Characterisation of inter-particle forces within agglomerated metallurgical powders

The strength of agglomerates of nickel flash furnace concentrate and dust was determined from experimental observations of agglomerates forming under controlled conditions, combined with mathematical equations from the literature. It was found that the agglomerates had a tensile strength ranging from 0.01 Pa to 38.7 Pa, while inter-particle forces ranged from 2.2 × 10^− 12 N to 1.5 × 10^− 10 N. These values were compared to the expected magnitude of van der Waals, electrostatic, magnetic and capillary forces within the agglomerates, and it was found that both electrostatic and van der Waals forces are likely to contribute to the cohesion of agglomerates, although sub-micron particles and the presence of sufficiently large asperities on the surface of particles limit the magnitude of van der Waals forces. Magnetic forces are large enough to contribute to the cohesion of dust agglomerates, which is in keeping with the high magnetite content of the recycle dust. It is postulated that electrostatic forces, acting over a longer range than van der Waals forces, may be responsible for initially bringing particles together. The methodology for determining inter-particle forces can be applied to the computer modelling of flash smelting systems, as well as other gas/particle systems such as fluidized beds.     

Studies of substrate specificities of lipases from different sources

Although lipases are widely applied in a wide variety of reactions, available information on the factors that are responsible for the substrate specificities of lipases from different sources is scarce. In this paper, nine lipase‐producing microorganism strains were isolated from oil‐containing samples. The properties of these enzymes, including pH optima, temperature optima, thermal stability, and pH stability, vary significantly with the different sources from which these lipases were isolated. The substrate specificities of the nine lipases, including fatty acid and positional specificities, were also studied. The fatty acid specificities of the nine lipases were observably different toward 15 substrates with different carbon chain lengths, different saturation degrees and different side chains. The lipases from S₃ Penicillium citrinum (PCL), MJ₁ Aspergillus niger (ANL), MJ₂ Aspergillus oryzae (AOL), YM Bacillus coughing (BCL), S₉ Geotrichum candidum (GCL), and S₁₁ Candida lypolytica (CLL) showed the strongest specificities to short‐chain esters, and the other lipases showed strong selectivity for medium‐ or long‐chain and branched esters. The positional specificities were examined by analyzing the hydrolytic products of triolein catalyzed by the nine lipases, using TLC. The lipases can be mainly classified into two groups by their specificities for the ester bond at position 2 of triglycerides; one group can selectively hydrolyze the ester bond at position 2 of the triglycerides, the other group cannot. All these nine lipases were divided into four groups by hierarchical clustering analysis on the basis of the results of fatty acid and positional specificities.     

Flammability ranking of foliage species by factor analysis of physical and chemical pyric properties

In this paper, factor analysis is introduced to evaluate the flammability of 55 foliage species that may be used in China for construction of the fuel break network of forest strips with lower flammability. Six pyric parameters, i.e. air dry moisture content, absolute dry moisture content, ignition point, ash content, caloric value and extractive content, are measured and used as variables for factor analysis. The covariance analysis shows that four principal factors can be extracted to reflect the flammability in different physical and chemical senses. In terms of the contributions of the four factors to the variances and the physical significance of the relevant parameters, the four factors are, respectively, termed as ‘flaming factor,’ ‘air dry factor,’ ‘ash factor’ and ‘absolute dry factor.’ The stability of the factor analysis method is examined by a different number of samples considered, and the variation degrees of the orderings indicate that the method has high reliability to measure the total flammability of foliage species. The results of the flammability evaluation are verified by comparison with the recommended tree species in the Chinese technology standard. Copyright © 2008 John Wiley & Sons, Ltd.     

Direct synthesis and catalytic performance of ultralarge pore GaSBA-15 mesoporous molecular sieves with high gallium content

Mesoporous GaSBA-15 molecular sieves with different n_Si/n_Ga ratios have been directly synthesized using Pluronic 123 triblock polymer as a structure-directing agent by pH-adjusting method. The mesoporous materials have been characterized using ICP-AES, XRD, N₂ adsorption, ⁷¹Ga-MAS NMR, SEM and TEM. ICP-AES studies show a high amount of gallium incorporation on the silica pore walls. The structural and textural properties of calcined GaSBA-15 are characterized by XRD and N₂ adsorption. ⁷¹Ga MAS NMR results demonstrate that a high amount of tetrahedral-gallium could be substituted for Si in the framework of SBA-15. TEM and FE-SEM images show the uniform pore diameter and rope-like hexagonal mesoporous structure of GaSBA-15. These GaSBA-15 materials have been used as catalysts for vapour-phase t-butylation of 1,2-dihydroxybenzene (DHB) for selective synthesis of 4-t-butylcatechol (4-TBC) under different reaction conditions. GaSBA-15(10) gave the highest 93.2% conversion of DHB and 95.7% selectivity of 4-TBC as compared with other GaSBA-15 catalysts.     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

