Synthesis of Hexagonal‐Phase NaYF4:Yb,Er and NaYF4:Yb,Tm Nanocrystals with Efficient Up‐Conversion Fluorescence

IR‐to‐visible up‐conversion fluorescent nanocrystals of hexagonal‐phase NaYF₄:20 %Yb,2 %Er and NaYF₄:20 %Yb,2 %Tm have been synthesized by decomposition of multiprecursors of CF₃COONa, (CF₃COO)₃Y, (CF₃COO)₃Yb, and (CF₃COO)₃Er/(CF₃COO)₃Tm in oleylamine at 330 °C. The average particle size is 10.5 ± 0.7 nm (from random measurements of 200 particles from five transmission electron microscopy images) and 11.1 ± 1.3 nm (from dynamic‐light‐scattering measurements). The up‐conversion fluorescence intensity of the hexagonal nanocrystals in this work is much higher than that of other cubic‐phase NaYF₄:Yb,Er nanocrystals, including the ones in this work (by a factor of 7.5). Mechanisms for nucleation and growth of the hexagonal‐phase nanoparticles are proposed. These nanocrystals are easily dispersed in organic solvents, producing a transparent colloidal solution. The hydrophobic surfaces of the particles are made hydrophilic using a bipolar surfactant. These nanoparticles and their dispersions in various media have potential applications in optical nanodevices and bioprobes.     

厦门市气源转换的技术分析

分析了气源转换时原有输配系统的管道、调压设备、计量设备、用气设备与天然气系统相适应的问题，提出了相应的措施。     

一种VSAT数据通信网络报文传输协议的分析

本文描述并分析了一种适用于多信道ＶＳＡＴ卫星数据通信网的报文传输协议，特别是考虑了无线信道误码率对传输协议的影响，分析表明利用Ｓ－ＲＥ－ＡＬＯＨＡ作为预订信道的多址方式及按报文占用数据信道方法可以减小报文传输延时并增加系统吞吐量。     

LD泵浦Nd：YVO4内腔倍频激光器获得120mW绿光连续输出

利用半导体激光器（ＬＤ）端面泵浦Ｎｄ：ＹＶＯ＿４和用ＫＴＰ内腔倍频的绿激光器获得了１２０ｍＷ连续、稳定的５３２ｎｍ绿激光输出。泵浦阈值Ｐ＿（ｔｈ）＝１６０ｍＷ，光－光转换效率η＿ｓ＝８．１％。换用激光腔输出耦合镜，在不加ＫＴＰ晶体倍频时，可连续输出１．０６μｍ的红外激光，输出功率为４５０ｍＷ，光－光转换效率为３１％。     

Self-stabilizing depth-first token circulation on networks

Summary This paper proposes a self-stabilizing protocol which circulates a token on a connected network in nondeterministic depth-first-search order, rooted at a special node. Starting with any initial state in which the network may have no token at all or more than one token, the protocol eventually makes the system stabilize in states having exactly one circulating token. With a slight modification to the protocol —by removing nondeterminism in the search — a depth-first-search tree on the network can be constructed. The proposed protocol runs on systems that allow parallel operations. Shing-Tsaan Huang was born in Taiwan on September 4, 1949. He got his Ph.D. degree in 1985 from Department of Computer Science, University of Maryland at College Park. Before he pursued his Ph.D. degree, he had worked several years in the computer industry in Taiwan. Professor Huang is currently the chairman of the Department of Computer Science, Tsing Hua University, Taiwan, Republic of China. His research interests include interconnection networks, operating systems and distributed computing. He is a senior member of the IEEE Computer Society and a member of the Association for Computing Machinery. Nian-Shing Chen was born in Taiwan on October 21, 1961. He received his Ph.D. degree in computer science from National Tsing Hua University in 1990. Dr. Chen is currently an associate professor with the Department of Information Management at Sun Yat-Sen University of Taiwan. His research interests include distributed systems, computer networks, computer viruses and expert systems. He is a member of IEEE and Phi Tau Phi honorary society.This research is supported by National Science Council of the Republic of China under the contract NSC81-0408-E-007-05 and NSC82-0408-E-007-027     

Probing acid sites in MAPO-36 by solid state NMR

An ordering of magnesium is observed in the as-synthesized MAPO-36 molecular sieve. Upon calcination, part of the magnesium is removed from the sample and part occupies extraframework positions thus rendering a random distribution of magnesium in the lattice. The shoulder observed in the³¹P spectrum of the calcined sample is assigned to P(3Al, 1Mg) sites in conflict with the earlier assignment to P-OH groups. The bridging hydroxyl groups located at these sites are detected in the¹H MAS spectrum at 3.6 ppm. Further, MAPO-36 catalyzed acetone conversion to mesityloxide that cracked at elevated temperature to yield acetic acid and aliphatics.     

Volumetric three‐dimensional up‐conversion display medium

Abstract— Several rare‐earth‐doped fluoride crystals that are excited to emit visible light by sequential two‐photon absorption have been investigated as display‐medium candidates for static volumetric three‐dimensional displays. Dispersion of powders of these materials in a refractive‐index‐matched polymer is reported because such a medium may result in a scalable display. The scattering problem in such a medium is greatly reduced by index‐matching the polymer to the crystalline particles. An index‐matching condition that optimizes the performance is identified.     

后工业时代米兰单功能城区更新

在物化的形式上,解释米兰城市发展历史上的单功能城区的改造意义,并由此分析单功能城区更新的经验:单功能城区向混合居住模式的更新是发展方向;城区的功能重新定义对城区发展有重要意义;以新的建设为基础,发展城区自身的特色,做到城市在更新和特色之间的协调。     

Using linear models in optimizing parameters of time-triggered protocols

A mechanism of synchronization of components of distributed systems in which communications are based on a common time schedule for all system components is illustrated by examples of simple Time-Triggered Protocols. For parametric linear models of synchronization, the optimization problem is considered for a parameter that should exclude the overlapping of messages in communication channels. The results of using numeric methods for estimation of the optimal value of this parameter are described. __________ Translated from Kibernetika i Sistemnyi Analiz, No. 3, pp. 24–32, May–June 2006.     

协议宏功能在PLC串行通信中的应用

越来越多的自动化设备自身配置有串行通信接口（如自动化仪表、变频器、伺服驱动器等）,在工业控制现场与可编程逻辑控制（PLC）之间需要进行大量的数据传输,包括现场数据采集、设备的远程控制等。本文以欧姆龙中型CJ2系列PLC协议宏功能为例,比较以往串行通信功能,在可靠性、程序繁琐程度、调试方便性等几方面的优越性。