Determination of the liquidus lines and isotherms of the Hg-Zn-Te system by a modified direct observation method

The modified direct observation method is employed for the determination of the liquidus lines in the (Hg_{1_x}Zn_x)_{1_y}Te_y, ternary system. The liquidus temperatures of the ternary samples of various compositions withx from 0.05 to 0.30 andy from 0.5 to 0.9 are measured. The temperature-composition phase diagrams and some liquidus isotherms are established for this system.     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

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通过对J.J.Arps方程的推导,提出了油气藏产量递减曲线分析的最佳拟合法。用该法可直接求出递减指数N、初始递减率D1及油气递减前的稳定产量Qi,避免了使用试差法的大量运算过程,大大提高了油气藏工程中指标预测的精度。     

An Arctangent Unwrapping Technique of Photoelasticity Using Linearly Polarized Light at Three Wavelengths

Abstract:  In the automatic measurements of the principal stress directions ψ and the total relative phase retardation ρ _tol, ψ and ρ _tol can be easily obtained by the phase unwrapping method using the arctangent function. However, only some published works exist on the measurements of ψ and ρ _tol by photoelastic techniques using a linearly polarised incident light source. This paper presents the technique of applying an unwrapping by means of the arctangent function to photoelasticity. The technique overcomes the error associated with the quarter-wave plate by using an incident light of different wavelength and does not need an interpolation for the determination of ψ . The technique is validated by determining ψ and ρ _tol for the well-known circular disk subjected to a diametral compressive load model.     

软起动器在烧结机混料系统中的应用

软起动器以微处理器为核心，能够产生平滑的电压起动曲线，可任意设置稳定的起动电流，并具有多种保护。张钢24m^2烧结机混料系统应用软起动器后，交流电机起动平滑、无噪声，年节电5．6万kW．h，经济效益约2．4万元。     

基桩反射波法动测曲线的数值模拟与特征分析

采用美国PDI公司开发的PDI-S软件,对不同缺陷基桩的反射波法低应变动测曲线进行数值模拟,对动测曲线的特征进行归纳与总结,以便在解释反射波法曲线时作为参考与借鉴,提高基桩质量检测的可靠度。     

Calendar maintenance of arbitrarily structured systems

A semi-Markov model is constructed that describes an arbitrarily structured multicomponent technological system and takes into account its calendar maintenance. Using an aggregation algorithm, approximate values of stationary reliability characteristics and an optimal term of maintenance work are determined for the system. __________ Translated from Kibernetika i Sistemnyi Analiz, No. 2, pp. 69–86, March–April 2006.     

Phase separation studies in RIM polyurethanes catalyst and hard segment crystallinity effects

Polyurethanes were prepared from pure 4,4′-diphenylmethane diisocyanate (MDI), 1,4-butane diol (BDO) or 1,2-ethane diol (EDO) and α,ω-hydroxyl poly(propylene oxide) (PPO) by reaction injection moulding (RIM). Hard segment (MDI + BDO or EDO) level was 45–50 wt%. The PPO had about 20% ethylene oxide copolymerized in at the chain ends to provide 80% primary OH end groups. M_n was varied from 2000 to 4000. Dibutyl tin dilaurate catalyst and mould temperature were varied. Dynamic mechanical, wide-angle X-ray, differential scanning calorimeter, molecular weight and tensile elongation measurements were made on the RIM polyurethanes. At low reaction rates (low catalyst or temperature) highly crystalline, well phase separated but low molecular weight polymers were produced. At high catalyst or temperature levels more poorly phase separated but high molecular weight, tough polymers resulted. Higher M_n PPO gave better phase separation and EDO gave higher melting temperatures. Preventing hard segment crystallinity by substituting asymmetric MDI or glycols resulted in phase compatibility.     

N.m.r. study of the ferroelectric phase transition in a 7030mol% copolymer of vinylidene fluoride (VF2) and trifluoroethylene (TrFE)

Nuclear magnetic resonance (n.m.r.) studies of ¹⁹F nuclei in a $\text{70}\text{30}\text{mol}\text{\%}$ random copolymer of vinylidene fluoride and trifluoroethylene were performed at 9.14 MHz and 20.0 MHz. The free induction decays (FIDs) were analysed in terms of two T₂ components attributed to the amorphous and crystalline portions of the polymer. The changes in crystallinity as well as the effects of the ferroelectric transition were observed during cycles of heating and cooling between 20°C and 140°C. The crystalline component of the FID lengthens by a factor of 2 at 100°C on heating and decreases by this factor at 60°C on cooling, thus exhibiting the thermal hysteresis of this ferroelectric transition. The spin-lattice relaxation was also investigated. From measurements at 9.14 MHz the observed longitudinal relaxation time T₁ appears to be dominated by the dynamics of the amorphous phase and exhibits no anomaly through the phase transition. However, from measurements at 20 MHz, well defined minima of T₁ were observed, which are associated with the ferroelectric transition (especially after repeated annealing of the samples). Results are discussed in terms of the crystalline phase structure, which appears dynamically disordered above the ferroelectric phase transition. An analogy is considered with the plastic phase transitions encountered in molecular crystals.     

修正步冷温度曲线试验研究

按修正步冷温度曲线对经步冷脆化的 2 .2 5Cr 1Mo和在加氢反应器内运行 5a的 2 2 5Cr 1Mo试块进行了修正步冷试验 ,评定了材料的回火脆性。结果表明 ,按修正步冷曲线进行修正步冷试验能使已经脆化的材料进一步脆化 ,为加氢反应器材料损伤的研究提供了一条途径。