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11.
The electrochemical properties of an electrochemical double-layer capacitor electrode based on an ultra-long (500 μm), aligned, carbon nanotube array (ACNTA) in Et4NPF6/propylene carbonate electrolyte are examined. The specific capacitance of the ACNTA electrode in an organic electrolyte is 24.5 F g−1, which is larger than that obtained in an aqueous electrolyte. The results of ac impedance measurements show that the ACNTA electrode gives a high power density and an excellent rate capability in an organic electrolyte. It is shown that the ACNTA electrode has a lower equivalent series resistance and a better rate capability than activated carbon electrode. This is due to the fact that ACNTA possesses a larger pore size and a more a regular pore structure. Both these features are conformed by scanning electron microscopic and nitrogen gas adsorption studies. 相似文献
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高技术产品用无源元件与中国钽工业发展 总被引:1,自引:2,他引:1
世界高技术产品市场总体看呈增长趋势,预计2020年销售额将比2000年翻一番。以高技术产品为主要应用领域的电阻、电容、电感等无源元件,也将随着高技术产业的发展呈现出良好的市场前景,但是钽电容器市场近几年表现出骤涨急落的发展态势。由于钽电容器产能过剩,且面临着被替代的威协,因此价格将无法返回到2000年以前的水平,并呈现整体持续走低的趋势。中国的钽工业发展应注重提高企业自身的综合竞争力,加强企业间的沟通、交流与合作,维护我国钽工业的整体利益,增强环保意识,做好国外转移到我国的初级产品和低端产品生产的环保工作。 相似文献
14.
电解电容器铝箔纯交流腐蚀工艺影响因素的研究 总被引:2,自引:0,他引:2
对电解电容器铝箔交流腐蚀体系中各影响因素的研究结果表明,在电流密度为0.5A/cm2,温度为47±2℃;控制腐蚀液中Al(3+)含量及适量添加表面保护剂和辅助添加剂的条件下,可获得最大比电容。通过循环伏安曲线测试,探讨了各因素影响腐蚀的机理及相互关系。 相似文献
15.
电感电容损耗电阻的讨论 总被引:3,自引:0,他引:3
通过对电容电感阻抗的测量,发现实验值偏离理论值。定性地分析了误差的来源,得出的结论是电感电容内部的损耗电阻随着频率的变化而变化,变化方向相反而并非相同。 相似文献
16.
Electrochemical parameters of the nanoporous carbide-derived carbon|organic electrolyte have been studied by cyclic voltammetry and electrochemical impedance spectroscopy. The gas adsorption measurements have been used for evaluating the specific surface area, pore size distribution and porosity as the essential parameters influencing the double layer performance of carbon. The region of ideal polarizability, values of series and parallel resistance, capacitance and other important electrical double layer parameters were established. It was shown that specific capacitance of typical nanoporous carbon derived from titanium carbide is in the range of 70-90 F cm−3 or 100-130 F g−1 and it depends on the synthesis conditions. The influence of the electrolyte solvent to the capacitance was insignificant, although acetonitrile was advantageous with respect of smaller viscosity. 相似文献
17.
铝电解电容器用新型宽温高压工作电解液 总被引:3,自引:0,他引:3
采用异癸二酸铵为主溶质,乙二醇和γ-丁内酯为复合溶剂,制备新型宽温(-40~105℃)、高压(400 V)铝电解电容器工作电解液,并检测了该电解液和用该电解液生产的电解电容器的性能。测试结果表明,该工作电解液25℃时电导率达到1.6 mS/cm,闪火电压为480 V,-40℃下未见晶体析出;CD 110/400 V铝电解电容器试样的漏电流≤10μA,损耗0.03,容量变化率只有-3%。经过105℃高温贮存250 h后各项电气性能不仅优于国家标准,而且能达到严格的企业标准。 相似文献
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19.
The electrochemical behaviour of the chromium electrode in borate buffer solution (pH 9.3) was studied by cyclic voltammetry and electrochemical impedance spectroscopy. Chromium passivity was observed over a broad potential region, from –1.0 to 0.5 V vs SCE. The passivation process took place in two steps: formation of a chromium oxide monolayer and transition of chromium to a higher valence state. The anodic film exhibited the properties of a p-type semiconductor. Transpassive dissolution of chromium occurred at 0.5 V vs SCE, with two reaction intermediates present, CrCr
III and Crad
4+. 相似文献
20.
Keiichi Okajima 《Electrochimica acta》2005,50(11):2227-2231
Modified activated carbon fibers (ACFs) were used as the electrodes of an electric double-layer capacitor and showed an enhanced capacitance effect after a RF-plasma treatment. The capacitance and the surface functional groups of the ACFs were studied. For the plasma-treated ACFs having a specific surface area of 1500 m2 g−1, the capacitance increased by 28% compared to the untreated sample and the highest electric capacitance value of 142 F g−1 was achieved with an oxygen feed concentration of 10 vol.%. The Brunauer-Emmett-Teller (BET) surface area was 2103 m2 g−1, which was 34% higher than that of the untreated sample. The pore volume was similarly increased to 483.1 cm3 g−1 STP, and from the pore distribution plot, quantities of mesopores of 10 nm or less and micropores also increased. However, in order to enhance the capacitance, the quinone functional group had a significant influence in addition to the BET surface area. The correlation between the capacitance and the number of quinone functional groups was confirmed because quinone is an electron acceptor. 相似文献