An Analytical Equation of State for Alkaline Earth Metals

In this work, an analytical equation of state based on statistical mechanical perturbation theory, which was initially developed for normal fluids and can be applied to predict the P–V–T data for saturated liquid alkaline earth metals, is presented. The equation of state is that of Ihm, Song, and Mason, and the temperature-dependent parameters of the equation of state are calculated from a corresponding-states correlation as functions of the reduced temperature. Two scaling constants are sufficient for this purpose, the surface tension and the liquid density at the melting point. The equation of state is used to predict the saturated liquid density of molten alkaline earth metals from the melting point up to 2000 K, for which experimental data exist, within an accuracy of 5%.     

Lanthanum Containing Polymer''s Modification to PP

Polypropylene (PP)'s low impact strength limits its usages. Adding some a rare earth polymer can enhance PP's tensile strength and impact strength. Acrylic lanthanum was prepared by the reaction between lanthanum oxide and acrylic acid. The IR spectrum prove that and optimum reacting conditions are that the bulk ratio of La(AA) 3 and MMA is not less than one and temperature is about 80 ℃. Lanthanum containing Polymer were added into PP. When percent of addition only was 3%, strength were enhanced 10% , and impact strength 40%. SEM shows the compatibility of rare earth polymer and PP; lanthanum containing polymer can form physical crosslinking between PP's molecules, then every particle's surface connect with several PP molecules and the PP mechanical property were enhanced.     

Molecular dynamics studies of atomic-scale tribological characteristics for different sliding systems

A slider-slab sliding model for hard-to-soft and soft-to-soft sliding systems with abrasive and non-abrasive wear conditions is used to investigate atomic-scale friction. The molecular dynamics simulation uses the Morse potential to calculate interatomic forces between atoms. Separation distance between the slider and the slab is changed to simulate repulsive and attractive interactive force fields exerted on interface between two sliding components. Effects of the interaction potential parameters on the sliding friction are investigated. The relationship of frictional force, normal force and temperature rise of the slider and the slab during sliding are established. Comparison of the hard-to-soft and the soft-to-soft sliding system are carried out and shows different tribological phenomena.     

氯化稀土与丙氨酸固体配合物的研究

LnCl_3·nH_2O和丙氨酸在水相介质中按物质的量比为1∶1和1∶3混合,制得6个新的氯化稀土与丙氨酸的配合物,通式为LnCl_3·L·6H_2O和LnCl_3·3L·nH_2O(Ln为Nd,Dy,Yb;L为丙氨酸)。通过化学分析、元素分析、红外光谱、热重分析及X光粉末衍射等方法对这些配合物进行了物理化学性质及结构表征。     

龙南稀土矿区周边水体污染特征及风险评价

为研究龙南稀土矿区地表水和地下水污染物迁移规律及污染成因机制,开展了矿区周边地表水、地下水水质现状监测工作,对研究区周边地表水、地下水中pH、硫酸盐、硝酸盐、亚硝酸盐、氨氮浓度进行分析测定,运用改进内梅罗综合污染指数法和健康风险评价模型对水体污染程度及不同年龄段人群健康风险进行评估。结果表明,地表水料坑处的综合污染指数最高,达到54.19,属于严重污染程度;关西翰岗桥处综合污染指数最低,仅为2.119,属于较清洁程度;料坑、黄沙河和临塘一处理站下游的综合污染指数均达到严重污染程度;地下水采样点综合污染指数均达标,水质清洁。健康风险评价结果表明,研究区地表水及地下水中的硝酸盐对人体造成的健康风险较大,亚硝酸盐与氨氮次之;经非致癌健康风险计算,饮用地下水和地表水对不同年龄人群的影响程度为幼儿＞青年＞成人,因此应对龙南稀土矿区周边0~6岁幼儿用水安全给予更多关注。     

Synthesis and Properties of Rare Earth Complexes with 3-Ferrocenyl-5-Phenyl-Pyrazoline-1-Dithiocarbamate

Sodium 3-ferrocenyl-5-phenyl-pyrazoline-1-dithiocarbamate (FPPD) reacts with anhydrousrare earth chlorides in absolute ethanol to give 14 new complexes.The results of elemental analysis show thatthe compositions of the complexes are RE(FPPD)_3·nH_2O(RE=La,Pr～Lu and Y;n=3).The ligand andits complexes have been characterized by infrared spectroscopy,UV-visible absorptionspectroscopy,~1H-NMR spectra,thermal analysis and molar conductivity measurement.     

稀土多元复合肥对甜菜增产增糖效应研究

利用稀土多元复合肥对甜菜进行施肥，不仅大幅度提高了产量，而且提高了甜菜含糖量，其经济效益十分可观。不论采取叶面施肥还是拌种均能获得稳定的增产增糖效果。     

离子液体浮选分离模拟乏燃料中的稀土元素

从乏燃料中高效分离稀土元素（中子毒物）是实现乏燃料再生循环利用的关键步骤。利用双有机相离子液体选择性浮选分离乏燃料中的稀土元素,使氧化铀和稀土氧化物几乎不被溶解,实现两者固相之间的分离,避免了二次废液的产生,具有节能和环保的双重意义。以2-乙基己基膦酸单-2-乙基己基酯（P507）为稀土元素的捕收剂、煤油或油酸为稀释剂,以1-丁基-3-甲基咪唑六氟磷酸盐（［C₄mim］［PF₆］）和1-丁基-3-甲基咪唑双三氟甲烷磺酰亚胺盐（［C₄mim］［Tf₂N］）两种离子液体作为浮选体系的另一相,优化得到了浮选分离稀土氧化物的最佳条件。结果发现：浮选分离去除率随着混合物中初始Nd含量以及浮选次数的增加而增加。另外,对所有稀土元素与U₃O₈分别组成的二元体系混合物进行了浮选分离研究,发现在相同条件下,该体系对不同稀土元素的分离也不同,浮选分离的去除率与稀土氧化物的密度有一定的相关性。在此基础上,利用浮选机开展了工艺化的初步探索,发现该浮选体系对Nd的去除率可达80%以上。     

不同介质环境条件下黏性土的分散性及其微观结构

采用碎块试验、双比重计试验、电动电位、扫描电镜等测试方法,对典型的分散性土和非分散性土在不同介质环境条件下的分散性及其微观结构特征进行了研究.研究表明,介质环境中的钠离子含量和pH值高低是决定土体是否产生分散的本质因素,两种因素缺一不可.如果土体中含有大量的钠离子,并且酸碱度呈强碱性,则土体具有分散性.通过掺加高价阳离子和酸性物质,降低土体中钠离子的相对含量和酸碱度,可对分散性土进行改良.在自然沉积条件下,分散性土的微观结构中含有较多的孔隙;而非分散性土比较密实,孔隙较少.     

直流接地引起断路器跳闸的原因分析及对策

通过对几种可能引起断路器跳闸的直流系统一点接地的详细分析 ,提出了行之有效的解决方法和对策。