锌电积过程中添加剂对阴极的影响

目前锌电积过程中常用到的添加剂有骨胶、硫脲、十二烷基磺酸钠及一些辅助添加剂等。本文从性质、机理及加入控制上详细地对各种添加剂进行了细致分析,并总结出不同添加剂对阴极板锌的析出质量的影响。     

微波高压提取快速测定饲料含氟量的探讨

采用微波高压制样技术,快速提取饲料中的氟元素,结合氟离子选择性电极标准添加和电位极差测试方法,能够快速、准确地测试饲料中的含氟量     

应用焊道长度控制线能量

运用ＨｅｒｂｓｔＦＷ公式原理对国产碱性条件进行了大量试验，建立了焊接线能量（Ｅ），焊条熔化长度（ｌＥ），焊道长度（ｌＲ）的关系式：Ｅ＝８０８Ｄ１．８ｌＥ／ｌＲ。并应用线算图和ＳＨ－ＣＣＴ图对该式施焊结果验证，热影响区的金相组织，硬度基本一致。因此，可以应用焊道长度校核与控制线能量。     

Low‐voltage and high‐transmittance blue‐phase liquid‐crystal device with slanted electrodes

Abstract— A low‐voltage (～10 V_rms) and high‐transmittance (～90%) polymer‐stabilized blue‐phase liquid‐crystal (BPLC) device with a slanted‐electrodes structure is proposed. Unlike the vertical‐field‐switching (VFS) mode in which oblique incident light and a vertical field are employed, the proposed device utilizes normal incident light and an oblique field. The slanted electrodes generate a strong and uniform oblique electric field, which contributes in obtaining low voltage and high transmittance. Moreover, no couple films or prism sheets are needed, which helps to enhance the optical efficiency and simplify of the device structure. This device has great potential application for emerging BPLC displays and photonic devices.     

以1,3-二(4-邻羟基苯亚胺次甲基)苯氧基丙烷为载体的铁离子(Ⅲ)电极的研究

以1,3-二(4-邻羟基苯亚胺次甲基)苯氧基丙烷为中性载体制备了PVC膜Fe3+离子选择性电极。该电极对Fe3+呈现出良好的选择性和近Nernst电位响应性能。电极斜率为21mV/dec,线性范围为3.0×10-5～1.0×10-1mol/L,检出限为1.0×10-5mol/L。采用交流阻抗技术研究了电极的响应机理,并将电极作为指示电极初步用于EDTA的电位滴定。     

基于2,4-二羟基苯甲酸铜(Ⅱ)为载体的硫氰酸根电极的电位响应

制备了基于一种简单的金属铜配合物2,4-二羟基苯甲酸铜(Ⅱ)(Cu(Ⅱ)DHBA)为载体的PVC膜硫氰酸根离子(SCN-)选择性电极。该电极在1.0×10-1～1.0×10-6mol/LSCN-浓度范围内呈现斜率为-59.5mV/dec的近Nernst电位响应,检测下限为9.1×10-7mol/L。利用紫外可见光谱及交流阻抗技术初步探讨了电极对SCN-呈现的选择性电位响应机理。该电极作为直接电位分析法的指示电极,成功运用于实验室废水中硫氰酸盐含量的测定。     

从废旧锌锰电池中回收锌和锰的工艺研究

废旧锌锰干电池经过剖开、焙烧处理，去除汞和碳粉，再用硫酸浸取，滤液采用沉淀法分离锌和锰。锌和锰的回收率分别为94．5％和93．6％。     

Electrochemical investigation of the iron-containing and no iron-containing AB5-type negative electrodes

The electrochemical behaviour of LaNi_3.55Mn_0.4Al_0.3Co_0.75−xFe_x (x = 0, 0.15, 0.55, 0.75) intermetallic compounds has been studied and presented [C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, Int. J. Hydrogen Energy 29 (2004) 307–311; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 360 (2003) 266–271; C. Khaldi, H. Mathlouthi, J. Lamloumi, A. Percheron-Guégan, J. Alloys Compd. 384 (2004) 249–253]. It has been deduced that the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound has interesting electrochemical properties. In this paper we present the electrochemical study of LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compound properties compared with the parent LaNi_3.55Mn_0.4Al_0.3Co_0.75 compound. Several techniques, such as, the chronopotentiometry, the constant potential discharge (CPD), the cyclic voltammetry (CV) and the linear polarization (LP) were applied to characterize these electrochemical properties. The electrochemical discharge capacity of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 alloy increases to reach 294 mAh g⁻¹ after few cycles only (five cycles). However, the activation of the LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloy takes more than 20 cycles to be achieved and the obtained maximum discharge capacity is 194 mAh g⁻¹. The hydrogen diffusion coefficient D_H was determined by constant potential discharge and cyclic voltammetry techniques. The obtained values of the LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 compounds are 6.29 × 10⁻¹¹ and 7.62 × 10⁻¹¹, and 2 × 10⁻⁸ and 7.5 × 10⁻⁸ cm² s⁻¹ by CPD and CV techniques, respectively. The exchange current density values, determined by a linear polarization technique, are 44 and 27 mA g⁻¹, respectively, for LaNi_3.55Mn_0.4Al_0.3Co_0.75 and LaNi_3.55Mn_0.4Al_0.3Co_0.4Fe_0.35 alloys.     

小波变换在伺服焊枪电极位移曲线分析中的应用

电极位移曲线能够反映出点焊规范参数波动，是一个理想的监控参数。采用离散Daubechies4阶小波对电极位移曲线进行滤波处理，成功地将测量曲线分为电极位移趋势曲线、波动曲线。这两种曲线分别反映了点焊质量的整体质量优劣、过程一致性这两方面特征，提高了位移曲线表征焊接过程的能力，为伺服焊枪的点焊质量控制提供了准确、优良的数据基础。     

二元稀土系AB5型贮氢电极合金的放电容量与晶胞体积和4f电子浓度的关系

制备了6个系列通式为AαA‘1-αB5的RE(NiCoMnTi)5贮氢电极合金(其中，AαA‘1-α为La，Ce，Pr，Nd4个元素中任意2个的组合)，测定了它们在100次循环中的最大放电容量Cmax及部分合金的晶胞体积Vcell．结果表明：Cmax主要由Vcell决定，Cmax先随Vcell的增大而增加，在Vcell≈85．66x10^-^3。nm^3时达到一极大值，然后又随Vcell的增大而减小；同时，Cmax还与4f电子浓度ne4f／naRE有关，A侧具有相同4f电子浓度的合金其Cmax随4f电子浓度的变化趋势相似．