太阳能电池有机电子传输材料研究新进展

当今能源危机问题日益紧迫,以太阳能为代表的新能源开发成为研究热点。有机半导体材料具有成本低廉、可塑性强、性能优异等特点,因此在太阳能电池领域中具有极大的应用前景。研发性能优异、成本低、稳定性高的有机电子传输材料是太阳能电池研究领域的重要内容。总结了近年来有机电子传输材料的研究进展和发展方向,按照其分子结构分为富勒烯衍生物、大π共轭体系、非π体系、改性材料、碳纳米材料等5类体系,分别介绍了其结构特性,讨论了其在太阳能电池应用中存在的问题及解决方法,综述了该领域的最新研究成果,最后总结了开发新型高效的有机电子传输材料的研究方向。     

CuInS2量子点敏化太阳能电池材料的研究进展

CuInS_2量子点因低毒、良好的光电性能和热电稳定性而成为量子点敏化太阳能电池(QDSSC)极具前景的量子点敏化剂。首先简单介绍了CuInS_2量子点材料的光电性质和QDSSC中CuInS_2量子点的合成,然后重点总结了CuInS_2量子点敏化电极的制备及各电池材料对QDSSC性能的影响,最后指出了该电池目前存在的问题以及对未来的展望。     

高效单晶硅太阳电池基区结构设计与参数优化

首先利用TCAD半导体器件仿真软件全面系统地分析了在不同少子寿命的情况下,基区电阻率对常规P型单晶硅太阳电池输出特性的影响。然后基于对仿真结果的分析,提出一种具有非均匀基区的单晶硅太阳电池结构,并对其输出特性进行了仿真研究。结果表明:当少子寿命一定时,存在最优的基区电阻率,使得常规电池的转换效率最大;随着少子寿命的减小,电池最优的基区电阻率减小;提高基区电阻率有利于常规电池长波段量子效率和短路电流的提高,但同时会降低电池的开路电压和填充因子;当少子寿命较低时,非均匀基区结构不具有提高常规电池转换效率的作用。但当少子寿命增大到一定值时,通过优化非均匀基区的表面浓度,非均匀基区结构可有效改善常规电池的电学性能。     

燃料电池用QCS键和层析硅胶膜的制备及其性能表征

以季铵化壳聚糖(QCS)和层析硅胶为原料,制备了不同硅胶含量的多孔膜。用傅里叶变换红外(FTIR)和扫描电镜(SEM)对多孔膜的结构和形貌进行表征。同时,考察了层析硅胶的用量对多孔膜的含水率(WU)、溶胀度(SR)、机械性能和电导率的影响。结果表明,随着层析硅胶含量的增加,多孔膜的含水率、溶胀度和电导率均升高,但机械性能下降。当层析硅胶的用量为40%时,多孔膜的含水率高达816%,但是膜的溶胀度仅为189%,拉伸强度为5.6MPa,断裂伸长率为4.2%;在测试温度为70℃时,不同层析硅胶含量多孔膜的电导率数值分布在2.4~3.9×10~(-2)S/cm的范围内,且随硅胶含量的增加而增加。     

稀土上转换发光在钙钛矿太阳能电池中的应用

目前,钙钛矿太阳能电池最常使用的钙钛矿材料为CH_3NH_3PbI_3,其禁带宽度为1.55eV,导致低于该能量值的太阳光的光子无法被直接地吸收利用。因此,提高器件对太阳光谱的响应范围是提高钙钛矿太阳能电池性能的关键。稀土上转换材料可以将低能量近红外光转换为高能量可见光,所以,稀土上转换发光的应用是提高钙钛矿太阳能电池性能的较为可行的途径。本文概述了稀土上转换发光的基本机制,介绍了钙钛矿太阳能电池的结构和工作原理,综述了该太阳能电池的研究现状及其主要优势,重点阐述了稀土上转换发光在钙钛矿太阳能电池中的应用,最后对该太阳能电池的发展前景进行了展望。     

