Rheology of cementitious paste with silica fume or limestone

The rheological behaviour of cementitious pastes where cement has increasingly been replaced by densified silica fume (SF), untreated SF or limestone has been studied. The effect of SF on the flow resistance, taken as the area under the flow curve, was found to depend on the dispersing ability of the plasticizer as illustrated by pastes with naphtalene sulphonate-formaldehyde condensate (SNF) and polyether grafted polyacrylate (PA).The gel strengths increased with increasing SF replacement of cement independently of plasticizer type. The cementitious gel strength was, however, depending on the type of SF since pastes with densified SF developed lower gel strengths than pastes with untreated SF. This phenomenon was attributed to agglomerates in the densified SF which remained unbroken by the mixing and measurement sequence.Both flow resistance and gel strength decreased with increasing limestone replacement. Thus, silica fume may have an advantage over limestone filler as stabilizing agent for self-compacting concrete preventing segregation upon standing and reduced form pressure due to a more rapid gel formation.     

筏板基础在自贡地区高层建筑设计中的应用研究

文章结合工程设计经验对自贡地区的高层建筑在选用天然筏板基础的设计过程中,对高层建筑基础设计中涉及到的重要的地基沉降计算、结构设计和地下水等有关问题的处理进行了具体分析,对在一般高层建筑中采用天然筏板基础的实用性和可行性从设计和施工两个方面进行了相关的工程探讨。     

Progress and recent trend in MILD combustion

Moderate or intense low oxygen dilution(MILD)combustion plays a significant role in the mitigation of combustion-generated pollutants and greenhouse gases whilst meeting thermal efficiency needs.However,due to the lack of the fundamental knowledge on this combustion,there is a misconception that MILD combustion should be established by high preheating of the air,which has limited its application.Our research and development on this combustion has been performed for several years. We have found that the requ...     

因子分析法和熵值法在高校科技创新评价中的应用

在已有研究的基础上总结出了一套科学合理并具有可行性的高校科技创新评价指标体系,并把因子分析法和熵值法应用于高校科技创新评价.首先对高校科技创新评价体系的5个一级指标分别进行因子分析,然后运用熵值法对其确定权重.分析结果表明两种方法的结合使用能够简化分析对象的结构,使评价结果更具科学性、客观性.     

以尿素为氮源的高氮复合肥生产技术

笔者根据多年的实践经验 ,阐述以尿素为氮源 ,生产高氮〔w(N)≥ 2 0 %〕复肥的现实意义及生产技术要点 ,具体介绍 2个高氮复肥 (2 30 7)、(2 0 10 15 )的配方实例及操作要点     

乳胶涂料中填料粒径测定与分散剂的选择

介绍了重力沉降法和容量沉降法两种测定乳胶涂料中填料粒径的方法。通过比较粉体粒径结果显示：沉降法比激光法更形象直观，更能代表体系粒径真实情况。以滑石粉、重钙、轻钙粉体为基准，采用不同用量、不同类型的分散剂的容量沉降法进行比较得出：用容量沉降法能定量地对分散剂性能做出评价。     

世界溶液丁苯橡胶的主要技术进展

评述了溶液丁苯橡胶的技术现状和主要技术进展。介绍了新型锡锂引发剂和用其制备的溶液丁苯橡胶的性能特点，特别是其突出的滚动阻力特性和在不损失湿牵引性下的优异耐磨性。分析了世界，特别是美国、欧洲和日本的溶液丁苯橡胶的需求现状及发展趋势。     

二氰基取代的四硫富瓦烯硫杂冠醚衍生物的合成及性质研究

在甲苯溶液中,在亚磷酸三乙酯存在下,采取高度稀释的方法,使4,5-二氰基-1,3-二硫杂环戊二烯-2-酮分别和多缩硫杂冠醚进行交叉偶联反应,成功地得到了不对称的2,3-二氰基四硫富瓦烯衍生物。用1HNMR、MSI、R和EA表征了其结构,并用循环伏安法研究了它们的电化学性质,用1HNMR初步评价了衍生物对钠离子的配合性能。     

Intergranular oxidation of silicon in 20Cr-25Ni niobium-stabilized stainless steel at 1140–1230 K

The kinetics of intergranular oxidation of silicon in a 20Cr-25Ni Nb-stabilized stainless steel are reported, at temperatures in the range 1140–1230 K, in CO₂ at 40 bar pressure. The depth of attack increased parabolically with respect to time, with an activation energy of 335±30 kJ/mol. The mechanism of growth is discussed in terms of classical internal-oxidation theories, and an alternative explanation based on an available-space theory is developed. The internal oxidation rates in a number of different alloys are compared with diffusivities of metals in the base alloy. It is proposed that intergranular oxidation in the 20–25 Nb steel is controlled by the rate of outward diffusion of iron or chromium in the alloy.