真空钙热还原炉渣的综合利用研究

研究了从真空钙热还原炉渣中回收稀土的工艺条件；采用本工艺得到的合格稀土溶液，其回收率达65．41％；副产品氟化钙用作炼硅铁合金的助熔剂，使钙热还原炉渣得到综合利用。     

An inverse solution methodology for estimating the diffusion coefficient of gases in Athabasca bitumen from pressure-decay data

An inverse solution methodology is developed for the estimation of diffusion coefficient of gases in highly viscous, oil-sands bitumens from isothermal, pressure-decay measurements. The approach involves modeling the rate of change in pressure using the diffusion equation for the liquid phase coupled with a mass balance equation for the gas phase. The inverse solution framework is utilized to arrive at two graphical techniques for estimating the diffusion coefficient. Both techniques involve the determination of the slope of a straight line resulting from plotting the experimental data in accordance with the developed model. An advantage of the proposed techniques is that the diffusion coefficient is estimated directly, i.e. without making it an adjustable parameter. The novelty of the proposed method is in its simplicity as well as its ability to isolate portions of the pressure-decay data affected by experimental fluctuations. The effect of the initial pressure on the predicted diffusion coefficient and pressure-decay profile was also investigated. The diffusion coefficients of CO₂, CH₄, C₂H₆ and N₂ in Athabasca bitumen at 50–90 °C and about 8 MPa were estimated and compared with literature values.     

开放的ladder型无反转激光系统的稳定性分析

利用开放的ladder型无反转激光系统的密度矩阵运动方程组的定态解和激光场运动方程分析了系统的稳定性。结果表明：如果增益大于激光腔损耗，则零解是不稳定的；如果增益小于激光腔损耗，则零解是稳定的；如果增益大于激光腔损耗，则非零解是稳定的。     

Boundary knot method for 2D and 3D Helmholtz and convection–diffusion problems under complicated geometry

The boundary knot method (BKM) of very recent origin is an inherently meshless, integration‐free, boundary‐type, radial basis function collocation technique for the numerical discretization of general partial differential equation systems. Unlike the method of fundamental solutions, the use of non‐singular general solution in the BKM avoids the unnecessary requirement of constructing a controversial artificial boundary outside the physical domain. The purpose of this paper is to extend the BKM to solve 2D Helmholtz and convection–diffusion problems under rather complicated irregular geometry. The method is also first applied to 3D problems. Numerical experiments validate that the BKM can produce highly accurate solutions using a relatively small number of knots. For inhomogeneous cases, some inner knots are found necessary to guarantee accuracy and stability. The stability and convergence of the BKM are numerically illustrated and the completeness issue is also discussed. Copyright © 2003 John Wiley & Sons, Ltd.     

A new bubble-point-pressure correlation for the binary LiBr/H2O solution

In accord with the increasing concern about the global environmental issues, the absorption refrigeration heat-pump systems are currently being considered very promising and attractive. For the purpose of supporting the advanced R&D technology in this area, we have developed a novel correlation to represent the bubble-point pressures of LiBr H₂O solutions. The developed correlation covers the most extensive range of validity ever proposed: 273–483 K for temperatures, 0.05 kPa to 1.0 MPa for pressures. and 29 76 wt% LiBr for concentrations.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994. Boulder, Colorado, U.S.A.     

Substituted uracils as corrosion inhibitors for copper in 3% NaCl solution

Substituted uracils were tested as corrosion inhibitors of copper in 3% NaCl medium using electrochemical polarisation, impedance measurements and non-electrochemical techniques (weight loss, IR and UV-visible). This study permitted to follow the evolution of the inhibitory effect of the uracil derivatives, according to their substituents, on copper in 3% NaCl medium. Comparison of results showed that dithiouracil (DTUr) was the best inhibitor. The maximum inhibition efficiency reached 98% at 10⁻³ M. DTUr adsorbs on the copper surface according to the Frumkin isotherm model.     

具有偏差变元的Volterra型系统的周期正解

利用Mawhin重合度理论研究了一类具有偏差变元的Volterra型系统周期正解的存在性问题，得到了一个新的存在性定理。     

THE FLOW PRODUCED IN PARTICLE-SUSPENSION BY AN INFINITE ROTATING DISK:SERIES SOLUTION

To the flow produced in particle-suspension by a rotating disk of infinite extent,the asymptotic behavior at infinity is analyzed.A corresponding series solution is presented.It isshown that this approach yields widely valid solutions of high accuracy for all the cases in whichthat suction or weak injection at the disk surface exists.For the cases that strong injection or par-ticle-free band exists,the series method fails.     

聚电解质溶液分子热力学模型

<正>链状聚电解质由于是长链大分子又有很高的电荷密度,其溶液即使在极低的浓度下仍具有很强的负偏差,与Debye-Huckel理论预测的结果相去甚远。工程上使用的Manning模型认为聚离子的电荷密度有一临界值,当超过临界值时,反离子即凝聚在聚离子表面使其实际电荷密度降至临界值。Nagvekar等在该模型的基础上引入NRTL方程,以计及短程相互作用的贡献。Manning等的方法虽然有一定的物理意义,但临界值的确定缺乏可靠的根据。