应用变频器技术实现SO2风机节能改造

铜目前,硫酸车间制酸一系列共有三台SO2风机,这三台风机均采用液力耦合器的调速方式,这种方式可以实现无极调速,但是存在着传动效率低,耗能大的缺点,并且这三台风机均已使用20年以上,处于设备的中晚期,工作效率已大大降低。目前行业内,均采用先进的变频调速方式。使用变频器来控制风机的转速,可以极大的节省电能,尤其是在低负荷情况下,可以实现低转速运转,大大提高硫酸系统的综合能耗指标。     

汽蚀对离心泵性能影响的实验研究

离心泵长时间运转后,会出现危害严重的汽蚀现象,造成泵性能下降,严重时影响泵的效率、寿命,甚至造成离心泵内部部件损坏。文章通过改变进口压力的方法对单泵、双泵并联、双泵串联等工况下汽蚀对离心泵性能影响进行实验研究。结果表明:当进口压力小于输送液体的饱和蒸汽压时,液体开始发生气化并伴随气泡产生,表明泵内发生汽蚀;汽蚀初期离心泵的效率开始下降,但表现不明显;随着汽蚀不断增大至严重汽蚀区时,Q 1~η曲线出现陡坡,效率出现明显下降并伴随嗡响。实验证明采用提高泵的进口压力等措施可适当减小汽蚀对泵性能的不利影响。     

Numerical modeling of hydrogen catalytic reactions over a circular bluff body

This paper was intended to delineate numerical research for hydrogen catalytic combustion over a circular cylinder. The wire/rod-type catalytic reactor is a simple geometry reactor with an economical design with less pressure loss. For the single rod in the reaction channel, the flow characteristic and the difference of conversion efficiency between non-gas-phase reaction and gas-phase reaction have been delineated in the present study. The flow field and the chemical reactions were numerically modeled using 2D Large Eddy Simulation combined with the gas-phase and surface reaction mechanisms. The results show that the current numerical simulation has been validated to precisely predict the vortex shedding and its frequency in the cold flows. Despite the variation trends being dominated by the upstream flow, the vortex shedding phenomena were affected by the flue gas generated from the rod surface. It can be seen from the linear relationship between the vortex shedding frequency of reacting flow and Reynolds Number. It is noted that the vortex shedding vanished if the gas-phase reaction was ignited in the reaction channel. In addition, the geometric modified conversion efficiency was proposed to delineate an indicator that could be potential for the optimization of rod-type catalytic reactor. In summary, the fundamental study of a rod in a 2D flow channel can provide information for optimizing the catalytic design or the rod array arrangement in the reactor. Moreover, the rod can also be a partial catalytic flame holder to ignite and stabilize the gas-phase reaction. The obtained results could be the potential for practical applications of rod-type catalytic combustion, catalytic gas turbine, hydrogen generation, partially catalytic reaction flame holder, and other catalytic reactions that can be appreciated.     

Biodegradation of Ammonia Nitrogen Using a Novel Candida sp. Strain N6 Immobilization

固定化假丝酵母菌株N6降解氨氮的研究

王 凯^1,2，孙亚文¹，李斯琪¹，张瑛洁¹，程喜全¹，马 军²

（1. 哈尔滨工业大学(威海)， 海洋科学与技术学院，山东 威海 264209；

2. 哈尔滨工业大学 市政与环境工程学院，哈尔滨 150090）

创新点说明：

发现一株假丝酵母菌株，具有较高的氨氮降解能力，采用固定化技术，将其固定化后用于模拟生活污水的处理效果仍然显著，表明将该菌固定化后具有较高的应用价值。

研究目的：

将高氨氮处理效率的菌株N6固定化，以期通过固定化的形式将其应用于废水处理中。

研究方法：

从山东威海金海湾排污口分离出一株假丝酵母菌，该菌株具有较高的氨氮处理效率。采用包埋固定化技术将N6固定，考察了固定化N6的氨氮降解能力以及稳定性，通过单因素以及正交试验确定了固定化材料以及最佳固定化条件。利用SBR反应器探究固定化N6的应用情况。

研究结果：

1）当固定化材料PVA, SA, CaCl2的浓度分别为9%, 1.5%, 2%时最适合N6固定化，在此条件下，固定化N6的氨氮去除率达到了97.97%。

2）稳定性测试表明固定化N6具有很强的稳定性，固定化小球在测试条件下未出现破碎现象。

3）固定化N6的最佳固定化条件为：固定化24h，N6接种量3%，pH 8。

4） 固定化N6在SBR反应器中表现出非常好的氨氮降解能力，去除率稳定在95%-99%。

5）在固定化N6的应用过程中，最适添加量为15%。

结论：

固定化高效菌株用于废水处理具有广阔的前景。高氨氮处理效率的假丝酵母N6固定化后氨氮降解能力仍然较强。固定化N6具有潜在的应用价值，将固定化N6应用到SBR中，具有较高且稳定的氨氮去除率。

关键词：氨氮废水；固定化；假丝酵母菌属；脱氮效率

     

Yeast and enzymatic hydrolysis in converting Chlorella biomass into hydrogen gas by Rhodobacter sp. and Rhodopseudomonas palustris

