关于燃煤电厂脱除NOx的技术分析

本文简要介绍了燃煤电厂NOx形成的原因。在对火电厂炉内和烟气中脱氮技术分析的基础上,针对我国国情和现阶段我国烟气净化的发展状况,提出了烟气脱氮技术在我国的实施建议。     

Structural and vibrational properties of high-dielectric oxides, HfO2 and TiO2: A comparative study

Within the framework of density functional theory, we have computed structural and vibrational properties of high-κ dielectric oxides, HfO₂ and TiO₂. We have considered different polytypes of these oxides and computed the corresponding static dielectric constants in order to investigate what are the more promising materials suitable for technological application. We found the flourite phase of hafnium dioxide, that is a promising candidate as gate oxide in ultra-scaled complementary metal-oxide-semiconductor (CMOS) technology, is structurally unstable due to the presence of soft phonon modes that have wave-vectors in the region of the Brillouin zone containing the K- and X-points. According to our results, the fluorite TiO₂ is structurally unstable as well but, contrary to HfO₂, the soft phonon modes have wave-vectors in the whole Brilouin zone. Calculations of the thermodynamical properties of the baddeleyite HfO₂, the stable phase at ambient condition, complete the work.     

La0.6Sr0.4Co1-yFeyO3的混合导电性研究

采用直流四探针法和两端子电子阻塞电极交流阻抗谱研究了GNP法制备La0．6Sr0．4Co1-yFeyO3陶瓷的电子-离子混合导电性能．在室温-900℃范围内，La0．6Sr0．4CoO3的电子电导率随温度的升高而单调降低，其它样品的电子电导率随温度的升高在600℃附近达到最大值．La0．6Sr0．4Co1-yFeyO3陶瓷的氧离子电导率随温度的升高而增加．在相同温度下，随着Co／Fe比例的增加，La0．6Sr0．4Co1-yFeyO3陶瓷的电子电导率和氧离子电导率增加，电子导电活化能和离子导电活化能降低．氧离子迁移数随温度的升高而增加，随Co／Fe比例的增加而降低．     

传统流程生产超细钨粉的工艺优化

通过对不同氧化钨原料的筛选和钨粉生产传统流程工艺的优化,可以生产出BET粒度0.1μm以下的超细钨粉,并筛选出紫色氧化钨是目前以传统工艺制取超细钨粉的理想原料。     

压水堆一回路模拟腐蚀氧化物的溶解去污试验

本文介绍了对两种压水反应堆一回路模拟腐蚀氧化物（铁镍铬氧化物和铁镍氧化物）的溶解去污试验结果。选择的去污剂为0.3%草酸、0.1%柠檬酸和0.1%高锰酸钾。结果表明，实验温度为95℃、去污时间在6－48h范围内，0.3%草酸对铁镍铬氧化物和铁镍氧化物的溶解率分别为24.1%-65.3%和4.9%-64.4%；0.1%柠檬酸对二者的溶解率分别为2.2%-4.4%和0.37%-1.55%；0.1%高锰酸钾对二者几乎没有溶解作用。采用在草酸或柠檬酸去污前使用高锰酸钾去污剂的二步去污法，对两种氧化物的溶解度小于单独使用草酸或柠檬酸去污的一步法。     

双束强辐照对氧化物弥散强化铁素体型合金强化相稳定性影响

采用双束复合辐照装置,研究了He存在条件下,强辐照对长期时效后的ODS合金中强化相(Y2O3)的稳定性和辐照损伤特征的影响。实验结果表明:双束强辐照下,ODS合金中强化相不稳定,发生聚集长大并造成附近基体中Ti、Y浓度增高,导致空洞尺寸和空洞肿胀增加,并对这一结果从理论上进行解释。     

Roles of Metallic Oxides in the Elimination Reactions of NO

The catalytic effect of several metallic oxides(Fe2O3, Cr3O3 and Ni2O3) on elimination of NO has been studied in a flow type reactor, and the roles of metallic oxide in the elimination reactions of NO has also been discussed. The results show that in the system of NO-CO-CO2-N2, the catalytic reaction of NO/CO on the metallic oxide plays a leading role in NO elimination especially for Fe2O3 and Cr2O3 samples. However, Ni2O3 and its pre-reduced samples show extremely remarkable catalytic effect on direct decomposition of NO.     

Cathodoluminescence study of semiconductor oxide micro- and nanostructures grown by vapor deposition

Nano- and microstructures of SnO(2), In(2)O(3) and ZnO have been grown during thermal treatment of compacted powders under argon flow. Indium-doped SnO(2) tube-shaped structures with rectangular cross-section are obtained by adding a fraction of In(2)O(3) to the starting SnO(2) powder. In-rich nanoislands were found to grow on some edges of the tubes. ZnO nanostructures doped with Sn or Eu were grown by adding SnO(2) and Eu(2)O(3) powder, respectively, to the ZnO precursor powder. All the samples have been characterized by the emissive and cathodoluminescence (CL) modes of scanning electron microscopy. CL images from SnO(2):In and In(2)O(3):Sn tubes and islands show a higher emission from the Sn-rich structures related to oxygen deficiency. CL of doped ZnO enables to detect the presence of dopant in specific regions or structures. CL appears to be a useful technique to study optical and electronic properties of semiconductor oxide nanostructures.     

变价稀土氧化物对催化剂性能的影响

本文从原子结构分析了变价稀土元素原子的结构特点 ,从机理上分析了变价稀土氧化物对催化剂原子氧化价的稳定性、贮氧能力和热稳定性等性能增强的根源 ,从理论上深入认识了稀土氧化物的助催化作用。