Effect of Additives on Magnetic Properties of High Frequency MnZn Power Ferrite

In keeping with the advance of more compact and more power-saving electronic equipment, the demand is increasing for smaller and more efficient switching power supply. Therefore, it is necessary to provide the adequate magnetic power ferrite materials to satisfy the demand. Such ferrite materials have to meet the following main requirement: 1) high initial permeability (μ i ); 2) high saturation magnetic induction (Bs); 3) high Curie temperature (Tc); 4) high electrical resistivity (ρ ); 5)…     

Structural and magnetic properties of Co1+ySnyFe2-2y-xCrxO4 ferrite system

The samples of the series Co_1+ySn_yFe_{2- 2y- x}Cr_xO₄ ferrites with x = 0.0, 0.1, 0.2, 0.3, 0.4, 0.5 and y = 0.05, were prepared by the usual double sintering ceramic technique. The single- phase spinel structure of the samples was confirmed by using X- ray diffractometry technique. The lattice parameter ’a’ with an accuracy of ± 0.002 Å were determined using Bragg peaks of XRD pattern. The lattice parameter ’a’ decreases with concentration, x, which is due to the difference in the ionic radii of Cr³⁺ and Fe³⁺ ions. The X- ray intensity calculations were carried out in order to determine the possible cation distribution amongst tetrahedral (A) and octahedral [B] sites. The X- ray intensity calculations show Cr³⁺ ions occupying B site. The saturation magnetization, σ_s, and magneton number, n_B (the saturation magnetization per formula unit), measured at 300 K determined from high field hysteresis loop technique decrease with increase in concentration, x, suggesting a decrease in ferrimagnetic behaviour. Thermal variation of low field a.c. susceptibility measurements from room temperature to about 800 K exhibits almost normal ferrimagnetic behaviour and the Curie temperature, T_C determined from a.c. susceptibility data decreases with increase in x.

     

关于混凝土钻芯取样法有关标准的讨论

本文对国内不同行业有关混凝土钻总取样方法的标准进行了讨论，供月行在使用和修订相应标准时参考。     

THE REACTIVITY AND DURABILITY OF ZINC FERRITE HIGH TEMPERATURE DESULFURIZATION SORBENTS

Cylindrical pellets of zinc ferrite high temperature desulfurization sorbent have been prepared using a number of formulation recipes and induration conditions. Physical and structural properties of the resultant sorbents were measured, and reactivity and durability screening tests were carried out using a single pellet electrobalance reactor. The formulation variables studied were ZnO to Fe₂O₃ ratio, Fe₂O₃ source, and the addition of inorganic (bentonite) and organic (methocel) binders to the sorbents. Pellet induration conditions ranged from 0.25 hours at 815^°C to 4.0 hours at 1038°C. Stronger pellets having greater attrition resistance resulted when 5% bentonite was added to the formulation recipe and when the pellets were indurated at high temperature for extended times. In contrast, bentonite content was not a significant factor in determining sorbent reactivity and durability, both of which were improved by mild induration conditions. Sorbent regeneration temperature was found to be an important factor in improving reaction durability, as was the addition of 0.5% methocel to the formulation recipe. Pellets containing catalyst-grade Fe₂O₃ were more reactive than those containing pigment-grade Fe₂O₃. This effect, however, was less important than the effect of induration conditions.     

Mössbauer effect studies and X-ray diffraction analysis of cobalt ferrite prepared in powder form by thermal decomposition method

Cobalt ferrite (Co_xFe_3?xO₄) is prepared in powder form by thermal decomposition of iron and cobalt salts and is analysed by X-ray diffraction and Mössbauer spectroscopic techniques. The variation of Mössbauer parameters, lattice parameters and crystallite size of the products formed with variation in the composition of Fe and Co ratios are studied. The studies confirm the formation of nano-size cobalt ferrite particles with defect structure and it is found to be maximum for the Fe : Co = 60 : 40 ratio of the initial precursor oxides.     

糯扎渡心墙堆石坝心墙方案比较研究

糯扎渡工程在可行性研究阶段，比较了直心墙堆石坝和斜心墙堆石坝两种方案，分析表明，直心墙堆石坝在坝坡稳定性、坝体应力及抗震性方面均满足设计要求，且在地形地质条件、基础处理、抗震性能、施工方便性、工程造价等方面不同程度地优于斜心墙堆石坝，因此，设计最终选择直心墙堆石坝方案。     

高频MnZn功率铁氧体烧结工艺研究

按照氧化物陶瓷工艺对高频MnZn功率铁氧体烧结工艺条件进行了研究。烧结温度越高，晶粒越大，晶界越薄，电阻率越低，磁芯损耗越大，起始磁导率和烧结密度分别在1240℃和1230℃达到最大值。延长保温时间，可以使晶粒充分生长，晶界变薄，电阻率减小，损耗增大。保温3h后，起始磁导率和烧结密度均可达到最大值。氧分压越低，材料起始磁导率越高，电阻率越小，损耗越大，但氧分压低于5％后烧结密度不再继续增加。     

片式抗电磁干扰滤波器Ni-Zn铁氧体材料与工艺研究

通过添加适量CuO和Bi2O3，将Ni-Zn铁氧体材料的烧结温度降至870—920℃，达到Ni-Zn铁氧体材料与Ag电极共烧匹配的目的。试制了片式抗电磁干扰滤波器，并对其插入损耗特性进行了计算机模拟，表明所研制的抗电磁干扰滤波器不仅适合高密度表面封装技术的要求，也可满足宽频域抗电磁干扰需要。     

Electromagnetic properties of ferroelectric-ferrite ceramic composites

The NiFe₂O₄ and Pb(Zr_0.52Ti_0.48)O₃ ceramic composites are prepared by conventional solid state reaction method. The microstructural and morphological properties of the composites are studied by X-ray diffraction analysis and scanning electron microscopy. Results indicate that the ferrite and piezoelectric phases can co-exist in the composites. The relationship between the dielectric constant and frequency (40 Hz–40 MHz) as well as temperature is also investigated. It is noted that the transition temperature of the composites is about 380 °C. A double electric hysteresis loop is observed in our composites. The magnetic properties are relatively weak according to the magnetic hysteresis loop. With increase in the content of the ferrite phase, the permeability increases. The electromagnetic properties of the as-prepared composites are tunable according to the content of the NiFe₂O₄ phase.     

锰锌铁氧体纳米粉体的液相制备及磁性能

以δ-FeOOH为前驱体,用氨水调节溶液的pH值,分别采用(1)90℃水浴加热动态转化、(2)沸腾回流动态转化,(3)90℃静态转化及(4)200℃水热法四种方法合成了锰锌铁氧体纳米粉体.采用X射线衍射仪(XRD),透射电子显微镜(TEM)、振动样品磁强计(VSM)和X射线荧光光谱仪(XRF)等方法对粉体进行了表征,对四种液相法制备的锰锌铁氧体纳米粉体的结构和性能等进行了对比和分析.结果表明,四种方法中沸腾回流相转化法得到的产物具有磁性能较好、形状较规则、粒径可控等优点.