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61.
62.
湿法相分离不对称超滤膜形成机理 总被引:1,自引:0,他引:1
本文选择了憎水的极怀非普质子性聚砜和亲水的极性质子怀聚砜酰胺两种膜材料,从铸膜液组成和凝胶过程两方面,用气相色谱和高效液相色谱研究了表征膜材料-溶剂-添加剂-水作用力的混合自由焓,平衡分配常数,及其与膜性能,不同溶剂特性粘度,雾点值和溶解度参数的关系,提出了铸膜液中有机溶剂的作用机理,及不对称超滤膜形成的一些规律。 相似文献
63.
针对建设设计阶段独立使用价值工程、优化设计和限额设计等方法进行投资控制的局限性,借鉴系统论、控制论、信息论等思想和方法,建立了设计阶段投资控制系统。系统主要由探测元件、控制元件和执行元件组成,探测元件进行设计阶段的信息收集;控制元件通过审核将各项投资控制活动与投资控制目标进行对比,提出应对策略;执行元件完成应对策略。通过投资控制系统的执行,实现对设计阶段各项活动的全面系统控制,从管理层面上解决设计阶段投资控制活动割裂问题,进而改善设计阶段整体投资控制效果。 相似文献
64.
依据弱耦合状态下的量子点-腔系统,提出了1个控制Z门和1个条件相位门.利用这个控制Z门并且测量光子和第1个电子的状态,可以将这个量子态转移到第2个电子上,从而实现2个远距离量子点之间的远程量子态转移.这些方案都是在弱耦合状态下实现的,不需要对腔有严格的要求. 相似文献
65.
66.
Confining a binary mixture, one can profoundly alter its miscibility behavior. The qualitative features of miscibility in confined geometry are ratheruniversal and shared by polymer mixtures as well as small molecules, but the unmixing transition in the bulk and the wetting transition are typically well separated in polymer blends. The interplay between wetting and miscibility of a symmetric polymer mixture via large-scale Monte Carlo simulations in the framework of the bond fluctuation model and via numerical self–consistent field calculations is studied. The film surfaces interact with the monomers via short ranged potentials, and the wetting transition of the semi–infinite system is of first order. It can be accurately located in the simulations by measuring the surface and interface tensions and using Young’s equation. If both surfaces in a film attract the same component, capillary condensation occurs and the critical point is close to the critical point of the bulk. If surfaces attract different components, an interface localization/delocalization occurs which gives rise to phase diagrams with two critical points in the vicinity of the pre-wetting critical point of the semi–infinite system. The crossover between these two types of phase diagrams as a function of the surface field asymmetry is studied. The dependence of the phase diagram on the film thickness Δ for antisymmetric surface fields is investigated. Upon decreasing the film thickness, the two critical points approach the symmetry axis of the phase diagram, and below a certain thickness Δtri, there remains only a single critical point at the symmetric composition. This corresponds to a second-order interface localization/delocalization transition even though the wetting transition is of first order. At a specific film thickness, Δtri, tricritical behavior is found. The behavior of antisymmetric films is compared with the phase behavior in an antisymmetric double wedge. While the former is the analog of the wetting transition of a planar surface, the latter is related to the filling behavior of a single wedge. Evidence for a second-order interface localization/delocalization transition in an antisymmetric double wedge is presented, and its unconventional critical behavior is related to the predictions of Parry et al. (Phys. Rev. Lett. 83:5535 (1999)) for wedge filling. The critical behavior differs from the Ising universality class and is characterized by strong anisotropic fluctuations.Invited paper presented at the Fifteenth Symposium on Thermophysical Properties, June 022–27, 2003, Boulder, Colorado, U.S.A. 相似文献
67.
对ITO粉样品用Rietveld全谱图拟合法进行了定量相分析,该样品由立方晶型的In2O3和少量的四方晶系的SnO2所组成。In2O3和SnO2质量百分含量分别为94.23%和5.77%。结果表明,用Rietveld法进行了定量相分析是非常有效和准确的。 相似文献
68.
Ki-Won Kim Pyeong-Seok Cho Jong-Heun Lee Seong-Hyeon Hong 《Journal of Electroceramics》2006,17(2-4):895-898
A new method for preparing SnO2 whiskers by the decomposition of SnC2O4 is suggested. A Whisker-like morphology of a SnC2O4 precipitate was attained via the gradual addition of an oxalic acid solution to a hot SnCl2 aqueous solution (T > 50∘C). In comparison, when the solution temperature was either lower than 50∘C or when ethanol was used as the solvent, the SnC2O4 precipitate showed an angular and relatively isotropic morphology. The morphology of the SnC2O4 precipitate remained even after its thermal decomposition into SnO2 at 400∘C indicating that SnC2O4 precipitation is a key step in preparing the whiskers. The formation mechanism of SnO2 whiskers was explained by the supersaturation during the precipitation of SnC2O4. 相似文献
69.
70.
A. A. Kalachev N. M. Blashenkov Yu. P. Ivanov V. A. Marikhin A. L. Myasnikov L. P. Myasnikova 《Measurement Techniques》2005,48(8):773-778
A nanoluminescent device, or nanoluminograph, has been developed, created, and patented. By means of the device, unique information
about the physicochemical properties of surface and near-surface layers of solids and ultrathin coatings of thickness less
than 0.4 μm may be obtained. There is also the hope of decreasing the thickness of the subject layer with further development
of the detecting component of the device.
__________
Translated from Izmeritel'naya Tekhnika, No. 8, pp. 28–31, August, 2005. 相似文献