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Let us consider n data measurements of a univariate process that have been altered by random errors. We assume that an underlying model function has a substantially smaller number of turning points than the observed ones. We propose algorithms that make least the sum of the moduli of the errors by requiring k monotonic sections, alternately increasing and decreasing, in the sequence of the smoothed values. The main difficulty in this calculation is that the optimal positions of the joins of the monotonic sections have to be found automatically among so many combinations that it is impossible to test each one separately. Moreover, the calculation seems to be very intractable to general optimization techniques because O(nk ) local minima can occur. It is shown that dynamic programming can be used for separating the data into optimal disjoint sections of adjacent data, where each section requires a single L1 monotonic calculation. This procedure is highly efficient, requiring at most O(kn2 ) computer operations and O(n) best L1 monotonic calculations to subranges of data for a global minimum. 相似文献
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The crystallization of poly(phenylene sulfide) (PPS) in a polymer–magnetic Nd—Fe—B powder suspension was studied. Isothermal crystallization behavior was analyzed by way of differential scanning calorimetry, and the kinetics were described via the Avrami equation. The Avrami parameters and the crystallization times were strongly affected by both the particle size and the presence of a coupling agent coated on the filler particles. The small Nd—Fe—B particles exhibited long induction and half‐times, whereas the large particles tended to have short crystallization times. Particles ranging from 38 to 150 μ appeared to have similar crystallization times and to have no significant change in the value of Avrami index with melt crystallization temperature. As a result of these analyses, the dynamic mechanical properties were determined to correlate the fundamental polymer crystallization characteristics and the physical properties of the PPS binder. The enhancement of the wetting of the filler to the binder was promoted through the coupling agent, as confirmed by dynamic mechanical testing performed on the samples. The storage modulus typically decreased because of the presence of the uncoated small particles. Conversely, the loss modulus was enhanced because of the presence of the coated small particles in the PPS binder. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1091–1102, 2002 相似文献
127.
陈小余 《中国计量学院学报》1997,(2)
用相干态的方法得到旋转磁场中自旋为j的粒子的态矢量的严格表达式,由此可计算相干态和叠加相干态的Abaronov-Anandan相位(AA相让).并具有清楚的物理图象. 相似文献
128.
简并量子拍频三能级系统中的光场压缩效应 总被引:10,自引:1,他引:9
本文讨论了V-型简并量子拍频三能级原子与单模相干辐射场相互作用时的动力学行为,并研究了光场的压缩效应。 相似文献
129.
采用DSC对不同分子量的聚醚酰亚胺的等温及动态热焓松弛行为进行了研究,并以KWW方程对实验数据进行了非线性拟合。结果表明,分子量对热焓松弛的影响是由高分子端基引起自由体积的差异所致。不同分子量的聚醚酰亚胺分子具有不同数量的端基,淬冷时端基数目的差异将产生不同数量的过剩自由体积,从而影响松弛热焓及松弛速率、低分子量的聚醚酰亚胺松弛相对较快,且起始热焓高,松弛的表观活化能亦较小。 相似文献
130.
An equation of state for 1,1-difluoroethane (HFC 152a, CH3CHF2) has been developed on the basis of reliable experimental data including PVT, liquid Cp, and saturated-liquid-density data measured by our group. It is a non-dimensionalized virial equation whose functional form is the same as that originally developed for 1,1,1,2-tetrafluoroethane (HFC 134a) in our group. The effective range is for pressures up to 15 MPa, temperatures from 230 to 450 K, and densities to 1000 kg m−3. The equation represents reliable PVT measurements within ± 1% in pressure for the superheated vapour and supercritical fluid, while within ±0.5% in density for the compressed liquid. In addition, it should be noted that the equation represents the other essential thermodynamic properties including vapour pressures, saturated-liquid/ vapour densities, isobaric/isochoric specific heats and sound velocity in both the liquid and gaseous phase of HFC 152a. 相似文献