稀土Eu~(3+)与牛血清白蛋白配合物合成及其分子光谱表征

研究了稀土 Eu3 +与牛血清白蛋白 ( BSA)的固体配合物合成方法 ,产物经傅里叶红外光谱分析表明 :Eu3 + 与牛血清白蛋白羧基的氧和胺基或酰胺基的氮形成强烈配位的配合物。在模拟生理条件下研究了 Eu3 + 与 BSA的结合性质。荧光光谱表明 :Eu3 + 与 BSA形成 2 .75∶ 1的配合物 ,表观配位常数为 lg K=1 2 .2 6     

Electrochemical characteristics of phase-separated polymer electrolyte based on poly(vinylidene fluoride-co-hexafluoropropane) and ethylene carbonate

A polymer electrolyte based on microporous poly(vinylidene fluoride-co-hexafluoropropane) (PVdF-HFP) film was studied for use in lithium ion batteries. The microporous PVdF-HFP (Kynar 2801) matrix was prepared from a cast of homogeneous mixture of PVdF-HFP and solvents such as ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC). After evaporation of DMC and EMC, a sold film of the PVdF-HFP and the EC mixture was obtained. EC-rich phase started its formation in the PVdF-HFP/EC film at EC content of about 60 wt.% based on the total weight of PVdF-HFP and EC. The formation of the new phase resulted in the abrupt increase of the porosity of the PVdF-HFP matrix from 32 to 62%. The ionic conductivity of the film soaked in 1 M LiPF₆-EC/DMC=1/1 was significantly increased from order of 10⁻⁴ S/cm to order of 10⁻³ S/cm at the EC content of 60 wt.%. Thermal and spectroscopic investigations showed that most of the EC interact with PVdF-HFP with the EC content being below 60 wt.%. MCMB/polymer electrolyte/LiCoO₂ cells employing the microporous PVdF-HFP polymer film showed stable charging/discharging characteristics at 1C rate and good rate capability.     

微孔发泡过程中聚合物/超临界CO2均相体系形成的研究

阐述以超临界CO2为发泡剂的微孔发泡中均相体系的形成过程，研究聚合物熔体和气体的混合机理，并分析影响均相体系形成过程的因素。结果表明，聚合物和气体本身的结构和性质、工艺条件、加工设备、外力场等均影响均相体系的形成，振动力场的引入可以提高多相体系的混合程度，在聚合物／气体均相体系的形成过程中引入振动力场是一个全新的研究方向。     

螺杆挤压机混合能力的分析

分析螺槽中熔体的流动状态 ,运用加权平均总应变来评价螺杆挤压机的混合能力 ,进而提出提高混合能力的途径。对于单螺纹螺杆 ,稍长的计量段 ,稍浅的计量段螺槽及较高的螺杆转速 ,有利于混合作用 ;开发新型螺杆 ,如犁钉分流混合螺杆 ;研制高效混合型螺杆挤压机 ,如球窝型高效混合型螺杆挤压机     

最小费用最大流问题的一种新算法

现有的最小费用最大流算法都有自身的缺陷,增广链的选取不当会给计算带来不便,同时费用也达不到理想的效果。鉴于对最小费用最大流算法的增广链选取和最小费用的探索,文章通过对费用差的定义给出了一种求最小费用最大流的新算法。新算法的原则是优先选择费用差最小的有向路径进行增广,当费用差相同时就选择修正后的路径。通过对最小费用最大流算法的改进,新算法易理解且便于计算。通过实例说明了新算法的有效性和执行效率。     

基于Android终端的车间数据管理系统的设计

为了适应高校工程训练中心教学管理活动日益强烈的信息化需求,以达到工程训练中心教学管理体系信息化升级目的,文中设计了一种针对高校工程训练中心的车间数据管理系统方案。该系统基于B／S与C／S混合模式,使用带有近场无线通信（NFc）模块的Android智能终端与车间无线组网方式,构建系统功能模块与网络连接模块。经过对系统的实现与运行,验证了该车间数据管理系统有效地降低了服务模块耦合度,增强了系统人机交互能力,使车间数据采集应用更加灵活易用。     

3-D hydrodynamics generated in a stirred vessel by a multiple-propeller system

The aim of this study is to optimize the position and the number of propellers in a non-standard tall vessel. Laser sheet flow visualization experiments were carried out for selected geometrical arrangements which produced stable flow patterns and good transport between the propellers. Four double-propeller arrangements corresponding to frequent industrial cases and a three-propeller system have been chosen. Comparison of LDA measurements in the r-z plane, dimensionless global parameters N_Qp, Nt_m, N_p, E_p and spatial distribution of local energy dissipation rate ? shows that a three-propeller system is the most efficient.     

Hydrodynamics of disturbed flow and erosion—corrosion. Part I — Single-phase flow study

Numerical simulations of turbulent flow have been used to determine the flow structure in a sudden pipe expansion, in order to explain the effects of disturbed flow on mass transfer controlled erosion–corrosion. Previously determined rates of mass transfer through the liquid boundary layer have been directly related to the predicted levels of near-wall turbulence. When rust films are present, the turbulent fluctuations affect both the mass transfer through the boundary layer and the removal of the film. The determining resistance to mass transfer, under the conditions examined, was that of the rust film.     

影响超声波热量表流量测量单元静态时间差因素的探讨

超声波热量表主要包含流量测量单元和温度测量单元两部分,其中流量测量单元主要由传感器管道、反射片保持架、换能器等零部件组成。流量测量单元的静态时间差很大程度决定了热量表整体性能。我们通过大量的标定实验来验证各个要素对测量单元静态时间差的影响。     

基于OPC的钠离子浓度监测系统的研究与设计

针对当前火力发电厂中监控系统存在多系统、多网络协议并存的情况,研究与设计了基于OPC的钠离子浓度监测系统。系统采用LM3S8962为核心处理器,16位高精度无偏差模数转换器AD7705作为AD采样模块,采用Modbus TCP为网络通信协议,设计一个基于Modbus TCP协议的OPC服务器,真正实现钠离子浓度监测系统的智能化、网络化和规范化。