从假性紫罗兰酮合成β-紫罗兰酮中主要副产物(I)的分离鉴定

假性紫罗兰酮在浓硫酸及 - 2 0°C低温条件下反应 ,主要生成 β-紫罗兰酮 ,少量的 α-及 γ-紫罗兰酮 ,同时生成副产物 ( I)及 ( II)。用 IR、1H NMR及 MS光谱分析方法 ,对副产物 ( I)进行了结构鉴定 ,结构为 3,4,4a,5 ,8,8a-六氢 - 2 ,5 ,5 ,8a-四甲基 - 2 H - 1 -苯并吡喃     

Can isotopic transient and formal steady-state kinetics lead to a converging surface chemistry analysis? Case study on the selective reduction of NO by CH4 over Co-ZSM-5 catalysts

The surface coverage analysis derived from two formal steady-state kinetic models is compared to values directly obtained from steady-state isotopic transient analysis (SSITKA) for the selective catalytic reduction (SCR) of NO by CH₄ over Co-ZSM-5 catalysts. It is shown that the most abundant reacting intermediates are NO _x adspecies, though no clear differentiation between the various adspecies identified by DRIFT spectroscopy was achieved. Less numerous carbon containing adspecies were identified and quantified in the reacting system, essentially as methoxy species. Nitromethane-like intermediates remained undetectable due to a very rapid transformation into N₂ and CO₂. On the basis of these converging kinetic analyses related to each elementary step of the SCR process, a microkinetic model can be derived, which allows describing transient operation, in view of a non steady-state application.     

15万t/a双甲氨合成联合装置设计

从工艺路线的比较、压力等级的选择、主要设备的选型等方面阐述了双甲氨合成联合装置的设计特点。结合生产运行实践,分析了双甲氨合成工艺路线的运行参数,与采用不同工艺的生产消耗和产品成本进行了对比。结果表明,该工艺吨氨节约成本80元,精醇成本为1112.6元/t,经济效益显著且生产运行稳定。     

裂缝-溶洞型碳酸盐岩水驱油机理研究现状

裂缝-溶洞型碳酸盐岩的油水两相流动形态复杂,本文针对此类油藏水驱油机理研究做了大量的文献调研,阐述了此类油藏的水驱油机理研究现状,并提出新的试验研究方法和建议,以进一步加深对这类油藏驱油理论的认识。     

水利血防工程中生态抑螺护岸设计与应用初探

传统的水利血防工程采用硬质护岸形式,极大程度地影响了河道生物多样性。依托某水利血防工程,在对河道附近水位站潮位资料统计排频的基础上,给出了常规硬质护岸的设计方案。结合植物抑螺理念,设计出一种生态型的抑螺护岸。并将不同抑螺植物组合设置成三个生态抑螺护岸试验段。通过现场调查比较,硬质护岸和生态抑螺护岸都能起到灭螺效果,相对于硬质护岸河流景观单一化,生态抑螺护岸更贴近自然,三个生态护岸试验区中,以密毛酸模叶蓼为挺水植物,以益母草为草本植物的实验段植物存活率更高。     

聚丙烯塑料循环利用技术

简要回顾了国内外聚丙烯(PP)塑料回收利用的发展情况．对分选利用、简单再生、降解、共混和燃烧等常用方法进行了论述，分析了PP回收利用的技术和经济可行性。     

针铁矿法沉铁过程亚铁离子浓度预测

针对针铁矿法沉铁过程出口亚铁离子浓度离线化验获得,存在很大滞后性,难以实现沉铁过程实时控制的问题,研究反应器出口亚铁离子浓度在线预测方法.本文在分析沉铁过程化学反应机理的基础上,考虑铜离子对反应过程的影响,结合连续搅拌反应器（Continuous stirred tank reactor,CSTR）特性,建立了针铁矿法沉铁过程的机理模型,并提出了基于信息交换的双粒子群搜索算法（Double particle swarm optimization,DPSO）优化选择机理模型的参数,构建基于最小二乘支持向量机（Least squares support vector machine,LS-SVM）的机理模型输出误差的补偿模型,采用并联补集成方式建立了亚铁离子浓度的集成预测模型.工业现场数据验证了所建模型能有效地反映亚铁离子浓度的变化趋势,为针铁矿法沉铁过程的优化控制奠定了基础.     

Activation of a Au/TiO2 Catalyst by Loading a Large Amount of Fe–Oxide: Oxidation of CO Enhanced by H2 and H2O

Catalytic activity of a 1 wt% Au/TiO₂ catalyst is markedly improved by loading a large amount of FeO_x, on which the oxidation of CO in excess H₂ is selectively promoted at temperature lower than 60 °C. Oxidation of CO with O₂ on the FeO_x/Au/TiO₂ catalyst is markedly enhanced by H₂, and H₂O moisture also enhances the oxidation of CO but its effect is not so large as the promotion by H₂. We deduced that activation of Au/TiO₂ catalyst by loading FeO_x is not caused by the size effect of Au particles but a new reaction path via hydroxyl carbonyl intermediate is responsible for the superior activity of the FeO_x/Au/TiO₂ catalyst.     

用DCS顺控实现电除尘自动控制

介绍一种对电除尘工序进行远程自动控制的方法。使用DCS顺序控制图，通过模块组态和内部编程，实现多台设备的自动控制，优化工艺过程，提高该工序的自动化水平。     

实施电石法PVC生产过程中的循环经济

介绍了电石法聚氯乙烯生产过程中水、尾气和电石渣的循环利用及超低含量氯化汞触媒的使用情况。提出了要以“减量化、再利用、资源化”为原则,实现低消耗、低排放、高效率的循环经济。