Dependence of oil stability index of fatty compounds on their structure and concentration and presence of metals

During storage and use, vegetable oil-derived industrial products such as biodiesel and biodegradable lubricants can be subjected to conditions that promote oxidation of their unsaturated components. The materials arising during oxidation and subsequent degradation can seriously impair the quality and performance of such products. Therefore, oxidative stability is a significant issue facing these vegetable oil-derived products, and enhanced understanding of the influence of various components of vegetable oils and storage parameters is necessary. In this work, the oil stability index (OSI) was used for assessing oxidation of monoalkyl esters of FA by varying several parameters. Neat fatty compounds and prepared mixtures thereof were studied for assessing the influence of compound structure and concentration. Small amounts of more highly unsaturated compounds had a disproportionately strong effect on oxidative stability. The recently developed concept of bis-allylic equivalents correlated more closely than the iodine value with the OSI times of mixtures of fatty esters. The OSI times of free acids were shorter than those of the corresponding alkyl esters. The presence of copper, iron, and nickel also reduced oxidative stability, but their effect was less than the presence of more highly unsaturated fatty compounds. Of these metals, copper had the strongest catalytic effect on OSI time. OSI may be an alternative to long-term storage tests for determining the influence of extraneous materials such as metals on oxidative stability.     

瓷质砖湿坯对流干燥过程的传热传质研究

引用建立于Whitaker的体积平均方程和Darcy定律基础止的多孔介质内部热质传递的等效耦合扩散模型，寻出一组关于液体饱和度、温度和气相压力的新支配方程，应用该方程组对瓷质砖坯体干燥过程进行了数值分析和实验测定。在平均含湿饱和度的变化方面，数值解与实验结果十分吻合。还改变影响坯体干燥过程的一些因素进行计算机模拟计算，通过改变这些因素的大小来考察计算结果，以期获得某些定性或定量的结论，从而用以指导实际生产过程。     

Dynamic equivalent method of interconnected power systems with consideration of motor loads

The existing equivalent methods usually only deal with static load models and neglect the dynamic characteristics of loads such as induction motors.This paper presents a dynamic equivalent method which considers motor dynamics.At first,the clustering criterion of motor loads is given.The motors with similar dynamic characteristics are classified into one group.Then,reduction of motors in the same group is carried out.Finally,parameters of the equivalent motor are calculated and the equivalent system is thus...     

基于Blowfish和MD5的混合加密方案*

针对Blowfish算法在实际应用中存在的等价密钥、重复初始化等问题,提出Blowfish与MD5算法相结合,将MD5算法的生成值作为密钥的一部分对Blowfish算法进行初始化,使用概率统计方法证明该方案弥补了Blowfish算法的实际应用缺陷。计算结果表明,混合加密方案具有更高的安全性、更快的速度。     

电力系统备用容量模型

发电设备合理备用容量和备用率问题是电力系统中的一个特殊问题。本文在等效持续负荷曲线概念的基础上,利用曲线拟合的思想,得出了负荷与时间的函数关系式,进一步求得合理备用容量和备用率。     

等效剪切刚度的框架结构损伤识别方法

为研究有别于现有侧重于研究结构具体构件(梁、柱及支撑等)的建筑结构损伤识别方法,提出应直接从整体开展框架结构损伤识别方法.将框架结构转换成"等效剪切型"结构,数值分析表明,结构具体构件出现损伤(即刚度发生退化)时,会引起受影响层的等效剪切刚度发生变化,因此,可以采用层等效剪切刚度变化率与层抗侧刚度作为指标来进行结构损伤定位与损伤程度评定.通过大量的框架结构数值模拟计算,归纳出了一套能将损伤定位到结构层及从整体来评定结构损伤程度的方法.     

Zonal disintegration phenomenon in enclosing rock mass surrounding deep tunnels -- Elasto-plastic analysis of stress field of enclosing rock mass

The zonal disintegration phenomenon (ZDP) is a typical phenomenon in deep block rock masses. In order to investigate the mechanism of ZDP, an improved non-linear Hock-Brown strength criterion and a bi-linear constitutive model of rock mass were used to analyze the elasto-plastic stress field of the enclosing rock mass around a deep round tunnel. The radius of the plastic region and stress of the enclosing rock mass were obtained by introducing dimensionless parameters of radial distance. The results show that tunneling in deep rock mass causes a maximum stress zone to appear in the vicinity of the boundary of the elastic and the plas-tic zone in the surrounding rock mass. Under the compression of a large tangential force and a small radial force, the rock mass in the maximum stress zone was in an approximate uniaxial loading state, which could lead to a split failure in the rock mass.     

印度应对能源需求的生态友好能源生产（英文）

全球能源需求增长显著,并且初级化石能源消耗已经呈现出很高的正增长.讨论不同的初级能源消耗情况,以及预测未来煤炭将继续作为主要能源.讨论印度的能源需求前景,以及预测未来印度对石油、天然气、煤层气和地下煤气的需求情况,同时还讨论当今国家的石油和石化工业的情况,以及在未来几年内的新能源来取代初级化石能源的最新进展.发展经济和缓解贫困取决于能否获得廉价的能源和国家的能源安全.在石油石化行业等能源行业,有必要通过政府政策的扶持,发展最新先进技术.设计这些行业路线图,规范能源企业在印度和海外的最佳实践.文中还讨论通过现代管理手段使其有效定位环境与社会的挑战,应对经济增长,并且满足能源需求的战略,但是这样的能源应当更多关注环境退化问题.结论指出能源安全可以引导能源自主是有可能的,并且可以通过规划方式来实现.     

基于MATLAB/Simulink的染料敏化太阳能电池输出特性仿真

根据染料敏化太阳能电池(DSSC)的等效电路,应用MATLAB/Simulink工具建立仿真模型,对DSSC的输出伏安特性及输出功率进行仿真,讨论串联电阻和分流电阻对DSSC性能的影响.仿真结果表明,随着串联电阻的增加,开路电压不变,短路电流密度、最大输出功率及填充因子降低;随着分流电阻的增加,开路电压、短路电流密度、...     

砌体等效断裂韧度的实用解析方法研究

根据砌体准脆性材料的断裂特性,提出了一种基于竖向灰缝模型的求解砌体等效断裂韧度的实用解析方法.首先根据复合材料力学和线弹性断裂力学的基本原理,运用修正的剪滞理论,分区引入变异层,建立了分层剪滞模型;然后根据能量法则,推导出了求解无筋砌体等效断裂韧度的解析计算模式;最后针对相关试验数据,得到了对应数值解的解析解,且与相关试验对应的数值解相比,解析解的均方差和变异系数更小,由此可以看出,本文的解析方法具有很好的鲁棒性.结果还证明了无筋砌体等效断裂韧度是与试件尺寸无关的断裂参数.该方法为砌体结构开裂机理的研究和发展,砌体结构力学性能的研究提供了新的技术路径.