Ni-金刚石复合涂层的结构优化及基础磨削性能

采用电沉积技术在304不锈钢基体上制备了Ni-金刚石复合涂层。通过金刚石掺入量、加厚镀时间优化了金刚石复合涂层结构,利用球-盘式摩擦磨损试验仪研究了优化后的金刚石复合涂层对不同材料偶件(GCr15、SiC、304不锈钢)的磨削性能。结果表明:金刚石掺入量为1.5g/L时,金刚石上砂均匀且密集;加厚镀15min时,金刚石埋入率约为2/3,附着强度较好,适合磨削加工;GCr15、SiC、304不锈钢3种材料偶件的磨损体积依次减小,分别为:0.353 76mm~3、0.315 90 mm~3、0.194 01 mm~3,金刚石复合涂层对GCr15有较好的磨削性能;金刚石复合涂层磨削GCr15、SiC、304不锈钢均发生了磨粒磨损,此外,GCr15还发生了微弱的化学磨损,不锈钢发生了较明显的化学磨损和粘着磨损。     

基于非理想爆轰的炸药-岩石相互作用过程

对炸药-岩石相互作用过程正确和全面的理解是研究岩石爆破破碎过程的基础。通过未反应炸药采用Murnahan状态方程、爆轰产物采用JWL方程、反应速率采用三项点火-增长-反应速率模型,改进了的炸药非理想爆轰模型。实验数据对比表明,改进的非理想爆轰模型能够较好地模拟工业炸药的非理想爆轰过程。基于改进的非理想爆轰模型,研究了不同装药结构和不同耦合介质下炸药与岩石的相互作用过程。研究表明,同种炸药在纵波速度不同的岩石中的爆轰结构存在显著差异,空气和水对爆轰冲击波有明显的缓冲和迟滞作用,与空气不耦合装药相比,水耦合装药荷载峰值高,持续时间长,具有更高的能量利用率,有利于改善破碎效果。     

硅烷偶联剂及氧化石墨烯二次改性对芳纶纤维界面性能的影响EI北大核心CSCD

为改善芳纶纤维(PPTA)与丁腈橡胶(NBR)复合材料之间的界面强度,采用硅烷偶联剂A172和氧化石墨烯(GO)对芳纶纤维表面进行接枝改性处理,并对处理前后的芳纶纤维进行化学结构、表面形貌及H抽出力分析。利用SEM对抽出纤维表面和橡胶基芳纶纤维复合材料截面进行微观结构分析。结果表明:硅烷偶联剂和氧化石墨烯对芳纶纤维进行二次表面改性后,纤维表面含氧基团增加,化学活性提高,处理后表面存在明显的表层附着物,纤维结构未发生明显损伤且表面粗糙度得到明显改善。每个处理阶段后H抽出力均有提高,且氧化石墨烯二次改性后的芳纶纤维H抽出力提高效果最佳,从18.192 MPa提高到48.748 MPa,芳纶纤维与丁腈橡胶的界面结合力得到了显著提升,从而证实了硅烷偶联剂和氧化石墨烯二次改性芳纶纤维的有效性,为橡胶基芳纶纤维复合材料性能的研究提供了参考。     

Observation of Exchange Interaction in Iron(II) Spin Crossover Molecules in Contact with Passivated Ferromagnetic Surface of Co/Au(111)

Spin crossover (SCO) complexes sensitively react on changes of the environment by a change in the spin of the central metallic ion making them ideal candidates for molecular spintronics. In particular, the composite of SCO complexes and ferromagnetic (FM) surfaces would allow spin-state switching of the molecules in combination with the magnetic exchange interaction to the magnetic substrate. Unfortunately, when depositing SCO complexes on ferromagnetic surfaces, spin-state switching is blocked by the relatively strong interaction between the adsorbed molecules and the surface. Here, the Fe(II) SCO complex [Fe^II(Pyrz)₂] (Pyrz = 3,5-dimethylpyrazolylborate) with sub-monolayer thickness in contact with a passivated FM film of Co on Au(111) is studied. In this case, the molecules preserve thermal spin crossover and at the same time the high-spin species show a sizable exchange interaction of > 0.9 T with the FM Co substrate. These observations provide a feasible design strategy in fabricating SCO-FM hybrid devices.     

一种修正的GFRP本构模型及其双层板结构抗冲击特性预测

玻璃纤维增强聚合物基材料(GFRP)是一种典型的各向异性复合材料,在冲击载荷作用下具有复杂的力学响应.Autodyn软件中现有的GFRP材料模型所采用的状态方程仅考虑了体应变的单一影响,忽略了各向异性材料中应力分量与应变分量之间的耦合效应.首先,在已有的解耦理论基础上,对现有模型中的状态方程和强化模型进行了修正,计算得...     

