Effects and properties of poly(arylene ether benzonitrile)s of various molecular weights blended with sulfonated poly(ether ether ketone)

Poly(arylene ether benzonitrile) (PAEBN) was synthesized with 2,6‐dichlorobenzonitrile and biphenol. PAEBNs with various molecular weights (MWs), 1,640,000 and 185,000 g/mol, were synthesized by control of the stoichiometry of the monomers and were blended with sulfonated poly(ether ether ketone) (SPEEK). The effects of MW on the water uptake, swelling, methanol permeability, and proton conductivity of the SPEEK/PAEBN blend membranes were investigated. The molecular mobility of the SPEEK/PAEBN blends was also examined in this study. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Measuring interdiffusion at an interface between two elastomers with tapping-mode and contact-resonance atomic force microscopy imaging

Despite the common use of tapping-mode atomic force microscopy to image composites or polymer blends, very few studies have focused on the measurement of the interdiffusion at an interface between two polymers in contact. In this study, we show how to assess the interphase between two polymers with two methods. First, stable and robust tapping conditions are established, and the problem of the phase contrast is discussed. Second, a contact-resonance method is presented: the tip in contact with the sample is electrostatically excited at its resonance frequency by a self-controlled oscillator. The gain and frequency images allow us to measure the interdiffusion width. Both methods (using high and weak mechanical solicitation) give the same assessment of the interdiffusion width. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Laser irradiation of oligosiloxane copolymer thin films functionalized with side chain bulky carbosilane moieties

Linear oligosiloxanes functionalized with bulky side chain tris(trimethylsilyl)hexyl (TTSH) substituents were transformed into cross-linked materials by UV 193 nm excimer pulsed laser ablation. The process occurred without any catalyst, by reactions of radicals formed in UV laser induced photolysis of side tris(trimethylsilyl)hexyl groups. Chemical changes were monitored by FTIR, LC/UV, GC/MS and solubility tests.     

Mixtures of tertiary amine functionalized azo-containing mesogens with acid-functionalized polymers

A tertiary amine functionalized 4-nitro-4′-alkoxy azobenzene mesogen with a 10 or 12 carbon spacer (azo-nN) was synthesized and complexed in equimolar proportions with poly(acrylic acid) (PA-H) and poly(sulfonic acid) (PSS-H), and investigated by thermogravimetric analysis, differential scanning calorimetry, polarizing optical microscopy, Fourier transform infrared spectroscopy and X-ray diffraction. The neat azo-nN is characterized by a partial bilayer S_A mesophase at higher temperatures, and a highly ordered phase, in which the molecules are stacked orthogonally in bilayers, at lower temperatures. As supported by infrared analysis, for the azo-nN/PA-H mixture, the complexation is partial while for the same azo-nN/PSS-H mixture, complete proton transfer occurs. When the azo-nN is blended with the PA-H, regarded as a weak acid, a biphasic system is generated and the thermotropic behavior of neat mesogen is not significantly affected. In contrast, by mixing the same mesogen with a PSS-H (regarded as a strong acid), the thermotropic behavior is significantly influenced: the complexation generated a partial or interdigitated smectic A or tilted smectic C lamellar phase.     

管线油电损耗的灰色模型及预测

对于管道运输来说，影响输油成本变化的因素有很多，但是对总成本影响最大的是油电损耗费用。由于来自现场的输量和相关参数样本数据不足，只知道连续几年的流量、油电损耗，要预测将来每年的油电损耗，经典经济数学不能满足这样的研究。然而灰色系统理论要求的研究样本较少，只要知道连续几年的流量、油电损耗，就能预测将来每年的油电损耗，估算其输油成本，且模型精度较高。利用灰色系统理论，以输油管线每年的输量、相应的电耗和油耗为时间序列，建立了三元素非等间距GM(1，1)模型，该模型为预测管线年输油成本提供了可靠的依据。     

面向技术创新机遇组建虚拟企业与兼并行为的比较分析

以技术创新机遇为例分析了核心企业选择实现市场机遇的战略模式的决策过程，并给出核心企业选择实现市场机遇的战略模式的决策模型。在模型中考虑了核心企业组建虚拟企业的一个重要目的就是快速地实现市场机遇，因此在提出的决策模型中引入了时间因素。研究结果表明，当市场机遇生命周期较长时，核心企业采取兼并策略优于组建虚拟企业，反之组建虚拟企业更有利。最后提出采用期权定价模型来判断组建虚拟企业的价值，并举例说明。     

武钢第二炼钢厂连铸坯喷号机自动控制系统

对武钢第二炼钢厂连铸坯喷号机自动化控制景统配置、网络通讯、伺服控制系统进行了阐述；经运行考验证明系统性能提高、稳定可靠。     

打捆机器人自动控制系统

介绍了莱钢中小型轧钢生产线打捆机器人自动控制系统的硬件配置、软件结构及其主要控制功能，并对打捆定位和打捆过程作了详细说明。     

Distinctive Features of Minimization of a Risk Functional in Mass Data Sets

A statistical learning model is considered within the framework of the theory of uniform convergence of frequencies of errors in the case where the convergence is violated as a result of increasing the informativeness of training examples. Drawbacks of nonconstructive refinements of Vapnik-Chervonenkis estimates based on an assumption on the distribution law of violations are shown. A new approach to obtaining constructive estimates for mass data sets is proposed.     

烧结原料场大面积扬尘的控制措施

针对烧结原料场大面积扬尘的情况。提出了综合治理措施。着重对适合于烧结用粉状物料的扬尘抑制剂进行了研究。