Modification of leather properties by grafting. I. Effect of monomer chain on the physico‐mechanical properties of grafted leather

Although leather has a number of desirable properties such as thermal stability and fire retardancey, in addition to high toughness, it has a few drawbacks such as weight, high water absorption, poor soil and rot resistance, and nonuniformity. If these defects are overcome, leather's usefulness would be further enhanced and its competitive position with respect to synthetics would increase. This study reports the physical and mechanical properties of buffalo leather after chemical graft copolymerization with ethyl acrylate, butyl acrylate, and 2‐ethyl hexyl acrylate using benzoyl peroxide as an initiator. The optimum conditions for grafting (e.g., monomer and initiator concentrations, temperature and time of grafting, and solvent leather ratio) were extensively investigated. The study achieved outstanding properties for buffalo leather in reduction of water uptake after grafting, especially on using 2‐ethyl hexyl acrylate and butyl acrylate monomers. FT‐IR and solid ¹³C‐NMR for leather before and after grafting confirmed the grafting process.© 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 1478–1483, 2003     

基于Web的重点建设项目管理系统

为提高重点建设项目的管理水平和工作效率,在详细分析重点建设项目的业务流程和用户需求的基础上,提出基于Web的重点建设项目信息管理系统。该系统采用典型的三层体系架构,具有较强的可扩展性和灵活性。通过该系统对重点建设项目信息科学管理,可以有效克服传统管理方式的弊端,极大地提高重点建设项目信息管理工作的效率。     

YL-1OO型自动加药装置在乙烯循环水场的应用

介绍了国产YL-100型自动加药装置功能及其在中国石化茂名石化乙烯工业公司乙烯循环水场的应用情况,结果表明其运行平稳,总磷测试数据可靠,可达到循环水自动加药控制的目的。     

施工项目管理与贯标工作相融合的探索与实践

由于建筑工程施工的单件性、复杂性，在工程项目实施过程中贯标工作与工程项目管理工作通常不太融合，有时甚至形成“两层皮”现象。因此，针对这一现象，在承建410t／h锅炉工程中，借贯彻2000版ISO9001标准的有力时机，进行了工程项目管理与贯标工作融合性的探索与实践，取得了较好的效果。     

快速高效隔膜压滤机在鹤壁四矿选煤厂的应用

介绍了快速高效隔膜压滤机的主要性能参数和特点 ;分析了压滤机在煤泥水处理系统中的应用情况和运行结果 ;应用快速高效隔膜压滤机对煤泥水处理系统进行改造后获得了较好的经济及社会效益     

烧碱生产用水的综台利用

阐述了河北盛华化工有限公司综合利用烧碱生产用水的意义，介绍了所采取的措施及效果。     

Synthesis of Pseudoionones by Acid and Base Solid Catalysts

The preparation of pseudoionones by aldol condensation reaction between citral and acetone have been carried out in the presence of acid (HY and beta zeolites), an acid–base (amorphous aluminophosphate) and basic catalysts such as an aluminophosphate oxynitride, MgO and different activated hydrotalcites. The results showed that acid or acid–base catalysts were not successful for performing in one pot the preparation of ionones. MgO and calcined hydrotalcites showed excellent activity and selectivity to pseudoionones, with calcined hydrotalcite more selective than MgO. Moreover, the rate of reaction can be improved by activating the hydrotalcite through rehydration. This activation can be successfully done by simply adding the optimum amount of water to the calcined hydrotalcite before reaction. The inhibiting effect of the concentration citral on the catalytic activity of rehydrated hydrotalcites that has been reported to occur at 273 K can be avoided by working at a reaction temperature of 333 K.     

碳钢贮热水箱的模拟腐蚀试验及涂层耐蚀性能研究

碳钢贮热水箱长期在30～80°C温变的热水环境中工作,易受到热水及水中杂质的腐蚀。研究了不同温度下Q235钢在自来水及含100μg/mLNaCl的自来水中的腐蚀速率。对裸钢及其涂覆相同厚度的不同涂层──酚醛环氧(自制)、钛纳米聚合物和改性聚乙烯后在70°C自来水中的极化曲线进行了比较。采用动电位扫描极化曲线测量和电化学交流阻抗谱法(EIS)分别对涂覆不同涂层的Q235钢进行了耐蚀性能研究。结果表明,3种防腐涂层均具有较佳的抗热水性,耐蚀能力较强,适宜对Q235钢贮热水箱进行防护。     

浅谈玻璃钢的加工

本文在实际研究和应用的基础上，对玻璃钢的传统加工方法和特种加工方法，如激光切割、纯水射流切割和磨料水射流切割作了简要论述。