应用频率-初速法测试推算单桩承载力须解决的几个关键问题

本文对当前频率 -初速法应用中存在的一些问题阐述了作者的看法并着重探讨桩振初速度V0的计算方法、W0 的正确单位、如何使桩 -土体系明显震动、怎样从激振曲线中突出及分离出桩振曲线 ,从而获得正确的桩振频率f0 和首波峰 -峰值Ad、动静对比系数 βv 的选取     

Micromechanical characterisation of fibre/matrix interfaces

Theoretical analyses for the single fibre pull-out and push-out models under monotonic loading are given which are based on a shear-lag analysis in a fracture mechanics approach considering non-constant friction at the debonded interface as a result of fibre Poisson contraction (or expansion). The solutions allow the determination of typical fibre/matrix interfacial properties such as the interfacial fracture toughness, G_ic, the coefficient of friction, μ, and the residual clamping stress, q₀. Under cyclic loading the interfacial properties are expected to degrade as a result of repetitive abrasion, and a power law function is assumed between μ and the number of elapsed cycles, N. However, G_ic is assumed to be unaffected and a fracture mechanics based debond criterion is derived for the relationship between the external applied stress, the debond length and the reduced friction coefficient for both fibre pull-out and fibre push-out. In addition, the relative displacements between the free fibre end and the matrix top are obtained for cyclic fatigue when the fibre is loaded and unloaded. A relationship obtained for the protrusion (or intrusion) length in fibre pull-out (or push-out) experiments allows the severity of the interface frictional degradation to be evaluated and characterised. Similarities and differences in the frictional degradation behaviour between fibre pull-out and push-out are also identified.     

鱼雷捷联系统动基座精对准的卡尔曼滤波法

为解决鱼雷捷联系统的初始对准，提出了失准角及陀螺随机常值漂移快速估计方法，经数字仿真，对缩短初始对准时间，提高初始对准精度有较好的效果。     

剂量率对聚四氟乙烯辐射裂解的影响

本文研究了在以电子加速器的电子射线为辐射源时,剂量率对PTFE辐射裂解的影响。在剂量相同的条件下,剂量率从1.44×10~4 rad/s增至5.75×10~4 rad/s,裂解效率提高3.3倍。剂量率和各断裂参数(单位剂量裂解度a_0,G(s)值等)均成线性关系。当裂解度一定时,剂量率与剂量成反变关系。     

Thermogravimetry and wide angle X-ray diffraction study on the structure of irradiated and thermally treated kodar film

The degradation behaviour of Kodar [poly(1,4-cyclohexylene dimethyl-eneterephthalate)] was investigated in air using thermogravimetry, differential thermal analysis and wide angle X-ray diffraction studies. The rates of crystallization and degradation were influenced by thermal exposure and polychromatic irradiation (Λ > 290 nm) for different time intervals. The crystallinity changes (X_c%) and activation energies (ΔE) for the systems have been determined.     

Some experimental findings in compression-after-impact (CAI) tests of CF/PEEK (APC-2) and conventional CF/epoxy flat plates

Compression-after-impact (CAI) tests have been conducted for quasi-isotropic thick plates with 48 plies by using the NASA method and on plates with 32 plies by using the SACMA method. Specimens are made of CF/PEEK (APC-2) and conventional CF/epoxy for the NASA plates and CF/epoxy for the SACMA plates. In the NASA CAI tests, the sequence of delamination buckling and its propagation is clearly revealed through various experimental techniques. One major technique is moiré topography, and the other is thermo-mechanical stress analysis with a high-accuracy infrared sensor. The arrest of delamination propagation just before catastrophic failure due to high fracture toughness is clearly captured by the moiré camera. This behavior provides good CAI values of CF/PEEK. The initial buckling properties of the delaminated region by the impact are then extensively discussed. Numerical predictions of initial buckling stress have been obtained by modelled geometry of the delaminated region simplified from its precise structure clarified by ultrasonic C-scanning. They agree fairly well with the experimental results. The in-plane stress distribution in the delaminated region before initial buckling is measured by an infrared stress graphic system. This compared favorably with finite element predictions. Two types of symmetric buckling modes with respect to the central plate surface, twin and single peak ones, are experimentally captured.     

