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71.
柴达木盆地北缘侏罗系烃源岩干酪根13C核磁共振研究 总被引:2,自引:1,他引:1
柴达木盆地北缘是柴达木盆地三大油气区之一,其源岩为早、中侏罗世煤系地层.烃源岩有机质类型以Ⅲ1型和Ⅱ型干酪根为主,Ⅰ2型干酪根仅在局部地区有分布.通过对柴达木盆地北缘侏罗系烃源岩中不同类型干酪根的13C核磁共振研究,指出了研究区Ⅰ2、Ⅱ、Ⅲ1型干酪根的化学结构特征以及化学结构中“芳构碳”、“油潜力碳”与“气潜力碳”的相对含量,据此从定量分析的角度对不同类型干酪根的生油气贡献作了评价.Ⅰ2、Ⅱ、Ⅲ1型干酪根的生烃能力依次减弱,对生油的贡献也依次减弱,且生成油气的比例不同,Ⅰ2、Ⅱ型干酪根以生油为主,Ⅲ1型干酪根则以生气为主. 相似文献
72.
73.
The use of activated carbon beds for the removal of natural humic and fulvic substances found in water supplies, has recently received considerable attention in water treatment operation (Lee et al., 1980; Le Cloirec et al., 1983). Moreover, the use of carbon adsorption for the reduction of haloform precursors (Anderson et al., 1981) and trihalomethanes produced by chlorination process, has contributed to a comprehensive investigation of adsorption characteristics of natural organic compounds (McCreary and Snoeyink, 1981). Many recent works showed the influence of adsorption system characteristics, such as pH, salt type, salt concentration and ionic heterogeneity in multicomponent adsorption systems, on the removal efficiency of humic and fulvic substances by activated carbon (McCreary and Snoeyink, 1980; Randtke and Jepsen, 1982; Weber et al., 1983). The purpose of this study is to examine the effect of a main component of domestic detergents, sodium triphosphate (STP), on the adsorptive capacities of powdered activated carbon (PAC) for commercially supplied humic acids, at different pH values in distilled water. Also, the effect of STP concentration and pH on the adsorption affinity of the PAC for humic acids, is discussed in relation with electrokinetic properties of carbon particles (zeta potential measurements).A first batch equilibrium study (Figs 1 and 2), showed an effective enhancement of adsorption capacity for humic acids as a function of STP concentration, in a non buffered media (pH of distilled water, close to 5.0). For example, visible absorption analysis of humic acids indicates an increase of 93% (500 mg l?1 PAC) and 133% (1000 mg l?1 PAC) in the carbon adsorption efficiency for a STP concentration from 0.2 to 1.0mM. A second batch equilibrium study (Figs 3 and 4) led to adsorption isotherms for humic acids in distilled water, as a function of STP concentration and initial pH value of the non buffered multicomponent system. Freundlich isotherms showed an increase in the adsorption capacity of the PAC for humic acids, with a decrease in pH and an increase in STP concentration. However, the adsorption capacity for humic acids is quite reduced at high pH values in presence of STP, in comparison with results obtained with distilled water.Electrokinetic measurements on PAC suspensions (Fig. 5) indicates that both humic acids and STP induce a negative variation of the zeta potential of carbon particles. In such a binary system, the zeta potential is a linear function of the pH; the negative surface charge of the carbon increasing with an elevation of pH (Fig. 6). Therefore, it appears that some adsorption of triphosphate polyanion from solution could occur, contributing then to the apparent negative surface charge of PAC particles.It has been previously showed that the type of anion in sodium salts, had little effect on the enhancement of adsorptive capacities of activated carbon for humic substances (Lafrance and Mazet, 1985), due to Na+ ions. However, adsorption of TP anions on the carbon surface may produce a source of repulsive charges, unfavourable to the co-adsorption of humic acids as the pH of the binary system reach more basic conditions. The influence of possible electrostatic interactions between adsorbates at the carbon surface, on the adsorption efficiency for humic acids, could then be studied by zeta potential measurements of PAC particles during the adsorption process. 相似文献
74.
A direct measurement of the dynamics of electrons in the X6 valley for a GaAs crystal by time-resolved absorption spectroscopy is reported for the first time. IR picosecond probe pulses were used to monitor the growth and decay of the population in the X6 valley subsequent to excitation by a 527 nm pump pulse. The intervalley X6→Γ6, L6 scattering time tx of 0.70 ± 0.50 ps is determined and the crossection for the X6→X7 transition is estimated to be 1.8 × 10−16 cm2. 相似文献
75.
W. Fischer 《Progress in Organic Coatings》1993,22(1-4):181-193
Corrosion protection of organic coated steel is determined by free corrosion potential measurements and impedance spectroscopy. The results are classified by means of very basic considerations and evaluation figures are developed. These electrochemical data are correlated with the extent of the corrosion for each coating system. The evaluation figures are used for ranking coating systems and this ranking is correlated with the ranking with reference to the results of standardized and exposure tests. 相似文献
76.
Providing performance guarantees for arriving traffic flows has become an important measure for today’s routing and switching systems. However, none of current scheduling algorithms built on CICQ (combined input and cross-point buffered) switches can provide flow level performance guarantees. Aiming at meeting this requirement, the feasibility of implementing flow level scheduling is discussed thoroughly. Then, based on the discussion, it comes up with a hybrid and stratified fair scheduling (HSFS) scheme, which is hierarchical and hybrid, for CICQ switches. With HSFS, each input port and output port can schedule variable length packets independently with a complexity of O(1). Theoretical analysis show that HSFS can provide delay bound, service rate and fair performance guarantees without speedup. Finally, we implement HSFS in SPES (switch performance evaluation system) to verify the analytical results. 相似文献
77.
感覆盖率是WSN系统中重要的性能指标之一。Sink节点的移动性能提高系统的传感覆盖率,人工势场能描述普通节点与Sink节点之间的关系。提出了一种利用人工势场方法有效的Sink节点移动控制策略,通过Sink节点的移动能够提高系统的传感覆盖率。普通节点搜集的数据能通过多跳的方式传送给Sink节点。在最初的随机部署之后,由人工势场产生的力迫使移动Sink节点移动到整个环境中的平衡点以获得更高的传感覆盖率。在整个算法执行过程中无需事先了解环境的情况,此方法能在实时的环境中采用。给出了具体的算法步骤,最后利用一个仿真实例对控制效果进行了说明。 相似文献
78.
79.
项敏 《网络安全技术与应用》2012,(4):66-68
本文介绍了网卡绑定技术在音频工作站网络中的应用和实施,解决了网络存在的现实问题,给进一步完善安全播出提供了新途径。 相似文献
80.
制备了基于一种简单的金属铜配合物2,4-二羟基苯甲酸铜(Ⅱ)(Cu(Ⅱ)DHBA)为载体的PVC膜硫氰酸根离子(SCN-)选择性电极。该电极在1.0×10-1~1.0×10-6mol/LSCN-浓度范围内呈现斜率为-59.5mV/dec的近Nernst电位响应,检测下限为9.1×10-7mol/L。利用紫外可见光谱及交流阻抗技术初步探讨了电极对SCN-呈现的选择性电位响应机理。该电极作为直接电位分析法的指示电极,成功运用于实验室废水中硫氰酸盐含量的测定。 相似文献