Advances and perspectives on one-dimensional nanostructure electrode materials for potassium-ion batteries

Potassium-ion batteries (PIBs) have aroused considerable interest as a promising next-generation advanced large-scale energy storage system due to the abundant potassium resources and high safety. However, the K⁺ with large ionic radius brings restricted diffusion kinetics and severe volume expansion in electrode materials, resulting in inferior actual rate characteristics and rapid capacity fading. Designing electrode materials with one-dimensional (1D) nanostructure can effectively enhance various electrochemical properties due to the well-guided electron transfer pathways, short ionic diffusion channels and high specific surface areas. In this review, we summarize the recent research progress and achievements of 1D nanostructure electrode materials in PIBs, especially focusing on the development and application of cathode and anode materials. The nanostructure, synthetic methods, electrochemical performances and structure-performance correlation are discussed in detail. The advanced characterizations on the reaction mechanisms of 1D nanostructure electrode materials in PIBs are briefly summarized. Furthermore, the main future research directions of 1D nanostructure electrode materials are also predicted, hoping to accelerate their development into the practical PIBs market.     

Mass-Producible,Quasi-Zero-Strain,Lattice-Water-Rich Inorganic Open-Frameworks for Ultrafast-Charging and Long-Cycling Zinc-Ion Batteries

Low-cost and high-safety aqueous Zn-ion batteries are an exceptionally compelling technology for grid-scale energy storage. However, their development has been plagued by the lack of stable cathode materials allowing fast Zn²⁺-ion insertion and scalable synthesis. Here, a lattice-water-rich, inorganic-open-framework (IOF) phosphovanadate cathode, which is mass-producible and delivers high capacity (228 mAh g⁻¹) and energy density (193.8 Wh kg⁻¹ or 513 Wh L⁻¹), is reported. The abundant lattice waters functioning as a “charge shield” enable a low Zn²⁺-migration energy barrier, (0.66 eV) even close to that of Li⁺ within LiFePO₄. This fast intrinsic ion-diffusion kinetics, together with nanostructure effect, allow the achievements of ultrafast charging (71% state of charge in 1.9 min) and an ultrahigh power density (7200 W kg⁻¹ at 107 Wh kg⁻¹). Equally important, the IOF exhibits a quasi-zero-strain feature (<1% lattice change upon (de)zincation), which ensures ultrahigh cycling durability (3000 cycles) and Coulombic efficiencies of 100%. The cell-level energy and power densities reach ≈90 Wh kg⁻¹ and ≈3320 W kg⁻¹, far surpassing commercial lead–acid, Ni–Cd, and Ni–MH batteries. Lattice-water-rich IOFs may open up new opportunities for exploring stable and fast-charging Zn-ion batteries.     

Inhibitory effects of three chemical dust suppressants on nitrocellulose dust cloud explosion

Three types of self-prepared chemical dust suppressants (CDSs) were investigated for their inhibitory effects on nitrocellulose (NC) cloud dust explosion. The results revealed that NC is extremely sensitive to electric sparks and has a high explosion intensity. CaCl₂-CDS effectively increased the particle size to control fly dust substantially inhibiting dust cloud explosions. However, both Na₂SO₄-CDS and MgCl₂-CDS exhibited poor abilities and even promoted explosion. Therefore, neither Na₂SO₄-CDS nor MgCl₂-CDS is recommended as a CDS for NC. Inappropriately using CDSs may engender severe explosions. Furthermore, a mechanism underlying NC dust cloud combustion and explosion was proposed. NC has three stages of heat release: autoxidation, thermal decomposition, and combustion. Thermal decomposition, combustion, and explosion were triggered depending on the energy provided from autoxidation. CaCl₂-CDS inhibited only combustion. This study reveals the mechanism underlying NC dust cloud explosions and provides useful information for the development of more optimized CDSs.     

Multi‐fault synergistic diagnosis of battery systems based on the modified multi‐scale entropy

Faults of lithium batteries in their early stage in electric vehicles (EVs) are usually undetectable, and their characteristics are difficult to be extracted by conventional methods. This paper presents a novel synergistic diagnosis scheme for multiple battery faults using the modified multi‐scale entropy (MMSE). The proposed MMSE can effectively extract the multi‐scale features of complex battery signals in the early stages of battery faults as well as overcome the shortage of the coarse‐grained mode in the standard multi‐scale entropy. The simulation results on experimental data and the real‐world operational vehicles show that the proposed method can effectively detect and locate multiple battery faults/abnormities before they trigger the alarm thresholds. The defined sensitivity factor can implement real‐time evaluation on abnormities with high efficiency and stability, and the developed variable‐calculation‐window diagnosis scheme can synchronously detect and locate different fault types in real time. Furthermore, feasibility, stability, reliability, versatility, robustness, and practicality of the proposed method are separately verified using multiple sets of real‐world operation data. More importantly, the proposed method also provides feasibility to effectively prevent battery thermal runaway caused by multiple battery abnormities/faults. The applications of multi‐scale entropy theory is the first of its kind to battery fault diagnosis on the real‐world operational vehicles.     

