In situ impedance study of the Y-Ni thin film under electrochemical hydrogenation

A thin film of yttrium Y (150 nm) protected by a 6 nm coating of nickel Ni on a glass substrate was completely hydrogenated in a 1 M NaOH electrolyte at a constant negative current until the transparent Y tri-hydride phase was achieved and hydrogen gas evolution from the electrode began. A series of impedance measurements were performed in situ during the electrochemical experiment to study the properties of the system as dependent on hydrogenation degree and time of relaxation. The equivalent electrical circuit (EEC) simulations were performed with a Randles-like scheme R₀[R₁CPE₁], where R₀ is the thin film electrode resistance, R₁ the charge transfer resistance and CPE₁ is the capacitive constant phase element. The behavior of all the components of the EEC undergoes a clear transition when the hydrogenation degree of the electrode is approximated to its maximum value (H to Y ratio 2.7) and electrochemical process changes from hydrogen uptake to hydrogen evolution.     

高分子破乳剂及其在大庆油田的应用实验

本文文综述了中老油田采出液性质的变化和高含水采出液的油水分离特性，探讨了聚醚型破乳剂和高分子破乳剂在高含水采出液状况下的适应性。通过理论分析和大庆两个联合站的现场实验证明，高分子破乳剂特别适用于高含水采出液的事实，并指出了其适应性和提出了其质量与适应性的评价方法。     

集成电路密封用高纯邻甲酚醛环氧树脂的制备

ECN树脂中的可水解氯含量是决定树脂质量的—个重要指标。本文研究了反应温度、ECH/OCN配比、反应时间和碱用量等因素的影响,取得了规律性的认识,并获得最佳配方,制备出高纯度的ECN树脂系列产品。     

浅谈变电运行中等电位倒闸操作的应用

倒闸操作是变电运行的重点和难点工作之一,倒闸操作的正确性直接关系到操作人员的人身安全及设备的安全运行,如果操作不当,将会导致整个电力系统处于崩溃的边缘,其重要性不言而喻。分析了倒闸操作的基本原理和存在的问题,并探讨了变电运行中等电位倒闸操作的具体程序。     

提高小水电线路重合闸成功率探讨

小水电具有无污染、分布广等特点,在农村或偏远山区应用广泛。但小水电难以迅速调节自身的功率,在因故障跳闸而形成孤岛时,容易导致重合闸失败。通过阐述、分析当前小水电并网重合闸的原理和现状,归纳了影响重合闸成功率的相关因素,以期为电网的安全、稳定运行作出贡献。     

Toughening of vinylester–urethane hybrid resins through functionalized polymers

Liquid nitrile rubber, hyperbranched polyester, and core/shell rubber particles of various functionality, namely, vinyl, carboxyl, and epoxy, were added up to 20 wt % to a bisphenol‐A‐based vinylester–urethane hybrid (VEUH) resin to improve its toughness. The toughness was characterized by the fracture toughness (K_c) and energy (G_c) determined on compact tensile (CT) specimens at ambient temperature. Toughness improvement in VEUH was mostly achieved when the modifiers reacted with the secondary hydroxyl groups of the bismethacryloxy vinyl ester resin and with the isocyanate of the polyisocyanate compound, instead of participating in the free‐radical crosslinking via styrene copolymerization. Thus, incorporation of carboxyl‐terminated liquid nitrile rubber (CTBN) yielded the highest toughness upgrade with at least a 20 wt % modifier content. It was, however, accompanied by a reduction in both the stiffness and glass transition temperature (T_g) of the VEUH resin. Albeit functionalized (epoxy and vinyl, respectively) hyperbranched polymers were less efficient toughness modifiers than was CTBN, they showed no adverse effect on the stiffness and T_g. Use of core/shell modifiers did not result in toughness improvement. The above changes in the toughness response were traced to the morphology assessed by dynamic mechanical thermal analysis (DMTA) and fractographic inspection of the fracture surface of broken CT specimens. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 672–680, 2002; DOI 10.1002/app.10392     

多周期多原料的供应链网络成本优化及其混合遗传算法

建立并求解一个基于成本最小的供应链网络模型.与以往研究不同,在该模型中生产一种产品需要至少两种原料,每种原料都可以由备选供应商提供.根据模型的特点,用0、1代表对原材料供应商、工厂和分销中心的选择情况,以MATLAB 7.6为平台,运用Sheffield大学的遗传算法工具箱,将遗传算法与线性规划算法相结合,实现了模型的求解.算例结果表明,给出的染色体编码方案正确,混合遗传算法有效,能解决多周期、多原料的供应链网络成本优化问题.还探讨了需求和距离变化,以及需求随机时对最优成本和最优个体的影响.研究表明,需求变化的影响大于距离变化的影响,需求随机对最优成本和最优个体的影响不大.     

基于矩阵初等变换的量子可逆逻辑电路双向综合算法

基于矩阵初等变换,提出了量子可逆逻辑电路双向综合算法。该算法依据两数字间的汉明距离,通过交换矩阵行号或矩阵元素对量子可逆逻辑电路的矩阵进行初等行变换。在变换的过程中,利用邻接矩阵的电路转化规则,生成任意给定置换的量子可逆逻辑电路。与其它同类算法相比,由于不需要穷尽搜索,该算法的时空复杂度有大幅降低;又由于采用任意n量子扩展通用Toffoli门,该算法可综合任一置换(奇或偶置换)的量子可逆逻辑电路,并且电路中门的数量有所减少。     

远端串扰下永磁探测电路相位鉴频特性测量

压电式永磁探测电路广泛应用在远程目标探测系统中,其在远端串扰下的相位鉴频特性准确分析可提高探测系统的测量精度。传统方法采用红外和声脉冲等探测进行电路相位鉴频特性测量控制,在强磁场中曲线趋于饱和,测量性能不好。提出一种基于引入正弦脉宽调制控制的端串扰下压电式永磁探测电路相位鉴频特性测量方法,并进行系统设计,首先进行压电式永磁探测电路系统设计,采用自适应噪声抵消方式处理远端串扰的干扰,设计远端串扰下压电式永磁探测电路,通过相位鉴频特性测量分析,实现电路的混频、倍频等频率变换,完成远端串扰下电式永磁电路的相位鉴频特性测量控制。系统测试结果表明,该测量方法和系统具有较好的远端串扰抵消性能,准确分析电路系统的相位鉴频特性,远程目标探测准确率提高,性能优越。为远程目标探测系统设计提供了硬件电路系统设计基础。