网络机房制冷效率研究

根据相关的调查显示,在传统观念和设计标准的影响下,网络机房存在各种各样的设计缺陷,其中的一些缺陷会导致网络机房内部空间形成热点、降低制冷容错能力、制冷效率和制冷量,从而提高运行成本。网络机房的制冷效率和运行成本的大幅提高成为制约发展的重要因素。文章从网络机房面临的实际问题出发,有针对性地分析了机房设计的典型错误,阐述了其原理和影响,并根据实践经验,介绍了一些简单可行的解决方案。     

A data collection protocol for real-time sensor applications

The nature of many sensor applications as well as continuously changing sensor data often imposes real-time requirements on wireless sensor network protocols. Due to numerous design constraints, such as limited bandwidth, memory and energy of sensor platforms, and packet collisions that can potentially lead to an unbounded number of retransmissions, timeliness techniques designed for real-time systems and real-time databases cannot be applied directly to wireless sensor networks. Our objective is to design a protocol for sensor applications that require periodic collection of raw data reports from the entire network in a timely manner. We formulate the problem as a graph coloring problem. We then present TIGRA (Timely Sensor Data Collection using Distributed Graph Coloring) — a distributed heuristic for graph coloring that takes into account application semantics and special characteristics of sensor networks. TIGRA ensures that no interference occurs and spatial channel reuse is maximized by assigning a specific time slot for each node. Although the end-to-end delay incurred by sensor data collection largely depends on a specific topology, platform, and application, TIGRA provides a transmission schedule that guarantees a deterministic delay on sensor data collection.     

锰红柱石中Mn~（3＋）谱的分析

本文利用锰红柱石的吸收光谱,考虑到锰红柱石中Ｍｎ３＋处于一种Ｃ２ｖ（Ｃ２＇＇）的低对称晶位,采用一简化的强场方案,把单电子晶场矩阵元用自旋允许吸收带代替,克服了多参数的困难．计算出了锰红柱石中处于八面体配位的Ｍｎ３＋的电子能谱,对锰红柱石的分析首次获得了较为理想的理论计算结果,并对Ｍｎ３＋和Ｆｅ３＋谱带的识别提出了新的看法．     

考虑EV充放电意愿的园区综合能源系统双层优化调度

随着电动汽车的普及度越来越高,工业园区的电动汽车用户日益增多,其充放电行为对园区综合能源系统规划和运行带来极大挑战。本文提出了考虑电动汽车充放电意愿的园区综合能源系统双层优化调度。首先基于动态实时电价、电池荷电量、电池损耗补偿、额外参与激励等因素建立充放电意愿模型,在此基础上得到改进的电动汽车充放电模型;然后,以园区综合能源系统总成本最小和电动汽车充电费用最小为目标建立双层优化调度模型,通过KKT条件将内层模型转化为外层模型的约束条件,从而快速稳定的实现单层模型的求解;最后,进行仿真求解,设置3种不同场景,对比了所提模型与一般充放电意愿模型,验证了文中所提引入EV充放电意愿模型的园区综合能源系统双层优化调度的有效性和可行性,具有一定的经济效益。     

考虑天然气混氢的园区综合能源系统电制氢优化配置

电制氢和天然气混氢技术在促进可再生能源消纳、降低系统碳排放量方面具有良好的理论研究和工程应用前景。面向含高比例可再生能源的园区综合能源系统,提出一种计及天然气混氢及跨季节存储的电制氢优化配置方法。首先梳理了含氢园区综合能源系统的运行框架和能量流动关系,建立园区内部能源生产、转换与存储设备的数学模型,其次以设备的年化投资成本、园区综合能源系统的年度运行成本和碳交易成本最优为目标,提出电制氢优化配置模型。最后通过算例分析表明电制氢及天然气混氢技术的引入可提升可再生能源的消纳能力,降低系统的整体经济成本和碳排放量,并分析了电解槽投资成本、混氢体积分数上限以及经济性和低碳性成本权重系数变化对规划运行结果的影响。关键词：园区综合能源系统;电制氢;天然气混氢;碳交易;跨季节储氢;优化配置 中图分类号：TM732     

考虑电-氢-热多能互补的微网多目标优化配置研究

氢储能具有储能容量大、储存时间长、清洁无污染、实现多种能源网络互联互补和协同优化等诸多优点,有望成为推动分布式能源发展和提升终端能源利用效率的重要支撑技术。为了提高独立型微网供电可靠性及可再生能源利用率,本文建立了考虑电-氢-热多能互补的独立微网多目标优化配置模型,并基于模拟退火的粒子群算法对目标问题进行求解。最后,通过东北某地独立微网优化配置算例,基于MATLAB平台验证了所提多能互补配置方案较传统电储能配置方案负荷失电率降低了3.18%,可再生能源利用率提高了8.37%,所提配置方案可有效促进可再生能源消纳,保证独立微网的供电可靠性。     

