世界PVC产业在调整中发展

本文简要介绍了近几年美欧日等主要工业发达国家聚氯乙烯(PVC)生产商的重组、兼并以及强强联合的情况,世界PVC10大生产商的排名,以及西欧、日本PVC生产商和产量,同时预测了世界各地区PVC的增长情况。     

球状碳单质分子的发现,研究现状及应用前景

综述了碳的第三种同素异形体──球状碳单质分子的发现、结构、性质及其应用前景。     

Ultrasonic study of molecular association of poly(vinyl chloride) solution in tetrahydrofuran

Ultrasonic absorption, velocity, adiabatic compressibility, relaxation time and relaxation amplitude measurements are reported on poly(vinyl chloride) (PVC) solution in tetrahydrofuran (THF) using pulsed ultrasonic apparatus operating at 2 MHz and 313 K. Results show a linear increase of velocity. density, viscosity, absorption coefficient, relaxation time and relaxation amplitude values with the increase of PVC concentration in THF. In contrast the compressibility decreases with increasing PVC concentration. This suggests interaction between PVC and THF molecules.     

镀锌层上有机物无铬钝化涂层的耐蚀性

选择了一种无毒的水溶性丙烯酸树脂（AC）加入至钼酸盐、磷酸盐中（M）得到一种钝化液（ACM），对镀锌层进行钝化处理以代替有毒的铬酸盐钝化。通过盐雾试验、扫描电镜、电化学测试等手段，研究了该纯化膜的耐蚀性及耐蚀机理。结果表明，热浸镀锌层采用该无毒钝化液进行钝化，可以推迟镀锌层出现白锈的时间，其抗蚀性已接近铬酸盐钝化水平；ACM钝化膜耐蚀性的提高是由于钝化膜中的钼酸盐与丙烯酸树脂产生交联作用，抑制钝化膜裂纹的扩展，同时由于膜层中钼酸盐的缓蚀作用，提高了镀锌层的抗蚀性。     

催化氧化法合成脂肪醇醚羧酸盐的研究进展

详细介绍了氮氧自由基催化氧化法和贵金属催化氧化法合成脂肪醇醚羧酸盐。氮氧自由基催化时,反应温度20～60℃,反应时间3～6 h,得到酸型产品。贵金属催化剂中,钯的催化活性比铂高。贵金属催化时,加入铅、铋等助催化剂,并以活性炭为载体,碱性条件下于50～90℃反应2～6 h,得到盐型产品。在适当的条件下,这两种方法均可使醇醚转化率达95％,选择性达90％以上。     

丙烯酸酯类助剂ACR的生产简况及市场分析

概述了ACR的功能、生产简况及市场趋势。     

A singular loop transformation framework based on non-singular matrices

In this paper, we discuss a loop transformation framework that is based on integer non-singular matrices. The transformations included in this framework are called Λ-transformations and include permutation, skewing and reversal, as well as a transformation calledloop scaling. This framework is more general than existing ones; however, it is also more difficult to generate code in our framework. This paper shows how integer lattice theory can be used to generate efficient code. An added advantage of our framework over existing ones is that there is a simple completion algorithm which, given a partial transformation matrix, produces a full transformation matrix that satisfies all dependences. This completion procedure has applications in parallelization and in the generation of code for NUMA machines. This work was supported by the Cornell Theory Center, NSF Presidential Young Investigator award #CCR-8958543. by NSF Grant #CCR-9008526, and by a grant from the Hewlett-Packard Company.     

基于交流比例积分控制器的单相逆变器

提出一种电感电流、输出电压瞬时值反馈控制和负载电流前馈控制相结合的复合控制策略。在此基础上,研制了一台800W的单相逆变器。实验结果表明,提出的控制策略改善了逆变器输出电压的波形,提高了系统的暂态特性。     

基于Vega粒子系统的自由大气分子运动虚拟仿真

在军事训练中,三维仿真的战场环境发挥了极为重要的作用。本文将对战场环境中的自由大气进行虚拟仿真。首先分析自由大气中运动分子的性质,详细介绍在模拟不规则自然现象中运用最多的粒子系统技术,最后在Vega中运用粒子系统对大气分子的运动进行模拟仿真。仿真结果能基本模拟出大气分子的运动特性,且可以通过接口编程访问粒子的属性,从而能在无人机等航迹规划的危险天气现象的规避中加以运用。     

Study of viscosity of mono-, di-, and trialkylamines

Viscosities of several mono-, di-, and trialkylamines have been measured in the temperature range 298 to 333 K. It is observed that viscosities are highly dependent on shape, size, and association through H-bond or through dipole. Following the transition state theory, energy, Gibbs free energy, and entropy of activation of viscous flow have been calculated. The values of expansion energy for these liquids have also been calculated using free volume theory, and subsequently amines have been classified as volume-restrained or energy-restrained liquids. The group contribution method of Van Velzen, Cardozo, and Langenkamp for estimating viscosity has been examined with the present and literature data, and the new group contribution increments N _i and B _i for amines have been evaluated.