Improving Thermal Stability of BaMgAl10O17:Eu Phosphor

Heterogeneous precipitation method was used to prepared surface coating on self-made BaMgAl10O17:Eu phosphor. Results illustrate that the coating film can be silicon dioxide in amorphous state with 50 nm in thickness. Photoluminescence results indicate that the coating layer presents an observable improved effect on the enhancement of thermal stability. When baked at 600 ℃ for 1 h, the luminance of coated BAM keeps at 92% higher than that of uncoated BAM by 23%. This protective effect can be attributed to the high compact degree and uniformity of this amorphous SiO2 coating film which is served as a diffusion block layer to inbreak oxygen atom, thus releases the oxidation extent of Eu2 effectively.     

Photocatalytic degradation of 2,2‐bis(4‐hydroxy‐3‐methylphenyl) propane (BPP) based on molecular recognition interaction

BACKGROUND: Endocrine disruptors in the aquatic environment and their potential adverse effects are currently issues of concern. One of these endocrine disruptors is 2,2‐bis(4‐hydroxy‐3‐methylphenyl)propane (BPP). In this work the molecular recognition interaction of BPP with β‐cyclodextrin (β‐CD) was studied using IR spectroscopy and steady state fluorescence spectroscopy, and the photocatalytic degradation behaviour of BPP based on molecular recognition interaction was investigated in a TiO₂/UV–visible (λ_max = 365 nm) system. This might provide a new method for the treatment of some organic pollutants in wastewater. RESULTS: β‐CD reacts with BPP to form a 1:1 inclusion complex, the formation constant of which is 4.94 × 10³ L mol^?1. The photodegradation rate constant of BPP after molecular recognition by β‐CD showed a 1.42‐fold increase in the TiO₂/UV–visible (λ_max = 365 nm) system. The photodegradation of BPP depended on the concentration of β‐CD, the pH value, the gaseous medium and the initial concentration of BPP. The photodegradation efficiency of BPP with molecular recognition was higher than that without molecular recognition. After 100 min of irradiation the mineralisation efficiency of BPP after molecular recognition by β‐CD reached 94.8%, whereas the mineralisation efficiency of BPP before molecular recognition by β‐CD was only 40.6%. CONCLUSION: The photocatalytic degradation of BPP after molecular recognition by β‐CD can be enhanced in the TiO₂/UV‐visible (λ_max = 365 nm) system. This enhancement is dependent on the enhancement of the adsorption of BPP, the moderate inclusion depth of BPP in the β‐CD cavity and the increase in the frontier electron density of BPP after molecular recognition. Copyright © 2008 Society of Chemical Industry     

Thermal stabilization effect of biphenol monoacrylate on polyamide 6

Biphenol monoacrylate (AL) was combined with a traditional hindered phenolic‐based binary antioxidant system to form a ternary stabilization system for the purpose of further improving the thermal–oxidative stability of polyamide 6 (PA6). The thermal stabilization effect of the antioxidant AL on PA6 was studied in terms of the reduced viscosity, the chemical structure, the yellow index, and the mechanical properties. The results showed that the antioxidant AL, with the proper chemical structure, could improve the thermal stability of PA6 effectively through a unique bifunctional stabilizing mechanism. The interaction of the molecules of PA6 with the antioxidant AL was investigated. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Microstructural investigation of long-term degradation mechanisms in GFRP dowel bars for jointed concrete pavement

Steel dowel bar is used to transfer loads in concrete pavement slab. However, once the steel dowel bar corrodes, it may cause faults, such as joint freezing in concrete pavement, level differences resulting from spalling or decreased efficiency of load transfer, etc., which are the same problems experienced by typical reinforcing steel. This study evaluated the applicability of glass fiber-reinforced polymer (GFRP) dowel bar as a substitute for steel dowel bar. A microstructural analysis was conducted to examine the decrease in durability of GFRP dowel bar exposed to deterioration environments. To analyze the deterioration mechanism of GFRP dowel bar, scanning electron microscopy was employed and the porosity was measured by the gas absorption method. It was concluded that the longer the GFRP dowel bar was exposed to deterioration environments, the more the interlaminar shear stress decreased. This result was validated by the microstructural analysis. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008