Production of high purity APT from scheelite and complex tungsten raw material with high Mo content

More than 73% of the tungsten resources in China are scheelite and 41% are high molybdenum content ores, and their dressing becomes increasingly difficult. Such situation calls for new and advanced processes that can treat complex ores and still attain high overall recovery of tungsten. The novel NaOH digestion process and selective precipitation process was developed. The former is universal for leaching tungsten from various tungsten materials,including scheelite concentrate and keeps most of the impurity elements P, As and Si in residue; while the latter is effective for removing impurities such as Mo and Sn. Combined with the traditional ion exchange process, the new process can be used to produce APT that confirms with the Chinese National Standard GB10116-88APT-0 with crystallization ratio of 95%. When treating high molybdenum scheelite concentrate from Shizhuyuan Deposit with WO3 content of 50%-55%, recovery of the new process may reach up to about 95% which is grossly the same as that from the traditional way for treating standard wolframite concentrates.     

断路器机械特性及参数检测装置

论文介绍了所研制的断路器三相同步性检测装置,以国产DBA、DBG、DBB等九种断路器为研究对象,选用工控机、伺服电机、力传感器和高速数据采集卡设计了一套数据采集、处理系统,完成对其分合闸机械特性参数、力变化曲线和过程曲线的自动测量、显示、存储查询及打印,检测功能全、速度快、精度高,可以将断路器诸多机械特性的测量集于一体,大大简化了测量过程,节省人力物力.最后对其测量结果及适用性作了分析和评议.     

铸态高韧性球铁QT400-18的生产应用技术

为了稳定生产铸态QT400-18、厚壁100～200 mm的高炉冷却壁铸件,通过生产试验与调整,控制化学成分(ω):C=3.35%～3.80%,Si=2.5%～2.9%,Mn≤0.2%,P≤0.055%,S≤0.025%;冲天炉熔炼,采用球铁专用生铁和铸造焦,出铁温度1 500℃;采用低稀土FeSiMg8RE3球化剂进行球化处理,75SiFe在包内、出铁槽、浮硅及随流等多次孕育,获得铸态强度δb≥430 MPa,伸长率≥20%的铸态球铁铸件.     

呋喃树脂自硬砂在纺织机械铸铁件上的应用

介绍呋喃树脂自硬砂在纺织机械类铸铁件生产中的实际应用，详细阐述了原材料选取，呋喃树脂自硬砂制备工艺、造型与制芯等工序的操作要点及应用实例，分析了呋喃树脂自硬砂代替普通粘土干型砂工艺的利益所在。     

Synthesis mechanism of titanium carbide nano-fiber during self-propagating high temperature synthesis

Titanium carbide nano-fiber was synthesized by self-propagating high temperature synthesis (SHS) method. The final products after the SHS reaction were titanium carbide containing excess carbon and metallic titanium, which were removed by additional leaching process. TEM observation revealed that the average diameter is about 20 nm. Neutron diffraction analysis was carried out to study non-stoichiometric number of the titanium carbide. The non-stoichiometric numbers of the titanium carbide were 0.89–0.94. The Rietveld refinement of each patterns converged to good agreement (÷2=0.49–1.34). The formation mechanism of the carbide is related to a liquid-solid reaction including the preferential diffusion process of carbon atom into liquid titanium. This article is based on a presentation made in the 2002 Korea-US symposium on the “Phase Transformations of Nano-Materials,” organized as a special program of the 2002 Annual Meeting of the Korean Institute of Metals and Materials, held at Yonsei University, Seoul, Korea on October 25–26, 2002.     

回火温度对Cr-Mo-V系高强度钢力学性能的影响

回火温度对Cr-Mo-V系高强度钢力学性能的影响并非单调变化，在低于500℃时，随着回火温度的升高，实验钢的硬度，强度和应变硬化指数降低，塑性和韧性提高，在500-630℃的温度范围内，由于二次硬化效应，实验钢的硬度，强度和韧性变化不大，对单轴拉伸实验过程的能量分析表明，在450℃附近回火时有一能量低谷，而在585℃附近回火时有一能量高峰。在单轴拉伸状态下，断裂受裂纹扩展控制。     

BHRB600热轧高强韧树脂锚杆钢筋的开发

为满足对高强韧矿用树脂锚杆钢筋的需求，山东石横特钢集团有限公司通过合理的化学成分及生产工艺设计，成功地开发出以σ8〉600MPa、δ5〉18％、AK〉25J的优质树脂锚杆钢筋。该钢筋在煤矿巷道中支护效果明显，可比普通强度锚杆钢筋用量减少5％以上。     

电工钢钢包渣结壳问题分析

针对电工钢生产过程中钢包渣结壳的现象,与不结壳渣进行对比,从物质的组成,物相和黏度等3个方面进行了分析。结果表明,随着温度的降低,炉渣中析出大量的高熔点物相如MgO、尖晶石(MgO·Al₂O₃)、2CaO·SiO₂等,在炉渣中起到“钉扎”强化作用的同时又能导致炉渣的黏度增加,失去流动能力,从而容易黏附在一起结块成壳。此外,提出了预防钢包渣结壳的有关措施。     

304不锈钢在高温水中的应力腐蚀破裂SCIEI

采用U型弯曲法应力腐蚀破裂试验、电化学测量以及Auger电子能谱(AES)分析方法研究了温度、氯离子浓度和溶解氧含量在高温水中对304不锈钢的应力腐蚀破坏(SC)敏感性的影响及其与表面膜之间的关系。在空气饱和的高温水中(溶解氧为8ppm),随着温度的升高(200—300℃)或氯离子浓度的降低(500—20ppm)304钢SCC敏感性降低。文中还讨论了氧化膜在SCC萌生和扩展中的作用。     

热处理对高钒高速钢中残余奥氏体量的影响

采用铁磁性法测定了高钒高速钢中残余奥氏体量。研究了淬火温度和回火温度对高钒高速钢残余奥氏体量的影响。结果表明：淬火加热温度升高，残余奥氏体量增加；回火温度升高，残余奥氏体量降低。在试验淬火温度范围(900～1100℃)内450℃以下回火，奥氏体含量变化不明显；回火温度达到550℃时，残余奥氏体含量迅速降低。