钙钛矿太阳能电池空穴传输材料的研究进展

钙钛矿太阳能电池具有工艺简单、可弯曲、应用前景广阔等优点。从2009年出现起,至今其效率从3.8%提高到了22%以上,引起了研究者的广泛关注。介绍了钙钛矿太阳能电池的基本结构和工作原理,概述了钙钛矿太阳能电池空穴传输材料的研究进展,着重介绍了无机空穴传输材料的研究进展。最后展望了钙钛矿太阳能电池未来的发展与商业化应用。     

Silver nanoparticles reduce the apoptosis induced by tumor necrosis factor-α

Silver nanoparticles (AgNPs) are widely known to have anti-inflammatory properties, but the exact mechanism underlying this anti-inflammatory effect is not clearly understood. Tumor necrosis factor-α (TNFα) is a major pro-inflammatory cytokine that is expressed in the early stage of cell inflammation and induces apoptosis by several known pathways. Our study aimed to investigate the effect of AgNPs on the response of lung epithelial cells to TNFα and the molecular mechanism of this response. Lung epithelial cell line NCI-H292 cells were exposed to AgNPs (5 µg/mL) and/or TNFα (20 ng/mL) for 24 h, then cellular uptake was analyzed using flow cytometry. Our results showed that AgNPs were taken up by cells in a dose-dependent manner and that the cellular uptake ratio of AgNPs was significantly increased in the presence of TNFα. Apoptosis assays indicated that exposure to AgNPs significantly decreased the apoptotic effect of TNFα. Confocal microscopy was used to localize the tumor necrosis factor receptor 1 (TNFR1) and revealed that TNFR1 localized on the surface of cells exposed to TNFα. In contrast, TNFR1 localized inside cells exposed to both AgNPs and TNFα, with very few receptors scattered on the cell membrane. The results indicated that AgNPs reduced the cell surface TNFR1 expression level. The results suggested that the reduction of surface TNFR1 reduced cellular response to TNFα, resulting in an anti-apoptotic effect.     

基于晶格的人工内分泌系统模型及在多机器人系统中的应用

为了解决多机器人系统分布式控制问题,借鉴人体内分泌系统研究的理论成果,提出基于晶格的人工内分泌系统模型.该模型以环境晶格化为基础,以细胞智能化为依托,以累加激素为纽带,以靶细胞为导向,能够适应外环境的持续变化,保持内环境的相对稳定,充分体现人体内分泌系统的自组织和自修复特性.实验结果表明,无需复杂的集中控制策略,基于该...     

Bicriteria robotic operation allocation in a flexible manufacturing cell

Consider a manufacturing cell of two identical CNC machines and a material handling robot. Identical parts requesting the completion of a number of operations are to be produced in a cyclic scheduling environment through a flow shop type setting. The existing studies in the literature overlook the flexibility of the CNC machines by assuming that both the allocation of the operations to the machines as well as their respective processing times are fixed. Consequently, the provided results may be either suboptimal or valid under unnecessarily limiting assumptions for a flexible manufacturing cell. The allocations of the operations to the two machines and the processing time of an operation on a machine can be changed by altering the machining conditions of that machine such as the speed and the feed rate in a CNC turning machine. Such flexibilities constitute the point of origin of the current study. The allocation of the operations to the machines and the machining conditions of the machines affect the processing times which, in turn, affect the cycle time. On the other hand, the machining conditions also affect the manufacturing cost. This study is the first to consider a bicriteria model which determines the allocation of the operations to the machines, the processing times of the operations on the machines, and the robot move sequence that jointly minimize the cycle time and the total manufacturing cost. We provide algorithms for the two 1-unit cycles and test their efficiency in terms of the solution quality and the computation time by a wide range of experiments on varying design parameters.     

基于PDA的血细胞自动计数系统的研究

为克服现有血细胞计数仪结构复杂、体积大的缺点,介绍了一种基于个人数字助理(PDA)的便携式血细胞自动计数系统.本系统具有操作简便、体积小、准确度高等优点,能够满足野外血细胞计数检验的需要.系统包括显微镜、CCD摄像头、PDA,并采用eVC++4.0编程,实现了WIN CE操作系统下细胞图片的实时观察与处理,直接获得细胞...