方波激励下纳米晶体铁心损耗模型建立与验证

为了实现电力机车小型化轻量化的发展要求,国内外专家考虑通过采用提高变压器的工作频率减小变压器整体的体积和质量。铁心作为高频变压器的关键部件,可以准确计算铁心损耗,对中高频变压器的设计和优化具有重要作用。针对高频变压器铁心通常是工作在方波或脉宽调制(PWM)波等非正弦激励下的特点,对传统Steinmetz损耗计算模型进行了优化改进,给出了考虑磁密的变化率及波形系数对损耗的影响的Steinmetz改进损耗模型。同时,为了提高损耗模型在不同特征频率下的通用性,进一步对损耗模型系数的非线性进行研究,给出了模型系数随频率变化的非线性函数。最后,利用有限元计算结果同实物测量结果进行比较,证明了所提损耗模型在方波激励下对纳米晶体铁心计算的准确性。     

多级结构MoS2/C复合材料的储锂性能

利用二硫化钼和葡萄糖为原料,采用一锅乙醇/水复合溶剂热-后热处理法制备了绣球花状结构MoS₂/C复合材料。考查了乙醇/水复合溶剂的合理组成和MoS₂/C复合材料中碳的合理含量,分别采用SEM和TEM表征了MoS₂/C材料的形貌结构,通过TGA测试和计算了材料中的碳含量。采用循环伏安、恒流充放电和交流阻抗等测试了MoS₂/C复合电极的电化学性能。结果表明,MoS₂/C复合材料拥有多级花球状结构,缓解了MoS₂的团聚,使电极材料的利用率和电化学稳定性显著提高。当V（乙醇）：V（水）为1：2,碳含量为50%时,MoS₂/C复合电极在200 mA·g^-1的电流密度下,充放电循环100次后,可逆容量达到762 mA·h·g^-1。     

The dynamic evolution of aggregated lithium dendrites in lithium metal batteries

Lithium (Li) metal anodes promise an ultrahigh theoretical energy density and low redox potential,thus being the critical energy material for next-generation batteries.Unfortunately,the formation of Li den-drites in Li metal anodes remarkably hinders the practical applications of Li metal anodes.Herein,the dynamic evolution of discrete Li dendrites and aggregated Li dendrites with increasing current densities is visualized by in-situ optical microscopy in conjunction with ex-situ scanning electron microscopy.As revealed by the phase field simulations,the formation of aggregated Li dendrites under high current den-sity is attributed to the locally concentrated electric field rather than the depletion of Li ions.More specif-ically,the locally concentrated electric field stems from the spatial inhomogeneity on the Li metal surface and will be further enhanced with increasing current densities.Adjusting the above two factors with the help of the constructed phase field model is able to regulate the electrodeposited morphology from aggregated Li dendrites to discrete Li dendrites,and ultimately columnar Li morphology.The methodol-ogy and mechanistic understanding established herein give a significant step toward the practical appli-cations of Li metal anodes.     

Technology for recycling and regenerating graphite from spent lithium-ion batteries

With the annual increase in the amount of lithium-ion batteries (LIBs), the development of spent LIBs recycling technology has gradually attracted attention. Graphite is one of the most critical materials for LIBs, which is listed as a key energy source by many developed countries. However, it was neglected in spent LIBs recycling, leading to pollution of the environment and waste of resources. In this paper, the latest research progress for recycling of graphite from spent LIBs was summarized. Especially, the processes of pretreatment, graphite enrichment and purification, and materials regeneration for graphite recovery are introduced in details. Finally, the problems and opportunities of graphite recycling are raised.     

A panoramic view of Li7P3S11 solid electrolytes synthesis,structural aspects and practical challenges for all-solid-state lithium batteries

The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.     

基于混合型Chopper电路的MMC-UPFC故障渡越方案

当交流系统发生短路时,基于模块化多电平控制器的统一潮流控制器(MMC-UPFC)串、并联侧MMC均会受到故障冲击,存在两侧换流器过流闭锁,MMC-UPFC完全退出运行的风险.对此,以交流系统发生最严重的三相短路故障为例,分析了MMC-UPFC串、并联侧MMC故障特性;在此基础上,借鉴风电场交流故障渡越的Chopper电路,并结合MMC-UPFC不同运行方式对故障特性的影响,提出了基于混合型Chopper电路的MMC-UPFC故障渡越方案.该方案能够在交流系统发生故障后隔离并联侧MMC与串联侧MMC之间的联系,从而抑制串联侧馈入并联侧MMC的故障电流.仿真结果表明在MMC-UPFC的不同运行方式下,所提方案均能避免故障后并联侧MMC闭锁,MMC-UPFC将切换至静止同步补偿器(STATCOM)工作模式,为交流系统提供无功功率支撑.     

