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991.
Amy?Richards Chakra?WijesunderaEmail author Phil?Salisbury 《Journal of the American Oil Chemists' Society》2005,82(12):869-874
Lipid oxidation is a major factor affecting flavor quality and shelf life of vegetable oils. Oxidative stability is therefore
an important criterion by which oils are judged for usefulness in various food applications. In this study a method based
on headspace analysis was developed to evaluate relative oxidative stability of canola oils. The method does not require the
use of chemicals, involves minimal sample preparation, and can be performed on a relatively small sample size in comparison
with traditional wet chemical methods. Canola oils freshly extracted in the laboratory from different seed samples were subjected
to accelerated oxidation and analyzed for PV by standard methods and headspace volatiles by solid phase microextraction/GC-MS.
Forward stepwise regression analysis of the data revealed a relationship between PV and headspace concentration of the volatile
lipid oxidation products hexanal and trans,trans-2,4-heptadienal. The PV calculated using this formula correlated (R
2=0.73) with those measured by conventional methods.
Presented in part at the 96th Annual Meeting of the AOCS, 1–4 May 2005, Salt Lake City, UT. 相似文献
992.
介绍了炼油过程中多产石油化工原料的有关工艺技术,从化学结构转化角度阐明了理论依据.由于原油特别是重油中丰富的烷基碳、环烷碳和芳碳资源均能通过一定途径转化为低碳烯碳以及芳碳,其潜在资源超过单纯依靠石脑油所能提供的数量,因而在经济合理和技术可行的原则下尽量提高其转化率成为当前炼油-化工一体化的研究热点. 相似文献
993.
运用价值链分析方法对炼油厂内、外部的价值活动进行了分析,将炼油厂内部价值链划分为主生产作业链、辅助生产作业链和辅助价值链三部分,通过分析指出产品结构不合理、炼油成本较高是影响炼油业务价值的主要原因,针对企业实际情况,提出价值链优化调整策略:提高炼油技术水平,优化装置结构和产品结构,增产高附加值产品,不断提高企业经济效益。 相似文献
994.
R. Maurin K. Fellat-Zarrouck M. Ksir 《Journal of the American Oil Chemists' Society》1992,69(2):141-145
The distribution of fatty acids between the sn-1, sn-2 and sn-3 positions of triacylglycerols fromArgania spinosa seed oil of Morocco has been determined. Saturated fatty acids showed a preference for external positions. The sn-1 position
contained slightly more palmitic acid than the sn-3 position, whereas stearic acid was preferentially esterified at the sn-3
position. Linoleic acid occurred predominantly in the sn-2 position with lesser amount evenly distributed between the sn-1
and the sn-3 positions, as generally found in vegetable oils. Oleic acid was distributed with a slight preference shown for
the internal position, whereas the distribution between the external positions revealed a slight preference for the sn-1 position.
The distribution of the triacylglycerols determined from high-performance liquid chromatography (HPLC) is at variance with
that calculated from the 1-random 2-random 3-random distribution theory. This is particularly true for trioleoyl and trilinoleoylglycerols.
In contrast, the agreement between theory and experiment is good for triacylglycerols containing two oleoyl and one linoleoyl
chains, one oleoyl, one linoleoyl and one palmitoyl chains or one oleoyl, one palmitoyl, and one stearoyl chains. 相似文献
995.
介绍了石化集团原油资源现状,分析了原油资源配置过程中存在的主要问题,提出了资源优化配置的原则与基本思路,及实施原油资源优化配置的配套措施和建议。 相似文献
996.
Jozef Kula Magdalena Sikora Robert Dabrowski 《Journal of the American Oil Chemists' Society》1994,71(5):545-546
A one-step procedure is described for the synthesis of (E)-2-nonenal from commercial castor oil by ozonolysis in methanol, followed by reduction of the ozonide products with dimethyl
sulfide and exposure of the resulting intermediate product to dilute sulfuric acid. The developed process allows the production
of the aldehyde with a yield of 80% at a purity of 95%. The method has advantages over all those reported earlier, because
of inexpensive raw material and reducing agent, recycling of the solvent and its unusual simplicity. 相似文献
997.
