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101.
102.
The shrinking core model (SCM) is widely used to model fluid-solid reactions such as the leaching of metals from minerals. In most cases, however, the particle size distribution (PSD) of the solid material was disregarded. In this paper the erroneous shift in the control regime when neglecting PSD was quantified and the dependence of the shift on the coefficients of variation (CV) and the type of PSD was analysed. By coupling the SCM with a Gamma PSD, it was found that neglecting the PSD would shift the control regime from chemical reaction to inert/ash layer diffusion, when the CV was between 0.7 and 1.2. For a system controlled by liquid film diffusion, neglect of the PSD, would shift the control regime to chemical reaction when CV is between 0.3 and 0.7 or to inert/ash layer diffusion when CV is greater (0.9-1.5). It was therefore postulated that some researchers had unknowingly made invalid conclusions about the control regime due to the neglect of PSD. However, an inert/ash layer diffusion-controlled process was insensitive to the neglect of PSD. When CV<0.3, neglect of the PSD would not cause any erroneous shifts, irrespective of the control regime. Experimental data confirmed the observation. For a given CV, the deviation in the fraction reacted from the mono-PSD increases with CV and decreases with time. The maximum deviation, which occurs at the beginning, is about 10% with a gamma PSD of CV=0.3. The percent deviation is dependent of the type of PSDs. Gamma PSD gives the lowest deviation while Gaudin-Schuhmann results in the largest deviation (maxi. ∼19%, with CV=0.3) in the first half of dissolution process. Log-normal distribution gives a larger deviation than gamma but quickly approaches the latter with time. The deviation for Rosin-Rammler is between log-normal and Gaudin-Schuhmann. For systems with CV less than 0.3, the SCM can be fairly used without considering PSD. When CV is greater than 0.3, particularly in the early stage of a dissolution process with a PSD other than gamma, PSD should be included to avoid substantial errors.  相似文献   
103.
纳米SiO2粉体的制备与研究   总被引:1,自引:0,他引:1  
贾东舒  童忠良 《化工进展》2003,22(7):735-738
纳米SiO2粉体的制备是以硅酸钠和盐酸为原料,添加适宜的稳定剂(非离子表面活性剂)和分散剂,在适宜的pH值和温度下,采用化学沉淀法合成。研究表明,要得到性能优良纳米的SiO2粉体,最佳工艺条件为:温度20~40℃,pH=6,反应液质量浓度P1=20g/L,P2=1.20g/L,反应时间15min。结果表明:制备的纳米SiO2粒径30~50nm,比表面积大,分散性好,质量优良,可达到产业化的生产。  相似文献   
104.
结合北京地区现阶段对相关技术的规定,以实际供用电方案为例,对中压电缆网双环接线方式的供电能力进行深入讨论。通过设计环网单元划分,发现某些条件下双环网供电能力可以得到进一步提升。  相似文献   
105.
为了保证电厂的生产效率,必须要分析电气的运行特征,确定电气故障发生的原因,综合考虑多方面因素,选择切实可行的措施解决问题。简要分析了电厂电气运行常见故障发生原因,并提出了相应的解决措施。  相似文献   
106.
A prototype wind-powered reverse osmosis desalination system was constructed and tested on Coconut Island off the northern coast of Oahu, Hawaii, for brackish water desalination. The system has four major subsystems: a multi-vaned windmill/pump, a flow/pressure stabilizer, a reverse osmosis module, and a control mechanism. The feedback control mechanism, developed by this study, allowed this prototype system to be operated satisfactorily under mild ambient wind of 5 m/s or less. No auxiliary power source was needed. The system operational data showed that at an average wind speed of 5 m/s, brackish feedwater at a total dissolved solids concentration of 3000 mg/1 and at a flow rate of 13 1/min could be processed by this system. The average rejection rate of this prototype system was 97% and the average recovery ratio was 20%. The energy efficiency of the system was measured at 3 5%, which is comparable to the typical energy efficiency of well-operated multi-vaned windmills. Generally, the system's energy efficiency decreases as wind speed increases.  相似文献   
107.
为提高服装的销售预测准确度,通过产品的生命周期曲线模型,使得服装销售预测的定性分析与定量预测有机地结合在一起。针对目前服装产品生命周期曲线模型的局限性,引入改进的BASS模型,对服装产品生命周期进行研究。通过销售实例探讨改进的BASS模型用于描述服装生命周期的可行性,建立了以改进的BASS模型为基础的服装产品生命周期模型,并利用该模型对服装销售量做预测,取得了比其他模型更高的精度。  相似文献   
108.
The existing equivalent methods usually only deal with static load models and neglect the dynamic characteristics of loads such as induction motors.This paper presents a dynamic equivalent method which considers motor dynamics.At first,the clustering criterion of motor loads is given.The motors with similar dynamic characteristics are classified into one group.Then,reduction of motors in the same group is carried out.Finally,parameters of the equivalent motor are calculated and the equivalent system is thus...  相似文献   
109.
The modified hydrodynamic theory of long rod penetration into semi-infinite targets was established independently by Alek-seevskii and Tate over forty years ago and since then many investigators contributed much to the development of the high speed penetration mechanics.However,in all the models proposed so far,the target resistance Rt is not well defined and usually determined by adjusting it until the predicted depth of penetration comes to an agreement with experimental data.In this paper,assumptions are...  相似文献   
110.
首次对标准模型下群签名的批验证协议进行了研究。利用小指数测试技术和双线性对映射的特殊性质,为目前效率较高的两个群签名方案按照多人签署相同消息和不同消息这两种情况,分别设计了相应的批验证协议。相较于单独验证,认证效率大大提高。  相似文献   
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