Effects of a Nd—Fe—B magnetic filler on the crystallization of poly(phenylene sulfide)

The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002     

聚醚酰亚胺热焓松弛的分子量依赖关系

采用ＤＳＣ对不同分子量的聚醚酰亚胺的等温及动态热焓松弛行为进行了研究，并以ＫＷＷ方程对实验数据进行了非线性拟合。结果表明，分子量对热焓松弛的影响是由高分子端基引起自由体积的差异所致。不同分子量的聚醚酰亚胺分子具有不同数量的端基，淬冷时端基数目的差异将产生不同数量的过剩自由体积，从而影响松弛热焓及松弛速率、低分子量的聚醚酰亚胺松弛相对较快，且起始热焓高，松弛的表观活化能亦较小。     

Practical method for generation expansion planning based on dynamic programming

This paper presents an efficient method which provides the optimal generation mix and the optimal generation construction process. The approximation method in which the dynamic programming technique and gradient method are combined is applied to determine the optimal generation mix with hydropower generation technologies. The successive approximations dynamic programming (SADP) technique, which is very suitable for high-dimensional multistage decision process problems, is used for obtaining the optimal generation construction process. The effectiveness and feasibility of the developed technique are demonstrated on a practical power system model which has five types of generation technologies including a hydropower generation technology.     

非串行生产线的建模,分析及设计

本文利用等效工作站理论和工件流平衡原理，推导出非串行离散事件生产线可以等价于串联系统，并归结为装配和拆卸两条定理，解决了系统的建模、分析与设计问题。     

Development and simulation studies of an unsteady state biofilter model for the treatment of cyclic air emissions of an α‐pinene gas stream

This paper describes the development and simulation of an unsteady state biofilter model used to predict dynamic behaviour of cyclically‐operated biofilters and compares it with experimental results obtained from three, parallel, bench‐scale biofilters treating both periodically fluctuating concentrations and constant concentrations of an α‐pinene‐laden gas stream. The dynamic model, using kinetic parameters estimated from the constant concentration biofilter, was able to predict the performance of cyclic biofilters operating at short cycle periods (ie, in the order of minutes and hours). Steady state kinetic data from a constant concentration biofilter can be used to predict unsteady state biofilter operation. At a 24 h cycle period, the dynamic model compared well with experimental results. For long cycle periods (ie, hours and days), removal efficiency decreased after periods of non‐loading: the longer the period of non‐loading, the poorer the biofilter's performance at the re‐commencement of pollutant loading. At longer time scales the model did not effectively predict transient behaviour, as adsorption and changes in kinetic parameters were not accounted for. Modelling results showed that similar biofiltration performance for the cyclic and constant concentration biofiltration of α‐pinene is expected for biofilters operating solely in the first order kinetics regime. Poorer performance for cyclic biofilters following Monod kinetics spanning the entire kinetics range is expected as the cycle amplitude increases. The most important parameters affecting the performance of a cyclically‐operated biofilter with short cycle periods are: amplitude of cyclic fluctuations, C_{g, max}/C_g, relative value of the half‐saturation constant in the Monod expression, K_s, and effective diffusivity of α‐pinene in the biofilm, D_e. Copyright © 2005 Society of Chemical Industry     

Displacement Discontinuity Method for Fracture Mechanics Analysis of Reissner Plates: Static and Dynamic

This paper is concerned with the displacement discontinuity method applied to the shear deformable plates (Reissner’s and Mindlin’s theories) with cracks subjected to static and dynamic loads. Fundamental solutions of dislocation are derived using the Fourier transform method and the Laplace transformation technique. Boundary integral equations are presented in terms of rotations/displacement on the crack surfaces. The Chebyshev polynomials of the second kind are used to evaluate the integral equations with hypersingular kernels on the crack boundaries and determine the stress intensity factors at the crack tips. Comparisons are made with other numerical solutions to demonstrate the proposed method is accurate both for static and dynamic problems.     

准噶尔盆地腹部超压层分布研究

准噶尔盆地腹部普遍发育深层（大于4000m）超压系统，很多钻井都钻遇超压。通过对超压段钻井、地质、测井、地震特征系统研究发现，超压段泥浆密度大幅增加，具有高声波时差、低电阻率以及地震低速的超压响应特征。利用Dix公式计算地震层速度和利用Fillippone公式计算地层压力，得到超压数据体。准噶尔盆地腹部超压在白垩系及其以下沉积地层中均有分布，超压层的深度范围不同。分1井西凹陷边缘以及昌吉凹陷西南有空层现象。超压顶面分布的层位由北往南、从东到西逐渐变浅，从三叠系顶部到白垩系底部。深部超压对油气分布和富集有着重要的控制作用，准噶尔盆地腹部超压层分布的研究将对本区油气勘探起积极的推动作用。     

莱钢职业安全健康动态监控信息系统的建立及运行分析

以网络技术和信息技术为依托，建立职业安全健康动态监控信息系统，进行职业安全健康管理的监控和预警，提高安全管理的现代化水平。     

陕西南部路基病害分布特征及主要控制因素探讨

在统计分析的基础上,归纳总结了陕西南部各类路基病害的分布特征,并从自然因素和人为因素两个方面分析了各类路基病害发生的主要控制因素。     

1 000 t/d湿磨干烧生产线工艺特点和调试

湿法生产线的技术更新改造有异地新建新型干法生产线和原地改成湿磨干法生产线二种。浙江虎山集团(?)3.0 m×88.68 m湿法线的改造,经方案比较和生产原料的状况,采用了湿磨干烧方案。其中,料浆脱水采用了真空吸滤法,浇成系统采用了南京院专有技术。改造投产后,获得了优质、高产、低耗和安全生产的技改效果。