q Tokamak safety factor (B /B _gq )(a/R _T ) - q _e EngineeringQ value, 1/e - R _T Major toroidal radius (m) - RFP Reversed-field pinch - RPE Reactor plant equipment (Account 22) - S Shield - SCR Annual spare component cost ($/yr) - SSR Second stability region for the tokamak - S/T/H Stellarator/torsatron/heliotron - ST Spherical tokamak or spherical torus - T Plasma temperature (keV) - TDC Total direct cost ($) - TOC Total overnight cost ($) - UDC Unit direct cost,TDC/10 ³ P _E ($/kWe) - V _p Plasma volume (m³) - W _p Plasma energy (GJ) - W _B Magnetic field energy (GJ) - Magnetic utilization efficiency, 2nk_BT/(B ²/2₀) - ₀ Permeability of free space, 4(10)^–7 H/m - XE Plasma confinement efficiency, a²/4_E - _e Plasma energy confinement time - _p Overall plant efficiency, _TH(1-) - _TH Thermal conversion efficiency - _FPC AverageFPC mass density (tonne/m³) - Plasma vertical elongation factor,b/a - Thickness of allFPC engineering structure surround plasma (m) - Total recirculating power fraction, (P _ET-P _E)/P _ET, or inverse aspect ratioa/R _T This work was performed under the auspices of USDOE, Office of Fusion Energy.