Synthesis of SnO2@MnO2@graphite nanosheet with high reversibility and stable structure as a high-performance anode material for lithium-ion batteries

In this study, SnO₂@MnO₂@graphite (SMG) anode material is prepared via a facile ball-milling approach combined with hydrothermal treatment. SnO₂ and MnO₂ nanoparticles are evenly dispersed on numerous sheet-like graphite. MnO₂ can not only play a catalytic role for facilitating the conversion reaction of Sn/Li₂O to SnO₂, but also as a barrier to impede the coarsening of Sn in the composite. Meanwhile, graphite nanosheets could serve as an ideal volume expansion buffer and good electron conductor. Consequently, the SMG anode delivers superior reversible capacity of 1048.5 mAhg⁻¹, ideal rate capability of 522.2 mAhg⁻¹ at 5.0 A g^-1 and stable long-life cyclic performance of 814.8 mAhg⁻¹ at 1.0 A g^-1 after 1000 cycles. This result indicates that the incorporation of MnO₂, graphite nanosheet and SnO₂ have a great potential in enhancing the performance of SnO₂-based anode for battery applications.     

Controlled morphology and optical properties of n-type porous silicon: effect of magnetic field and electrode-assisted LEF

Fabrication of photoluminescent n-type porous silicon (nPS), using electrode-assisted lateral electric field accompanied with a perpendicular magnetic field, is reported. The results have been compared with the porous structures fabricated by means of conventional anodization and electrode-assisted lateral electric field without magnetic field. The lateral electric field (LEF) applied across the silicon substrate leads to the formation of structural gradient in terms of density, dimension, and depth of the etched pores. Apart from the pore shape tunability, the simultaneous application of LEF and magnetic field (MF) contributes to a reduction of the dimension of the pores and promotes relatively more defined pore tips as well as a decreased side-branching in the pore walls of the macroporous structure. Additionally, when using magnetic field-assisted etching, within a certain range of LEF, an enhancement of the photoluminescence (PL) response was obtained.     

适用于小型热气机性能试验的电加热器的研制

介绍了一种针对小型家用热气机性能试验开发的电加热器系统.该电加热器可以模拟性能试验时外燃系统对热头的加热情况,精确控制输入的热量.针对不同材料不同形式的加热器进行理论试验研究,确定并制造了应用于试验的电加热器系统.试验验证了其可行性,可满足家用小型热气机性能试验的要求.     

ZWB-10（6.3）kV线路无功功率自动补偿器的使用

采油二厂现有30条6 kV配电线路,每条线路的功率因数各不相同,有的达到标准,有的没有达到标准。众所周知,如果线路的功率因数低,就会造成线路电流增大,电能损耗增加,用电量也随之增加,电量的增加也就带来了企业成本的增加。因此,提高配电线路的功率因数是目前所有供电部门的一项非常重要的工作。     

LD4型电动刀架的故障诊断及维修

介绍了LD4型电动刀架的工作原理，针对其常见的几种故障现象进行分析并提出维修方法，以供参考。     

Optimization of dielectric heating parameters in the production of high‐voltage LiNiPO4‐core and carbon‐shell ceramics

Excellent core‐shell morphology and nanoscale high‐voltage LiNiPO₄@C cathode materials have been synthesized by a low‐level and long‐time microwave and solvothermal synthesis methodology. The effects of the changing physicochemical parameters on the crystal‐quality and electrochemical properties of the products have been evaluated in relation to the cycling stability. X‐ray diffraction analysis shows that it is possible to synthesize phase‐pure LiNiPO₄ material when the reaction parameters are carefully elaborated. High‐resolution transmission electron microscopy analysis reveals a core‐shell morphology with a coating thickness of 6‐8 nm for 30 minutes at 180°C solvothermal temperature and time‐spread microwave energy. This mentioned cathode material exhibits the best electrochemical properties, achieving a discharge capacity of 157 mAh·g^?1 at a 0.l C current rate, and shows a remarkable 81% capacity retention at the end of the 80th cycle.