Calorimetric determination of the enthalpy change for the binding of methyl orange to poly(vinylpyrrolidone) in aqueous solution

Thermodynamic parameters have been determined for the interaction of methyl orange and poly(vinylpyrrolidone) in aqueous solutions containing tris, tris and hydrochloric acid, or water only. Enthalpy changes were determined by use of a flow microcalorimeter. Free energy changes were calculated from the results of equilbrium dialysis studies. The results are interpreted in terms of the behaviour of poly(vinylpyrrolidone) in these systems. Analysis of data shows that the hydrophobic interactions in the systems are in the order: tris > wateronly > tris-HC1.     

舞钢扁钢锭咬边参数的确定

本文根据我公司自产的11.7t及13.34t扁钢锭在4200mm轧机生产过程中,运用正交试验方法,合理应用咬边参数的轧制方案,以此降低金属消耗。此方案使“咬入返回轧制”及“留尾轧制”新技术进一步得到完善,板形更加矩形,使锭一材成材率提高2％左右。     

铜街子工程坝基预裂控制爆破

本文介绍了在复杂地质条件下,通过反复试验、采用预裂爆破技术在玄武岩坝基进行各种坡面角度的全方位、大面积的生产性实践,并对预裂控制爆破提出了一些意见和具体施工方法.     

弱激发氩离子激光的振荡频率特性

通过改变激光器的相对激发,观察到了氩离子激光器振荡频率的演变特性。用模竞争效应对实验现象进行了理论解释。     

激光脉冲和工件参数对激光微孔加工质量的影响

研究了激光功率、重复频率、焦点位置以及光束质量对激光打孔质量的影响。通过调整和优化激光脉冲、聚焦光学系统和工件参数，在０．１～２ｍｍ厚的不同材料上打出孔径０．０６～０．２ｍｍ的精密小孔。利用ＴＥＭ００模激光脉冲和望远镜扩束后再聚焦的办法，加工出孔径２５～３０ｍｍ的微孔。     

叶绿素衍生物─CPD_4在人血清中的激发和发射荧光谱

叶绿素衍生物４号（ＣＰＤ４）是一种新型中药光敏剂，本文研究了不同浓度的ＣＰＤ４分别在含１０％不同血型人血清的生理盐水中以及纯生理盐水中的激发和发射荧光光谱，并对结果进行了分析，结论对ＣＰＤ４在光动力诊断恶性肿瘤的临床应用具有一定的指导意义．     

小型全内腔脉冲Ar~＋激光管的研制

介绍一种小型全内腔脉冲Ａｒ＋激光管的设计和结构。并对不同阴极，放电管直径，激励电压及Ａｒ气压等对输出功率及激光管寿命的影响作了一系列的实验，试制出结构简单，使用方便，价格便宜的有一定实用价值的小型全内脏脉冲Ａｒ＋激光管。     

Rapid determination of chlorophylls in vegetable oils by laser-based fluorometry

The presence of chlorophylls in vegetable oils is considered undesirable due to their adverse effects on oxidative deterioration, bleachability and hydrogenation. The usual methods for determination of chlorophylls in vegetable oils are absorption spectrophotometry, fluorometry and liquid chromatography using fluorescence detectors. This paper outlines a fluorometric method using a laser as the excitation source. The chlorophylls in crude palm oil, rapeseed oil, soya bean oil and olive oil were determined directly by laser-based fluorometry using (a) a helium-neon laser (632-8 nm, 5 mW) as the excitation source and an optical-multichannel analyser (OMA) with an intensified diode array as the detector, and (b) a helium-neon laser and a photomultiplier tube as the detector. The method is especially suitable for the detection of chlorophylls in crude palm oil since no pre-extraction step is required. The levels of chlorophylls measured in vegetable oils using the laser technique was also compared against values obtained by conventional spectrophotometric methods. The simplicity and rapid quantification of laser based fluorometry suggest that this technique can be readily applied to the detection or a wide variety of fluorescing species in vegetable oils.     

混合结构楼房爆破拆除倒塌范围的确定

通过对混合结构楼房爆破倾倒过程特点的分析,提出了楼房在倾倒过程中的运动计算模型,并应用体积平衡原理,得到这类楼房爆破爆堆参数计算公式,用该公式计算的结果与实例中爆堆实测数据相比较,相对误差不超过11%.     

Electron-Impact Cross Sections for Dipole- and Spin-Allowed Excitations of Hydrogen,Helium, and Lithium

Electron-impact excitation cross sections are presented for the dipole- and spin allowed transitions from the ground states to the np ²P states for hydrogen and lithium, and to the 1snp ¹P states for helium, n = 2 through 10. Two scaling formulas developed earlier by Kim [Phys. Rev. A 64, 032713 (2001)] for plane-wave Born cross sections are used. The scaled Born cross sections are in excellent agreement with available theoretical and experimental data.