油气集输系统新增产能建设拓扑优化方法研究

在油气集输新增产能建设中,为充分利用已建管网系统的处理能力,达到降低投资,提高经济效益的目的,进行了油气集输新增产能建设布局优化方法的研究。针对新建集输管网为树状结构的情况,建立了油气集输系统新增产能建设拓扑优化的数学模型,讨论了计算复杂性问题。根据模型的特点,将问题分解为拓扑级优化和几何级优化两个子问题,并通过它们之间的迭代进行求解。实例计算表明,所建立的数学模型正确,求解方法可行,能用于工程实际设计。     

Synthesis of 2,7‐Carbazolenevinylene‐Based Copolymers and Characterization of Their Photovoltaic Properties

New electroactive and photoactive conjugated copolymers consisting of alternating 2,7‐carbazole and oligothiophene moieties linked by vinylene groups have been developed. Different oligothiophene units have been introduced to study the relationship between the polymer structure and the electronic properties. The resulting copolymers are characterized by UV‐vis spectroscopy, size‐exclusion chromatography, and thermal and electrochemical analyses. Bulk heterojunction photovoltaic cells from different copolymers and a soluble fullerene derivative, [6,6]‐phenyl‐C₆₁ butyric acid methyl ester, have been fabricated, and promising preliminary results are obtained. For instance, non‐optimized devices using poly(N‐(4‐octyloxyphenyl)‐2,7‐carbazolenevinylene‐alt‐3″,4″‐dihexyl‐2,2′;5′,2″;5″,2″′;5″′,2″″‐quinquethiophenevinylene 1″,1″‐dioxide) as an absorbing and hole‐carrier semiconductor exhibit power conversion efficiency up to 0.8 % under air mass (AM) 1.5 illumination. These features make 2,7‐carbazolenevinylene‐based and related polymers attractive candidates for solar‐cell applications.     

Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry     

Low Electrical Percolation Threshold of Silver and Copper Nanowires in Polystyrene Composites

Silver and copper nanowires have been synthesized using a scalable method of AC electrodeposition into porous aluminum oxide templates, which produces gram quantities of metal nanowires ca. 25 nm in diameter and up to 5 and 10 μm in length for Ag and Cu, respectively. The nanowires have been used to prepare polystyrene nanocomposites by solution processing. Electrical resistivity measurements performed on polymer nanocomposites containing different volume fractions of metal indicate that low percolation thresholds of nanowires are attained between compositions of 0.25 and 0.75 vol %.     

钠冷快堆中喷雾钠火的计算分析

根据钠冷快堆中喷雾钠火的特点建立了理论模型，编制了SSPRAY程序。该程序模拟钠喷雾燃料过程中钠滴的运动、钠和氧气的燃烧反应、热量传递和质量传递等瞬态过程。用该程序计算了气体和墙壁温度、气体压力、氧气摩尔份额、喷雾流燃烧速率和热量热递速率等主要参数。利用AI实验数据和美国SPRAY－3A的计算结果对程序进行了验证，结果符合较好。     

槽孔式水力驱动控制棒槽孔阻力系数实验研究

对槽孔式水力驱动控制棒槽对孔阻力系数进行了大量实验研究，获得了槽孔式水力驱动控制棒槽对孔阻力系数和其随槽对孔位移的变化规律，分析了槽对孔阻力系数与控制棒槽对孔结构参数之间的关系。结果表明：随槽对孔位移的增加，槽对孔阻力系数从某一较大的定值迅速降低到某一较小的定值，然后再迅速反回到初始的定值，形成一个对称的宽幅波谷；槽高使阻力系数曲线波谷幅宽发生变化，也使完全不重合段的阻力系数发生变化；随内套孔径的增大，阻力系数有所降低，其对阻力系数的影响也进一步减弱。孔径增大到一定程度，阻力系数基本不受孔径参数的影响。     

Kinetic study of the hydrolysis of isocyanic acid in the gas phase

The hydrolysis of isocyanic acid in the gaseous phase has been investigated at temperatures between 553 and 613 K by mass spectrometry and evaluated to obtain the corresponding kinetic data. The reaction order and reaction constant have been determined. Finally, the influence of water on the catalysed formation of melamine from isocyanic acid under the operating conditions employed has been investigated in order to determine whether there is a need to try the process gas.     

工业聚合反应装置 Ⅴ.流化床气相聚合反应器

简介了流化床气相聚合反应器的原理和6种典型的聚合装置。     

变结构变参数设计方法及其在机械CAD中的应用

提出了一种新颖的机械结构设计思想－变结构变参数设计方法，并结合实例，阐述了变结构变参数设计的概念、原则、实施措施和意义。由此对Ｉ－ｄｅａｓ软件包进行了二次开发，编制了发动机曲轴专用ＣＡＤ软件程序，并用某型号发动机曲轴进行了验证。