Accelerator Analysis of Tributyltin Adsorbed onto the Surface of a Tributyltin Resistant Marine Pseudoalteromonas sp. Cell

Tributyltin (TBT) released into seawater from ship hulls is a stable marine pollutant and obviously remains in marine environments. We isolated a TBT resistant marine Pseudoalteromonas sp. TBT1 from sediment of a ship’s ballast water. The isolate (10^{9.3 ± 0.2} colony-forming units mL⁻¹) adsorbed TBT in proportion to the concentrations of TBTCl externally added up to 3 mM, where the number of TBT adsorbed by a single cell was estimated to be 10^8.2. The value was reduced to about one-fifth when the lysozyme-treated cells were used. The surface of ethanol treated cells became rough, but the capacity of TBT adsorption was the same as that for native cells. These results indicate that the function of the cell surface, rather than that structure, plays an important role to the adsorption of TBT. The adsorption state of TBT seems to be multi-layer when the number of more than 10^6.8 TBT molecules is adsorbed by a single cell.     

Automatic coding of dialogue acts in collaboration protocols

Although protocol analysis can be an important tool for researchers to investigate the process of collaboration and communication, the use of this method of analysis can be time consuming. Hence, an automatic coding procedure for coding dialogue acts was developed. This procedure helps to determine the communicative function of messages in online discussions by recognizing discourse markers and cue phrases in the utterances. Five main communicative functions are distinguished: argumentative, responsive, informative, elicitative, and imperative. A total of 29 different dialogue acts are specified and recognized automatically in collaboration protocols. The reliability of the automatic coding procedure was determined by comparing automatically coded dialogue acts to hand-coded dialogue acts by a human rater. The validity of the automatic coding procedure was examined using three different types of analyses. First, an examination of group differences was used (dialogue acts used by female versus male students). Ideally, the coding procedure should be able to distinguish between groups who are likely to communicate differently. Second, to examine the validity of the automatic coding procedure through examination of experimental intervention, the results of the automatic coding procedure of students, with access to a tool that visualizes the degree of participation of each student, were compared to students who did not have access to this tool. Finally, the validity of the automatic coding procedure of dialogue acts was examined using correlation analyses. Results of the automatic coding procedure of dialogue acts of utterances (form) were related to results of a manual coding procedure of the collaborative activities to which the utterances refer (content). The analyses presented in this paper indicate promising results concerning the reliability and validity of the automatic coding procedure for dialogue acts. However, limitations of the procedure were also found and discussed.     

永州电力通信交换网集中操作和维护的实现

分析实现永州电力通信交换网集中操作和维护的必要性，介绍了实现程控交换机远程操作和维护的两种方式，总结在实践过程中所得到的经验和教训。     

Numerical characterization of a microscale solid-oxide fuel cell

In this study, a single unit of planar micro-solid-oxide fuel cell (μSOFC) is investigated numerically to evaluate the influences of flow channel design, oxygen composition, and thermal operating conditions on cell performance. Four flow channel designs are examined under the co-flow configuration: serpentine, double serpentine, rod bundle, and oblique rib. For all designs, the contacts areas of interconnect to electrodes are kept consistent to maintain the ohmic losses at the same level. To characterize the mass transport effects, there are three different compositions, 100% O₂, 50% O₂/50% N₂ and air, fed to the cathode inlet. Different thermal conditions, adiabatic and isothermal, are applied to the outer boundary of the μSOFC and the results are compared. The outcomes suggest that both thermal conditions and oxidant composition show remarkable influences on μSOFC performance. Under adiabatic conditions, the rise of cell temperature causes a decrease in reversible voltage, deteriorating the overall cell competence. When oxygen is diluted with nitrogen, local gas diffusion becomes dominant to the cathode reaction. Bulk flow, on the other hand, plays a minor role in cell performance since there is little deviation in the polarization curves for all flow channel designs, even at high current densities. For comparison, the flow visualization technique is employed to observe the transport phenomena in various flow channel designs. The flow patterns are found to resemble the concentration distribution, providing a useful tool to design μSOFCs.