Enhanced hydrogen evolution was pursued in this work. Rhodobacter sp. (Rb) and Rhodopseudomonas palustris (Rp), single or mixed were used to extract hydrogen molecules from Chlorella fusca biomass. To elevate their fermentable contents, Chlorella was grown at nitrogen and/or phosphorus deprivation. Besides, cellulase and/or macerozyme, Triton X100 or sonicated yeast were applied for further biohydrogen fermentation. Utilizing hydrolysates of mineral deprived Chlorella cultures, Rb exhibited relatively higher cumulative hydrogen (4200 ml L^?1) than Rp (2500 ml L^?1) while mixed cultures attained significantly higher levels (4700 ml L^?1). Triton or enzymes significantly enhanced hydrogen evolution, with more effectiveness of macerozyme than cellulase. A novel use of sonicated yeast, as enzymes pool, induced the highest significant collective H₂ (up to 47 times that of microalgal supernatant). Sonicated yeast induced a remarkable hydrolysis of algae, as inferred from increased reducing sugars. However, hydrogen evolution efficiency exhibited poor proportionality with reducing sugars, indicating fermentation of other metabolites.     

Comparative study to use nanofluid ZnO and CuO with phase change material in photovoltaic thermal system

In this study, the simultaneous use of nanofluid and phase changing material as a coolant for photovoltaic fluid collector system and its effects are investigated experimentally. Two types of nanofluid are taken for the consideration, that is, ZnO and CuO, which are water‐based fluid. The experiments are performed in five different types of photovoltaic thermal system conventional: PT, PVT (ZnO), PVT (CuO), PCM medium (PVT/PCM/ZnO), and PCM medium (PVT/PCM/CuO). The results are obtained for surface temperature, energy, and thermal efficiency, and it is compared with each other. Further, the effect of the nanofluid as the effective alternative for pure deionized water is measured. From the results, it is evident that the PVT/PCM/CuO system minted 15% high electric output compared with convention module. Furthermore, the addition of the CuO nanofluid increases the thermal output significantly up to 8% for PVT and 12% for PCM without energy consumption. It also found that the nanofluid increases the overall energy efficiency of the system compared with convention PV.     

Experimental analysis of the influence of the voltage waveform on ozone generation efficiency

Although the dielectric barrier discharge (DBD) has been widely considered and studied for ozone generation, only a few studies have examined the influence of the alternating voltage waveform on the ozone rate production. This paper analyses the influence of the voltage shape on the ozone concentration and the energy efficiency of a DBD cylindrical ozone generator. Three voltage signals were studied using a high-voltage amplifier: sinusoidal, triangular and rectangular signals with voltage values up to 8 kV and frequencies up to 1.1 kHz. The obtained results showed that the efficiency of the ozone generator depends strongly on the type of the voltage waveform. The maximum values of the energy efficiency and the ozone concentration were obtained with the triangular voltage signal. This wave shape configuration has been successfully used for discolouration of water contaminated by textile dye.     

Comparative analysis of the infield response of five types of photovoltaic modules

Five types of photovoltaic (PV) modules were comparatively analyzed considering the electrical output, efficiency and relative loss in efficiency, based on infield data collected in a temperate mountain climate, over 14 months. The mono-, poly-crystalline silicon, CdTe, CIS and CIGS modules were mounted on two identical platforms, installed close to a row of buildings. Based on the data collected from individual or groups of modules on the two platforms, analyses focused on the photovoltaic output, considering: the mean monthly values; the influence of the neighboring buildings; the influence of the irradiance, temperature and wind in different seasons (winter, summer); the influence of tracking on each PV module type. The qualitative analysis shows that small PV platforms installed in the built environment require accurate investigations on the air currents with influence on snow and frost retention/melting and water vapor condensation. In the temperate climate, with snowy winters and rather warm summers, the best performing modules are of poly-crystalline silicon; among thin film modules, the best output corresponds to CIGS, while the steadiest efficiency corresponds to CdTe. Tracking has a “leveling” effect on the conversion efficiency, making the PV output more predictable during days with preponderant direct solar irradiance.     

基于变效率压气机的AA-CAES变工况性能分析

先进绝热压缩空气储能系统(advanced adiabatic compressed air energy storage system,AA-CAES)是一种清洁、环保的大规模储能技术,能够为可再生能源并网及电网调峰提供新的解决方案。为了深入研究压气机模型对变工况下AA-CAES系统运行性能的影响,本文在传统模型的基础上添加了压气机效率模型。求解系统模型发现:相对于储气室最高压比,换热器效能对储能效率的影响较大,换热器效能每提高0.05,储能效率平均提高2.9%;随着储气室最高压比的上升,储能密度近似呈线性增加;AA-CAES系统在储能阶段,稳定运行的前两级压气机功率保持不变,非稳定运行的第3级压气机功率随储气室压比的升高而逐渐增大,储能阶段结束时第3级压气机耗功最多。     

磷酸铁锂电池储存性能研究

评估了一种高功率的磷酸铁锂电池在长时间满荷电储存以后的电性能,认为其具有良好的满荷电储存性能,可用于长期储存型锂电池组的开发设计。