Synthesis and properties of an alkoxysilane dye containing three electronic donor groups for nonlinear optical applications

In order to obtain an efficient hybrid inorganic–organic nonlinear optical (NLO) materials, an azo-dye containing three electronic donor groups 2,5-dimethyl-4-(4′-nitrophenylazo)phenol (DMNPAP) was synthesized and reacted with 3-isocyanatopropyl triethoxysilane (ICTES) to give an alkoxysilane dye (ICTES–DMNPAP). Molecular structural characterizations for DMNPAP and ICTES–DMNPAP were investigated by elemental analysis, ¹H NMR, FTIR, UV–visible spectra and differential scanning calorimetry (DSC). The alkoxysilane dye could be hydrolyzed and polymerized in the presence of water, and then transparent hybrid films could be fabricated by spin coating on the indium–tin-oxide (ITO) glass substrates. Compared with the dye 4-nitro-4′-hydroxy-azobenzene (NHA) containing only one hydroxyl as donor group, DMNPAP exhibited larger β_CTμ_g value measured by solvatochromic method, and second harmonic generation (SHG) measurement of the hybrid films was in agreement with the result.     

复杂电磁暂态下变压器差动保护异常动作行为分析及对策

随着电力系统结构与组成的复杂性增加,变压器差动保护发生原因不明的误、拒动作几率明显上升,给电网安全带来隐患,也影响工业生产的正常运行.分析变压器经历外部故障切除、有载合闸、非线性负荷投入、换流变合闸等复杂电磁暂态过程时基于二次谐波制动的差动保护误动的机理,指出TA局部暂态饱和、非线性特性元件的相互作用是造成上述保护误动的根本原因.并对换流变压器差动保护在故障情况下长延时动作的原因进行分析,基于相电压突变量和差流突变量的时差,提出一种能有效解决上述问题的变压器差动保护判据。在任何非故障的异常情况下,该时差总是存在,而内部故障时该时差很小,可以将变压器故障和其经历的异常运行状态相区分.通过大量的试验对该判据的可行性和有效性进行验证.     

电量测量抗混叠滤波器设计与研究

在电力谐波分析中,为了最大程度地抑制或消除频谱混叠对动态测控系统的影响,必须采用抗混叠滤波器。分析基于DSP电力谐波分析系统中产生频谱混叠的原因,介绍单一采样频率下模拟滤波器设计过程,为了降低对单一采样频率下模拟滤波器技术要求,又介绍采用过采样技术与∑-△式A/D转换器设计的模拟滤波器以及数字滤波器,取得了较好的抗混叠滤波效果。最后,从实际应用出发,给出由RC-运放和集成滤波实现高阶巴特沃斯抗混叠滤波器电路及其参数选择,具有一定实际应用价值.     

新型有机非线性光学材料的制备及性能研究

合成了一种新型含呋喃共轭桥的有机二阶非线性光学生色团分子,用IR、1H-NMR和元素分析表征了其结构。热失重分析(TGA)结果表明,化合物的热分解温度为272℃。利用溶致变色法对材料的超极化率μβ值进行了测量,在1 064 nm激光波长下,材料的μgβ值达24 898×10-48esu。将材料作为客体掺杂于聚砜(PSU)中,用旋涂成膜法制成薄膜,对薄膜进行电晕极化后用二次谐波法(SHG)测量其二阶非线性光学系数d33,在激光基频波长为1 064 nm时,测得d33=70 pm/V。     

脂肪醇生物活性和理化性质的QSAR/QSPR研究

为了研究脂肪醇结构-性质(活性)的定量关系,用相对键长取代拓扑距离,结合距离矩阵,提出了距离调和拓扑指数Te,Te和醇的许多理化性质和生物活性具有良好的相关性.用Te及δ(醇中和羟基相连的碳原子的支化度)与脂肪醇的溶解度、辛醇/水分配系数、急性生物毒性、蒸发热、摩尔磁化率关联,复相关系数分别为0.9955,0.9951,0.9941,0.9964,0.9968,优于文献.同时与脂肪醇的气相色谱保留指数也相关得很好,相关系数为0.9956.结果表明,Te指数可用于醇多种理化性质和生物活性的预测.     

分数布朗运动下的可分离债券定价

假定股票价格服从分数布朗运动,且无风险利率为时间的确定性函数,股票价格的波动率为常数。利用分数布朗运动随机分析理论与方法,建立股票价格服从分数布朗运动的金融市场数学模型,并得到了可分离债券的定价公式。     

Fractional partial differential equation denoising models for texture image

In this paper,a set of fractional partial differential equations based on fractional total variation and fractional steepest descent approach are proposed to address the problem of traditional drawbacks of PM and ROF multi-scale denoising for texture image.By extending Green,Gauss,Stokes and Euler-Lagrange formulas to fractional field,we can find that the integer formulas are just their special case of fractional ones.In order to improve the denoising capability,we proposed 4 fractional partial differential equation based multiscale denoising models,and then discussed their stabilities and convergence rate.Theoretic deduction and experimental evaluation demonstrate the stability and astringency of fractional steepest descent approach,and fractional nonlinearly multi-scale denoising capability and best value of parameters are discussed also.The experiments results prove that the ability for preserving high-frequency edge and complex texture information of the proposed denoising models are obviously superior to traditional integral based algorithms,especially for texture detail rich images.     

An H∞non‐fragile observer‐based adaptive sliding mode controller design for uncertain fractional‐order nonlinear systems with time delay and input nonlinearity

In this paper the problem of non‐fragile adaptive sliding mode observer design is addressed for a class of nonlinear fractional‐order time‐delay systems with uncertainties, external disturbance, exogenous noise, and input nonlinearity. An H_∞ observer‐based adaptive sliding mode control considering the non‐fragility of the observer is proposed for this system. The sufficient asymptotic stability conditions are derived in the form of linear matrix inequalities. It is proven that the sliding surface is reachable in finite time. An illustrative example is provided which corroborates the effectiveness of the theoretical results.     

Fast method for SAR echo simulation of a three-dimensional ground scene

Due to huge calculation of SAR echo simulation of a three-dimensional (3D) ground scene, a fast simulation method is proposed. First, the data of a 3D ground scene are fractionally interpolated based on the Fractional Brownian Motion (FBM) model. Second, the data interpolated are divided into lots of small facets whose precision meets the simulation requirement, the backscattering coefficients of the small facets are calculated. Third, the shaded area is judged by the comparison method of overlook angles. Three parallel levels are analyzed and the kernel function is designed. Finally, the computing method of reduction adding and external thread are also utilized under the framework of GPU in order to get high efficiency. With the methods mentioned above, the imaging result of experimental DEM data verifies the validity and superiority of the proposed method.     

基于投影浸入边界法的流固耦合计算模型

针对建立的刚体和流体相互作用的浸入边界法数学模型,借助求解不可压缩N-S方程组的分步投影方法的思想来求解基于浸入边界法的耦合系统方程.在空间离散上,对流项采用Quick格式,扩散项采用中心差分格式.时间推进采用显式欧拉法,固体对流体的作用力源项引入流体体积(VOF)方法中的体积比函数,通过龙贝格算法高效求解每个网格单元中浸入刚体所占的体积比.利用VC++编写投影浸入边界法的数值计算程序,并以单圆柱绕流为基准数值算例,通过与其他文献和实验结果的对比,验证了数值计算结果的准确性和可靠性,并进一步分析了不同雷诺数下圆柱绕流场的涡结构分布特征.