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21.
The polymer electrolyte based solid-state lithium metal batteries are the promising candidate for the high-energy electrochemical energy storage with high safety and stability. Moreover, the intrinsic properties of polymer electrolytes and interface contact between electrolyte and electrodes have played critical roles for determining the comprehensive performances of solid-state lithium metal batteries. In this review, the development of polymer electrolytes with the design strategies by functional units adjustments are firstly discussed. Then the interfaces between polymer electrolyte and cathode/anode, including the interface issues, remedy strategies for stabilizing the interface contact and reducing resistances, and the in-situ polymerization method for enhancing the compatibilities and assembling the batteries with favorable performances, have been introduced. Lastly, the perspectives on developing polymer electrolytes by functional units adjustment, and improving interface contact and stability by effective strategies for solid-state lithium metal batteries have been provided. 相似文献
22.
Qiang Wang Lei Shen Tong Xue Gao Cheng Cheng Zhi Huang Hong Jin Fan Yuan Ping Feng 《Advanced functional materials》2021,31(2):2002187
The {100} facet of single-crystalline TiO2(B) is an ideal platform for inserting Li ions, but it is hard to be obtained due to its high surface energy. Here, the single-crystalline TiO2(B) nanobelts from H2Ti3O7 with nearly 70% {100} facets exposed are synthesized, which significantly enhances Li-storage capacity. The first-principle calculations demonstrate an ab in-plane 2D diffusion through the exposed {100} facets. As a consequence, the nanobelts can significantly accommodate Li ions in LiTiO2 formula with specific capacity up to 335 mAh g−1, which is in good agreement with the electrochemical characterizations. Coating with conductive and protective poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), the cut-off discharge voltage is as low as 0.5 V, leading to a capacity of 160.7 mAh g−1 after 1500 cycles with a retention rate of 66% at 1C. This work provides a practical strategy to increase the Li-ion capacity and cycle stability by tailoring the crystal orientation and nanostructures. 相似文献
23.
Changwei Dun Guoxi Xi Ye Zhang Tingting Zhao Yumin Liu Xiaoying Heng Lu Yao 《Ceramics International》2018,44(17):20984-20991
In this study, we investigated the effects of substituting Li+ for Co2+ at the B sites of the spinel lattice on the structural, magnetic and magnetostrictive properties of cobalt ferrites. The Li+ substituted cobalt ferrites, Co1-xLixFe2O4, with x varying from 0 to 0.7 in 0.1 increments, were synthesized with a sol-gel auto-combustion method using the cathode materials of spent Li-ion batteries. X-ray diffraction analysis revealed that all the Co1-xLixFe2O4 nanopowders had a single-phase spinel structure and the lattice parameters decreased with increasing Li+ content, which can be proved by slight shifts towards higher diffraction angle values of the (311) peak. Field emission scanning electron microscopy was used to observe the fractured inner surface of the sintered cylindrical rods and the increased porosity resulted in a decreased magnetostriction. The oxidation states of Co and Fe in the cobalt ferrite samples were examined by X-ray photoelectron spectroscopy. High resolution transmission electron microscopy micrographs showed that most particles were roughly spherical and with sizes of 25–35?nm. Li+ substitution had a strong effect on the saturation magnetization and coercivity, which were characterized with a vibrating sample magnetometer. The Curie temperature was reduced due to the decrease in magnetic cations and the weakening of the exchange interactions. The magnetostrictive properties were influenced by the incorporation of Li+ at the B sites of the spinel structure and correlated with the changes in porosity, magnetocrystalline anisotropy and the cation distribution. 相似文献
24.
In this article, we study a linear array of bowtie nanoantennas placed between two metallic strips that can work from 800 to 1420 nm (600 nm linewidth), with an electric field enhancement factor close to 20. We study the dynamical change of the position of the electric field enhancement amongst different elements in the array and, at the same time, the effects of dispersion on the scalability of the array elements. A systematic analysis and methodology to produce an array that can operate over a large bandwidth whilst maintaining the electric field enhancement without significant variation is provided. 相似文献
25.
简述了电动助力转向系统的研究现状及其基本结构、工作原理和主要特点。分析了该系统的主要元件,论述了亥系统的发展趋势。 相似文献
26.
提高电脱盐效果的措施 总被引:1,自引:0,他引:1
中国石油天然气股份有限公司庆阳石化分公司常压蒸馏装置一、二期技术改造结束后,装置加工能力由0.5 Mt/a增加到1.0 Mt/a,最高时达到1.3 Mt/a。但电脱盐装置脱后原油中盐的质量浓度一直在4.0-5.0 mgNaCL/L居高不下。为了降低脱后原油中盐的质量浓度,提高催化裂化装置催化剂活性,对电脱盐装置进行了技术改造,优化了操作参数,这到了脱后原油中盐的质量浓度小于3 mg- NaCl/L的预期效果,取得了较好的经济效益。 相似文献
27.
28.
MPTA型原油脱金属剂的工业应用 总被引:2,自引:2,他引:0
在对高金属含量原油进行初步评价的基础上,利用SH—Ⅰ型电脱盐试验仪对自主开发的MPTA型原油脱金属剂进行了原油脱金属的实验室研究。结果表明,当MPTA型脱金属剂加入量为250μg/g时,钙的脱除率可达97.4%,并且对其它金属元素,如镍、铁、钠、锰、铝和钒也有明显的脱除效果。该剂在山东恒源石油化工股份有限公司重交沥青车间500kt/a的电脱盐装置上进行原油脱金属工业试验的结果表明,经过二级电脱盐处理后,钙的脱除率达到99.1%,钠的脱除率为94.6%,铁的脱除率为82.9%,并可在一定程度上降低原油中镍和铜的含量。使用MPTA型原油脱金属剂显著降低了一、二级电脱盐装置的电场电流,有利于炼油厂的节能降耗。 相似文献
29.
通过分析数字集成芯片多输出中电源电压瞬间下降的原因,对常规驱动电路结构进行改进。改进后单输出电路的峰值电流降为原来的2/3,再通过优化版图的电源布线,能有效防止电源电压下降,使芯片正常稳定地工作。 相似文献
30.