Castor oil dehydration kinetics 总被引:4,自引:0,他引:4
F. Seniha Guner 《Journal of the American Oil Chemists' Society》1997,74(4):409-412
The dehydration reaction kinetics of castor oil was investigated with sodium bisulfate-sodium bisulfite mixture (SB-SB) or
p-toluenesulfonic acid as catalyst. Reactions were carried out at 210, 220, and 230°C, and a kinetic model was determined for
each case. The reactions with SB-SB catalyst at 210 and 220°C and with p-toluenesulfonic acid at 210°C followed second-order kinetics. A first-order rate equation showed the best fit to the experimental
data for the reaction with SB-SB at 230°C. p-Toluenesulfonic acid-catalyzed reactions at 220 and 230°C were also first-order reactions. Additionally, some mathematical
equations were derived between iodine value, refractive index, viscosity, and reaction time. 相似文献
998.
V. Shukla M. Singh D. K. Singh Ri Shukla 《Surface Coatings International Part B: Coatings Transactions》2005,88(3):217-220
Summary Over the past few years, the challenges of globalisation, consolidation and economical point of view have meant that manufacturers
of epoxy formulations have to constantly improve their capability to meet the needs of customers. An active area for advancement
is that of epoxy and polyamide resin with castor oil. Generally, people working in the coating industries are familiar with
castor oil, but this paper provides information on the new use of castor oil in epoxy and polyamide resin. This novel product
(castor oil-modified epoxy resin/castor oil-modified polyamide) provides a previously unattainable combination and improved
flexibility and toughness to a variety of ambient cure applications. This communication will review the performance of these
castor oil-modified epoxy and polyamide resin surface coatings and adhesives. Based on the results of this study, these systems
offer some advantages without much affecting the traditional properties of epoxy and polyamide resin in a variety of applications. 相似文献
999.
A. C. Lanser G. R. List R. K. Holloway T. L. Mounts 《Journal of the American Oil Chemists' Society》1991,68(6):448-449
A user-interactive computer-assisted Fourier transform infrared (FTIR) method has been developed for estimation of free fatty
acids (FFA) in vegetable oil samples by deconvolution of the infrared (IR) absorbances corresponding to the triglyceride ester
and FFA carbonyl bonds. Peak areas were used to determine FFA as a percentage of the total carbonyl areas in weighed standards
of refined, bleached, deodorized soybean oil containing from 0 to 5% added oleic acid. These data for percent FFA by FTIR
were compared to corresponding FFA data obtained by two titration methods-the AOCS Official Method Ca 5a-40 and the Official
Method with a slight modification. Correlation coefficients were 0.999 for the Ca 5a-40, 0.999 for the modified and 0.989
for the FTIR methods. FFA in samples of crude soybean oils extracted from damaged beans (0.5 to 2.1% FFA) were measured by
FTIR and compared to data obtained by titration of the same samples (correlation coefficient, 0.869).
To whom correspondence should be addressed at National Center for Agricultural Utilization Research, Agriculture Research
Service, U.S. Department of Agriculture, 1815 North University Street, Peoria, IL 61604.
1The mention of firm names or trade products does not imply that they are endorsed or recommended by the U.S. Department of
Agriculture over other firms or similar products not mentioned. 相似文献
1000.
W. Dennis Pocklington 《Journal of the American Oil Chemists' Society》1992,69(8):789-793
The development, by collaborative study, of a standardized method for the determination of tetrachloroethylene in olive oils
is described. The results of the study, which was carried out in 1989 under the direction of the International Olive Oil Council
(IOOC), are presented and show that tetrachloroethylene can be readily determined, to an acceptable degree of precision, by
gas-liquid chromatography with electron capture detection. A limited number of results obtained for the determination of trichloroethylene
and chloroform by the same method indicate that a similar precision could be obtained with the method when determining these
solvents also. 相似文献