孤岛微电网逆变器不平衡负载下的控制策略

提出一种孤岛微电网逆变器在不平衡负载下的控制策略,采用分序网络解耦控制,在虚拟同步发电机(VSG)控制的基础上引入自适应负序补偿环.对三相负载不平衡下的电路进行分析,得到逆变器分序网络等效电路和逆变器间负序环流产生机理.通过分序网络解耦控制得到电压环参考电压各序分量,引入分序网络虚拟阻抗改进逆变器各序输出阻抗.正序网络采用VSG控制实现正序调频调压和电流的自主分配,负序网络加入负序补偿环抑制微电网三相电压负序分量.详细分析了微电网电压负序分量与负序补偿系数和逆变器输出电流负序分量的关系.负序补偿环采用自适应控制,在实现微电网三相电压平衡的同时根据逆变器额定容量自主分配输出电流负序分量.建模仿真结果验证了所提控制策略的有效性.     

基于长短期记忆网络的电网故障区域定位与故障传播路径推理

为了在发生故障后维持电力系统的安全稳定,有必要实现对故障区域的快速定位并确定故障冲击的传播路径,提出基于长短期记忆网络(LSTM)的故障区域定位和故障传播路径推理方法.首先,利用LSTM建立2个故障诊断模型分别实现在线检测故障时刻和确定故障区域;然后,通过计算故障点附近线路的端口供给能量确定故障冲击的传播路径;最后,以8机36节点电网为例进行算例验证,结果表明所提模型可在发生故障后短时间内检测到故障,给出故障区域和故障冲击传播的路径,且对噪声有较强的鲁棒性.     

准均匀电场下C5F10O/干燥空气与C5F10O/N2的绝缘特性

SF_6因优异的电气特性广泛应用于电器绝缘设备中,但其产生的温室效应对大气环境具有极大损害。近年来,C_5F_(10)O作为一种环保型SF_6潜在替代气体受到国内外科研工作者的关注。为进一步探究C_5F_(10)O/干燥空气与C_5F_(10)O/N_2的绝缘特性,文中利用气体绝缘性能测试平台,对不同气压、不同C_5F_(10)O分压下的2种混合气体在准均匀电场下进行工频击穿试验。实验结果表明,C_5F_(10)O混合气体绝缘强度随气体压强的增大而增大;提高C_5F_(10)O分压亦可提高两类缓冲气体的绝缘强度,且对N_2绝缘强度提升相对值大于干燥空气。从绝缘强度考虑,适当增大C_5F_(10)O混合气体气压和C_5F_(10)O分压,C_5F_(10)O/干燥空气比C_5F_(10)O/N_2混合气体更具潜力替代室内中低压设备中的SF_6。     

Room-Temperature Solid-State Lithium Metal Batteries Using Metal Organic Framework Composited Comb-Like Methoxy Poly(ethylene glycol) Acrylate Solid Polymer Electrolytes

Solid polymer electrolyte with good thermal stability and flexibility is an excellent candidate for solid-state lithium metal batteries, while its low ionic conductivity caused by high crystallinity limits its application at ambient temperature. Here a metal organic framework (zeolitic imidazolate framework-8, ZIF-8) composited comb-like methoxy poly(ethylene glycol) acrylate polymer electrolyte (MCPE) with high ionic conductivity (9.96 × 10⁻⁵ S cm⁻¹ at 30 °C) is prepared by an in situ UV polymerization method. The as-prepared MCPE exhibits improved mechanical property due to the introduction of porous ZIF-8 nanofillers, which is beneficial to suppress the growth of lithium dendrites. Consequently, the LiFePO₄||MCPE||Li cells show a high capacity of 116 mAh g⁻¹ at 30 °C and 0.5 C, and maintain 89.4% of initial capacity after 150 cycles with the average Coulombic efficiency of 99.9%. These results demonstrate that the MCPE shows great potential in solid-state lithium metal batteries near room temperature.