加氢裂化反应器新型冷氢箱的研究与工程设计

报道了加氢加化反应器新型旋流式冷氢箱的研究设计及实用效果，催化剂床层径向温差不大于5℃。     

基于神经网络的河道浅滩演变预测模型

河道浅滩演变是一个复杂的非线性动力学过程, 作者借助神经网络处理非线性问题的优势, 在分析影响河道浅滩演变因素的基础上, 建立了预测河道浅淮演变的BP网络模型, 并对模型中的输入因子和样本的提取进行了探讨. 以闽江竹岐至侯官河段为实例,用“试控法”给出了BP网络模型的建模方案, 用正交设计原理选取相应的训练样本集, 利用该样本集对网络进行学习和训练, 并用训练好的BP网络模型预测浅滩上年内最小水深和年平均淤积厚度. 计算结果表明: 模型预测结果与实际值吻合良好. 这为河道浅滩演变预测研究提供了新方法.     

Electron-Impact Cross Sections for Dipole- and Spin-Allowed Excitations of Hydrogen,Helium, and Lithium

Electron-impact excitation cross sections are presented for the dipole- and spin allowed transitions from the ground states to the np ²P states for hydrogen and lithium, and to the 1snp ¹P states for helium, n = 2 through 10. Two scaling formulas developed earlier by Kim [Phys. Rev. A 64, 032713 (2001)] for plane-wave Born cross sections are used. The scaled Born cross sections are in excellent agreement with available theoretical and experimental data.     

A Method of Combined SHPB Technique and BP Neural Network to Study Impact Response of Materials

Abstract:  A new method combining the split Hopkinson pressure bar (SHPB) technique with the back-propagation (BP) neural network program is proposed. By this method, the treated strain wave signals become smooth with less noises induced by the transverse inertia. Moreover, the dynamic rate-dependent constitutive behaviour of materials can be identified, without any pre-assumption of a constitutive model. It is found that by taking the experimentally measured data of strain, strain rate and time as 'input' and the corresponding data of stress as 'output' of the BP neural network, the dynamic constitutive behaviour with internal damage or phase transformation evolution is easy to be identified, where the time could represent either the internal damage evolution or phase transformation process accompanied with the deformation process. It is emphasised that the data learnt by the BP neural network must include both loading and unloading processes, if the whole loading and unloading response is to be correctly predicted. The comparisons between the predictions and experimental results are in good agreement for both polyamide (PA) polymer (as an example of nonlinear viscoelastic materials) and Ti–Ni alloy (as an example of superelastic materials with stress-induced phase transformation).     

钛及钛合金中氧和氢的联合测定

叙述了用红外吸收法对钛及钛合金中氧和氢联合测定的方法，取得了测定的最佳条件。连续测定6次的相对标准偏差在10％以下，作加标回收试验的回收率为95．6％～103．9％。分析时间在3min以内，可应用于日常分析，结果满意。     

Procedure for Measuring Low Concentrations of H2 and H2S Above a Water Surface

A simple measuring procedure for low concentrations of H₂ and H₂S (at the level of ppm fractions) above the surface of water by using sensitive gas analyzers is suggested. The procedure is easily accomplished in conditions outside the laboratory (under field conditions).     

管内材料高温放气性能的测试及应用研究

管内材料放气性能的优劣直接影响着整管的性能和寿命.本文简介了测试管内材料高温放气性能的原理、装置和方法.文中列举的几项应用实例表明,本项测试结果对产品质量控制、工艺技术改进和材料进厂检验及国产化攻关都具有指导意义.     

高强度钢的Zn—Ti合金新镀层

本文研究了一种Ｚｎ－Ｔｉ合金新镀层，经盐水浸泡、中性盐雾和大气暴露试验结果试验，其耐蚀明显超过镀Ｚｎ层，并与镀Ｃｄ层相近，用缺口持久拉伸试验检验氢脆性，拉伸持续时间超过２００ｈ，达到原航空部部颁标准（ＨＢ５０６７－８５），该镀层适用于高强度钢防护。     

有机介质中合成二硫化钛

本文研究了硫化氢与四氯化钛在某些有机介质中的反应，并提出了一个合成二硫化钛的新方法。该法是将干燥的硫化氢通入沸腾的四氯化铁的α－氯代萘溶液中，使硫化氢和四氯化钛发生复分解反应而生成二硫化钛。方法简便易行。Ｘ－射线物相鉴定及化学分析结果表明，产物为单一物相的、符合化学计量的二硫化钛。     

Prebiotic synthesis of sequential peptides on the Hadean beach by a molecular engine working with nitrogen oxides as energy sources

Addressing the still open question of the prebiotic origin of sequential macromolecules (peptides, nucleic acids) on the primitive Earth, we describe a molecular engine (the primary pump), which works at ambient temperature and continuously generates, elongates and complexifies sequential peptides. This new scenario is based on a cyclic reaction sequence, whose keystep is the activation of amino acids into their N‐carboxyanhydrides (NCA) through nitrosation by NOx. This process could have taken place on tidal beaches; it requires a buffered ocean, emerged land and a nitrosating atmosphere. With the help of geochemical studies and computer simulations of atmosphere photochemistry, we show that the primitive Earth during the Hadean may have satisfied all these requirements. © 2001 Society of Chemical Industry.