Phase separation in polymer blends comprising copolymers: 6. Effect of molecular architecture of block copolymers

To study the effect of the molecular architecture of a copolymer on its miscibility with corresponding homopolymers a series of block copolymers of styrene and isoprene with diblock, triblock and four-arm star architectures have been prepared and the morphologies of the blends of the copolymers and polyisoprene with different molecular weights have been examined by electron microscopy. The results show that miscibility varies in the sequence diblock>triblock>four-arm star copolymers. This sequence is in the opposite direction to the variation of the architectural complexity of the block copolymers, i.e. the more complex is molecular architecture, the greater is conformation restriction in microdomain formation and the less is solubility of homopolymer in corresponding domains.     

Influence of Zn ion implantation on structures and field emission properties of multi-walled carbon nanotube arrays

The structures and field emission properties of multi-walled carbon nanotube arrays implanted with Zn+ by MEVVA ion implanter have been investigated.The results revealed that Zn+implantation induced structural damage and that the top of carbon nanotubes with multi-layered graphite structure were transformed into carbon nanowires with amorphous structure.Meanwhile,C:Zn solid solution was synthesized after Zn+ implantation.The turn-on field and threshold field were 0.80 and 1.31 V/μm,respectively for original...     

交通运输业节能减排国际管理手段及启示

交通运输业的能源消费在许多国家中都占有较高比例,经济发展较快的国家更是如此。介绍了能源消费大国英国、美国、欧盟以及日本交通运输业节能减排采取的主要管理手段,包括健全的法律体系、节能技术创新、有效的税费政策等。借鉴其先进经验,为我国交通运输业节能减排管理工作提供启示。     

企业节能减排的监控系统研究

经济发展与节能减排是一个矛盾的统一体,如何在二者之间进行平衡,考验着中国人的智慧。通过行业分类选取恰当的节能减排指标、采用统计学的基本原理、应用质量控制的技术与方法,提出了节能减排的指标体系和监控方法,以期对节能减排实施动态监控,对我国现阶段的企业节能减排工作有着重要的参考价值。     

含给电子Z-N催化剂催化乙烯/1-丁烯共聚的研究

研究了两种含有给电子体分别为对硝基苯胺、乙二醇二甲醚的Ziegler-Natta催化剂催化乙烯与1-丁烯高压的共聚反应性能,主要考察了反应条件对聚合活性、聚合物物理性质的影响,同时采用红外光谱法测定了聚合物的支化度.研究表明,给电子体为乙二醇二甲醚的催化剂催化活性高于对硝基苯胺.反应条件如反应压力、温度、铝钛比对聚合活性、丁烯的插入率以及聚合物性质都有明显影响.高的反应压力有利于1-丁烯插入和聚合物堆密度的提高;反应温度在50℃时的聚合活性最大,聚合物的支化度较高,聚合物熔点较低;铝钛比为500时聚合活性高于低铝钛比的聚合活性.     

膨胀石墨的饱和吸附量与微观结构的关系

采用不同的方法测定膨胀石墨对不同油质的饱和吸附量,来探讨膨胀石墨的结构与饱和吸附量的关系.由扫描电镜可知,膨胀石墨具有较大的比表面积,其孔结构是以中、大孔为主;蠕虫石墨的表面结构与其内部结构不同,其内部为典型的片层结构.通过观察石墨内部孔结构特征变化,可以分析膨胀石墨对油的去除效率以及影响因素.     

Preparation of highly crystalline nanofibers on Fe and Fe-Ni catalysts with a variety of graphene plane alignments

The present study confirmed that highly crystalline nanofibers with controlled structure may be prepared over Fe and Fe-Ni alloy catalysts. The degree of graphitization of various carbon nanofibers (CNFs) was analyzed by using C(0 0 2) peaks from the XRD profiles. The C(0 0 2) peaks of CNFs over Fe catalyst shifted to higher angle and became narrower as the preparation temperature increased from 560 to 620 °C. Tubular CNFs prepared at temperature higher than 630 °C showed lower 2θ angles compared to those of platelet fibers. CNFs prepared over Fe-Ni catalysts tended to resemble those prepared over Fe catalysts. The degree of graphitization of platelet CNFs resembled natural graphite, while d_0 0 2 of the tubular CNFs showed values below the 3.39 Å reported as a theoretical minimum for a cylindrical alignment. Lc_0 0 2 of platelet and tubular CNFs increased by heat treatment at 2000 and 2800 °C though d_0 0 2 changed little. A transverse section of platelet and tubular CNFs had a hexagonal shape, not a round shape. The hexagonal column allows AB stacking of hexagonal planes that can give perfect hexagonal alignment.     

基于无线通信方式的TV二次压降现场测试方法

针对传统的TV二次压降现场测试方法存在的问题,提出基于无线通信技术的检测方法。以提高工作效率,降低安全风险。     

光化学反应中的磁场效应 Ⅱ.电子转移光敏化1,2-二苯乙烯的顺反异构化反应

前文报道了外加磁场对吸附在硅胶表面上的芳砜光解反应的影响,本文报道外加磁场影响光化学反应的另一个例子——电子转移光敏化1,2-二苯乙烯的异构化。 近年来电子转移光敏化反应引起了有机光化学家们的极大注意。一些异构化、重排、裂解、氧化反应都可以通过电子转移机理敏化。电子转移光敏化的机理可以用(1)描述。图中A和D分别代表电子的受体和给体。     

Global Avalanche Characteristics of Boolean Functions by Concatenation

In order to measure the correlation propeties of two Boolean functions,the global avalanche characteristics of Boolean functions constructed by concatenation are discussed,i.e.,f_1‖f_2and f_1‖f_2‖f_3‖f_4.Firstly,for the function f = f_1‖f_2,the cross-correlation function of f_1,f_2 in the special condition are studied.In this case,f,f_1,f_2 must be in desired form.By computing their sum-of-squares indicators,the crosscorrelation function between f_1,f_2 is obtained.Secondly,for the function g = f_1‖f_2‖f_3‖f_4,by analyzing the relation among their auto-correlation functions,their sum-of-squares indicators are investigated.Based on them,the sum-of-squares indicators of functions obtained by Canteaut et al.are investigated.The results show that the correlation property of g is good when the correlation properties of Boolean functions f_1,f_2,f_3,f_4 are good.