一种改进的基于挑战/应答机制的短波接入认证系统研究与设计

挑战/应答方式是一种常用的安全性较高的动态身份认证技术,但窄带信道条件和高效率、高安全性要求限制了其在军事短波环境中的应用。基于短波终端和岸基短波台站已有的安全基础—预共享对称密钥,设计了一种改进的基于挑战/应答机制的短波接入双向认证系统。针对短波接入网实际应用,在认证过程中引入随机数和时间戳两种动态因子,在增强接入认证系统安全性的同时,有效减少了认证过程中的开销,实现通信双方相互认证的同时还能够完成会话和完整性密钥的协商。     

频变耦合双通带滤波器的综合方法

为了解决频变耦合双通带滤波器缺少有效综合方法的问题,文中提出一种优化综合方法.该方法首先通过频率变换技术得到滤波器在归一化双通带域内的特征多项式,然后应用经典的耦合矩阵综合方法得到双通带滤波器的全规范耦合矩阵,进而以矩阵的特征值为趋近目标构造目标函数,最后应用梯度优化算法进行优化获得了双通带滤波器的频变耦合矩阵.文中对...     

一种小型化带通滤波微带巴伦设计

提出一种小型化带通滤波微带巴伦的设计。在Marchand巴伦的基础上,使用一个半波长和两个1/4波长传输线作为谐振器,在带通滤波微带巴伦的两个输出端口可以获得相同幅度和相反相位的平衡信号。利用谐振器平行线耦合可以观察到通带两侧存在两个传输零点。对提出的中心工作频率在2.65 GHz的带通滤波微带巴伦进行了实物加工与测试。两个输出端口信号幅度差与相位差分别为±0.4 dB和180°±5°。仿真与测量结果有较好的一致性,验证了本文所提方案的可行性。     

Construction of VS2/VOx Heterostructure via Hydrolysis-Oxidation Coupling Reaction with Superior Sodium Storage Properties

Heterostructure engineering is one of the most promising modification strategies for reinforcing Na⁺ storage of transition metal sulfides. Herein, based on the spontaneous hydrolysis-oxidation coupling reaction of transition metal sulfides in aqueous media, a VO_x layer is induced and formed on the surface of VS₂, realizing tight combination of VS₂ and VO_x at the nanoscale and constructing homologous VS₂/VO_x heterostructure. Benefiting from the built-in electric field at the heterointerfaces, high chemical stability of VO_x, and high electrical conductivity of VS₂, the obtained VS₂/VO_x electrode exhibits superior cycling stability and rate properties. In particular, the VS₂/VO_x anode shows a high capacity of 878.2 mAh g⁻¹ after 200 cycles at 0.2 A g⁻¹. It also exhibits long cycling life (721.6 mAh g⁻¹ capacity retained after 1000 cycles at 2 A g⁻¹) and ultrahigh rate property (up to 654.8 mAh g⁻¹ at 10 A g⁻¹). Density functional theory calculations show that the formation of heterostructures reduces the activation energy for Na⁺ migration and increases the electrical conductivity of the material, which accelerates the ion/electron transfer and improves the reaction kinetics of the VS₂/VO_x electrode.     

Bio-Inspired Artificial Fast-Adaptive and Slow-Adaptive Mechanoreceptors With Synapse-Like Functions

Development of artificial mechanoreceptors capable of sensing and pre-processing external mechanical stimuli is a crucial step toward constructing neuromorphic perception systems that can learn and store information. Here, bio-inspired artificial fast-adaptive (FA) and slow-adaptive (SA) mechanoreceptors with synapse-like functions are demonstrated for tactile perception. These mechanoreceptors integrate self-powered piezoelectric pressure sensors with synaptic electrolyte-gated field-effect transistors (EGFETs) featuring a reduced graphene oxide channel. The FA pressure sensor is based on a piezoelectric poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) thin film, while the SA pressure sensor is enabled by a piezoelectric ionogel with the piezoelectric-ionic coupling effect based on P(VDF-TrFE) and an ionic liquid. Changes in post-synaptic current are achieved through the synaptic effect of the EGFET by regulating the amplitude, number, duration, and frequency of tactile stimuli (pre-synaptic pulses). These devices have great potential to serve as artificial biological mechanoreceptors for future artificial neuromorphic perception systems.