含多电解槽的新能源制氢能量管理优化

新能源制氢系统是提升风能、太阳能等新能源发电消纳的有效途径。目前国内外关于电解槽能量管理的相关研究以单电解槽为主。单电解槽能量管理未考虑电解槽非线性的工作特性,难以兼顾多个电解槽制氢效率,影响系统经济性。论文针对含有多电解槽新能源制氢系统的能量管理问题进行了研究。以新能源消纳率、经济收益、制氢率为目标,考虑单个电解槽运行特性及生产约束等条件,建立包含风电、光伏、蓄电池、电解槽多个模块的能量管理优化模型,并采用SPEA2算法求解多目标优化问题。仿真研究表明,所提能量管理策略能够实现新能源发电的100%消纳,单位制氢效益可提升5.15%。因此,多电解槽制氢系统进行有效的能量管理有助于提高制氢效率,有效克服单电解槽运行及能量管理的不足。     

Amine Coordinated Electron-Rich Palladium Nanoparticles for Electrochemical Hydrogenation of Benzaldehyde

Electrocatalytic hydrogenation (ECH) is a burgeoning strategy for the sustainable utilization of hydrogen. However, how to effectively suppress the competitive hydrogen evolution reaction (HER) is a big challenge to ECH catalysis. In this study, amine (NH₂ R)-coordinated Pd nanoparticles loaded on carbon felt (Pd@CF) as a catalyst is successfully synthesized by a one-step solvothermal reduction method using oleylamine as the reducing agent. An exceptional ECH reactivity on benzaldehyde is achieved on the optimal Pd@CF catalyst in terms of a high conversion (89.7%) and selectivity toward benzyl alcohol (89.8%) at −0.4 V in 60 min. Notably, the Faradaic efficiency for producing benzyl alcohol is up to 90.2%, much higher than that catalyzed by Pd@CF-without N-group (41.1%) and thecommercial Pd/C (20.9%). The excellent ECH performance of Pd@CF can be attributed to the enriched electrons on Pd surface resulted from the introduction of NH₂ R groups, which strengthens both the adsorption of benzaldehyde and the adsorbed hydrogen (H_ads) on Pd, preventing the combination of H_ads to form H₂, that is, inhibiting the HER. This study gives a new insight into design principles of highly efficient electrocatalysts for the hydrogenation of unsaturated aldehydes molecules.     

A 2.20 eV Bandgap Polymer Donor for Efficient Colorful Semitransparent Organic Solar Cells

Semitransparent organic solar cells (ST-OSCs) have attracted increasing attention due to their promising prospect in building-integrated photovoltaics. Generally, efficient ST-OSCs with good average visible transmittance (AVT) can be realized by developing active layer materials with light absorption far from the visible light range. Herein, the development of ultrawide bandgap polymer donors with near-ultraviolet absorption, paired with near-infrared acceptors, is proposed to achieve high-performance ST-OSCs. The key points for the design of ultrawide bandgap polymers include constructing donor–donor type conjugated skeleton, suppressing the quinoidal resonance effect, and minimizing the twist of conjugated skeleton via noncovalent conformational locks. As a proof of concept, a polymer named PBOF with an optical bandgap of 2.20 eV is synthesized, which exhibited largely reduced overlap with the human eye photopic response spectrum and afforded a power conversion efficiency (PCE) of 16.40% in opaque device. As a result, ST-OSCs with a PCE over 10% and an AVT over 30% are achieved without optical modulation. Moreover, colorful ST-OSCs with visual aesthetics can be achieved by tuning the donor/acceptor weight ratio in active layer benefiting from the ultrawide bandgap nature of PBOF. This study demonstrates the great potential of ultrawide bandgap polymers for efficient colorful ST-OSCs.     

Empowering wave energy with control technology: Possibilities and pitfalls

With an increasing focus on climate action and energy security, an appropriate mix of renewable energy technologies is imperative. Despite having considerable global potential, wave energy has still not reached a state of maturity or economic competitiveness to have made an impact. Challenges include the high capital and operational costs associated with deployment in the harsh ocean environment, so it is imperative that the full energy harnessing capacity of wave energy devices, and arrays of devices in farms, is realised. To this end, control technology has an important role to play in maximising power capture, while ensuring that physical system constraints are respected, and control actions do not adversely affect device lifetime. Within the gamut of control technology, a variety of tools can be brought to bear on the wave energy control problem, including various control strategies (optimal, robust, nonlinear, etc.), data-based model identification, estimation, and forecasting. However, the wave energy problem displays a number of unique features which challenge the traditional application of these techniques, while also presenting a number of control ‘paradoxes’. This review articulates the important control-related characteristics of the wave energy control problem, provides a survey of currently applied control and control-related techniques, and gives some perspectives on the outstanding challenges and future possibilities. The emerging area of control co-design, which is especially relevant to the relatively immature area of wave energy system design, is also covered.